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PNNR <br /> naphthanate, creosote, DEN, Hope and Lit). These data area presented in Attachment C, and were used <br /> for initial identification of chemical analytes expected to be present due to the wood preservative process. <br /> 3. Statistical Data Characterization <br /> According to USEPA's SW-846 Method (Chapter 9), the appropriate statistic to consider during waste <br /> classification is the upper confidence limit(UCL)on the mean analyte concentration in the waste sampled. <br /> Specifically, a significance level of 0.20 is used for the confidence interval (comprised of the lower and <br /> upper confidence limits; see Equation (6) in Table 9-1 of SW-846), and thus the upper confidence limit <br /> provides 90 percent confidence that the true mean concentration in the waste is no higher than the UCL. <br /> Determination of whether or not a waste is hazardous is decided as described in footnote (a) of Table 9-1 <br /> of the SW-846: <br /> "The contaminant of concern is not considered to be present in the waste at a hazardous level if <br /> the upper limit of the CI[confidence interval]is less than the applicable RT[regulatory threshold]. <br /> Otherwise, the opposite conclusion is reached." <br /> The appropriate calculation of a confidence interval for a data set depends on observed characteristics, in <br /> particular the data distribution (e.g., normal, gamma, lognormal), the presence of potential data outliers, <br /> and the presence of censored data (non-detects). Detailed discussion of UCL method selection and <br /> calculation is available in various USEPA guidance documents (e.g., 2015, 2009, 2006). The SW-846 <br /> method indicates that non-normal data sets may be normalized through the use of an appropriate data <br /> transformation if needed. <br /> GHD subjected the compiled waste characterization data (Attachment B)to a series of statistical <br /> procedures consistent with the SW-846 requirements focused on the following questions: <br /> i) Are UPRR's rail tie wastes non-hazardous on an overall basis? <br /> ii) How much do individual waste batches vary, and can a confidence interval on a "non-hazardous" <br /> classification be developed? <br /> Initial consideration was given to identifying chemical analytes present due to the wood treatment process. <br /> This was based on the analytical results for new rail ties treated with common preservatives. Table 3.1 <br /> (following text) summarizes the concentration ranges observed in untreated wood and compares the <br /> newly-treated wood ties to the control samples. Cases where an analyte was found to consistently be <br /> present at concentrations above controls in at least one of the treatment types (typically in at least half of <br /> the samples analyzed) are highlighted in yellow in Table 3.1. The following analytes were identified as <br /> being associated with the rail tie wood preservatives tested: <br /> a) Metals (arsenic, barium, cadmium, chromium, cobalt, copper, lead, molybdenum, nickel, silver, <br /> thallium and zinc) <br /> 11183843Pol lack-1.dou 3 <br />