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Carbon dioxide <br />Safety Data Sheet P-4574 <br />Maldng our planet more productive This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication. <br />Date of issue: 01/01/1980 Revision date: 10/17/2016 Supersedes: 07/19/2016 <br />5.3. Advice for firefighters <br />Firefighting instructions <br />Other information <br />WARNING! Liquid and gas under pressure. <br />Evacuate all personnel from the danger area. Use self-contained breathing apparatus (SCBA) <br />and protective clothing. Immediately cool containers with water from maximum distance. Stop <br />flow of gas if safe to do so, while continuing cooling water spray. Remove ignition sources if <br />safe to do so. Remove containers from area of fire if safe to do so. On-site fire brigades must <br />comply with OSHA 29 CFR 1910.156 and applicable standards under 29 CFR 1910 Subpart <br />L—Fire Protection. <br />: Containers are equipped with a pressure relief device. (Exceptions may exist where authorized <br />by DOT [U.S.] or TC [Canada].). <br />SECTION 6: Accidental release measures <br />6.1. Personal precautions, protective equipment and emergency procedures <br />General measures WARNING! Liquid and gas under pressure. Rapid release of gaseous carbon dioxide <br />through a pressure relief device (PRO) or valve can result in the formation of dry ice, <br />which is very cold and can cause frostbite. <br />For non-emergency personnel <br />For emergency responders <br />Environmental precautions <br />Try to stop release. <br />Methods and material for containment and cleaning up 11.11=111111111111•1====1 <br />No additional information available <br />No additional information available <br />For containment Prevent waste from contaminating the surrounding environment. Discard any product, residue, <br />disposable container, or liner in an environmentally acceptable manner, in full compliance with <br />federal, provincial, and local regulations. If necessary, call your local supplier for assistance. <br />6.4. Reference to other sections <br />See also sections 8 and 13. <br />SECTION 7: Handlin • and storage <br />7.1. Precautions for safe handling <br />Precautions for safe handling : Avoid breathing gas <br />Do not get in eyes, on skin, or on clothing <br />This gas is heavier than air and in an enclosed space tends to accumulate near the floor, <br />displacing air and pushing it upward. This creates an oxygen-deficient atmosphere near the <br />floor. Ventilate space before entry. Verify sufficient oxygen concentration <br />WARNING: Concentration levels of carbon dioxide above about 1 percent are <br />dangerous. Praxair recommends continuous monitoring with alarms to indicate unsafe <br />conditions before and during potential personnel exposure. Use appropriate monitoring devices <br />to ensure a safe oxygen level (minimum of 19.5 percent) and a safe carbon dioxide level <br />Wear leather safety gloves and safety shoes when handling cylinders. Protect cylinders from <br />physical damage; do not drag, roll, slide or drop. While moving cylinder, always keep in place <br />removable valve cover. Never attempt to lift a cylinder by its cap; the cap is intended solely to <br />protect the valve. When moving cylinders, even for short distances, use a cart (trolley, hand <br />truck, etc.) designed to transport cylinders. Never insert an object (e.g, wrench, screwdriver, pry <br />bar) into cap openings; doing so may damage the valve and cause a leak. Use an adjustable <br />strap wrench to remove over-tight or rusted caps. Slowly open the valve. If the valve is hard to <br />open, discontinue use and contact your supplier. Close the container valve after each use; <br />keep closed even when empty. Never apply flame or localized heat directly to any part of the <br />container. High temperatures may damage the container and could cause the pressure relief <br />device to fail prematurely, venting the container contents. For other precautions in using this <br />product, see section 16. <br />EN (English US) <br /> SOS ID: P-4574 <br /> 3/9 <br />This document is only controlled while on the Praxair, Inc. website and a copy of this controlled version is available for download. Praxair cannot assure the integrity or <br />accuracy of any version of this document after it has been downloaded or removed from our website.