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Signal word Warning <br />Hazard statement(s) <br />H315 Causes skin irritation. <br />H319 Causes serious eye irritation. <br />H336 May cause drowsiness or dizziness. <br />H351 Suspected of causing cancer. <br />Precautionary statement(s) <br />P201 Obtain special instructions before use. <br />P202 Do not handle until all safety precautions have been read and <br />understood. <br />P261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. <br />P264 Wash skin thoroughly after handling. <br />P271 Use only outdoors or in a well-ventilated area. <br />P280 Wear protective gloves/ protective clothing/ eye protection/ face <br />protection. <br />P302 + P352 IF ON SKIN: Wash with plenty of soap and water. <br />P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable <br />for breathing. Call a POISON CENTER/ doctor if you feel unwell. <br />P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. <br />Remove contact lenses, if present and easy to do. Continue <br />rinsing. <br />P308 + P313 IF exposed or concerned: Get medical advice/ attention. <br />P332 + P313 If skin irritation occurs: Get medical advice/ attention. <br />P337 + P313 If eye irritation persists: Get medical advice/ attention. <br />P362 Take off contaminated clothing and wash before reuse. <br />P403 + P233 Store in a well-ventilated place. Keep container tightly closed. <br />P405 Store locked up. <br />P501 Dispose of contents/ container to an approved waste disposal <br />plant. <br />2.3 Hazards not otherwise classified (HNOC) or not covered by GHS - none <br />SECTION 3: Composition/information on ingredients <br />3.1 Substances <br />Synonyms : Methylene chloride <br />DCM <br />Formula <br />Molecular weight <br />CAS-No. <br />EC-No. <br />Index-No. <br />: CH2Cl2 <br />: 84.93 g/mol <br />: 75-09-2 <br />: 200-838-9 <br />: 602-004-00-3 <br />Component Classification Concentration <br />Dichloromethane <br />Skin Irrit. 2; Eye Irrit. 2A; <br />Carc. 2; STOT SE 3; H315, <br />H319, H351, H336 <br />Concentration limits: <br />20 °/0: STOT SE 3, H336; <br /><= 100 % <br />Sigma-Aldrich - 270997 <br />Page 2 of 12 <br />The life science business of Merck KGaA, Darmstadt, Germany <br /> hilittiPORQ <br />operates as MilliporeSigma in the US and Canada SiGNIa