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Site Specific Health, Safety and Environmental Plan <br /> 12 <br />Compound Physical/Chemical Characteristics <br />(Target Organs/ Route of Entry) <br />OEL <br />(STEL) <br />Odor <br />Threshold <br />LEL <br />(%) <br />IP <br />(eV) <br />chrysene, <br />phenanthrene, <br />fluoranthene, <br />pyrene, <br />acenaphthene, <br />methylnaphthalenes, <br />and anthracene) <br />be irritating to the eyes. Direct contact can <br />be highly irritating to the skin and can cause <br />dermatitis. Exposure to high vapor <br />concentrations may cause headaches, <br />nausea, vomiting, and other symptoms. <br />Includes human carcinogens. Reacts with <br />acids and oxidizers; produces acrid smoke, <br />toxic gases when involved in fires, thermal <br />decomposition. <br />Exposure to all routes should be carefully <br />controlled to levels as low as possible. <br />Confirmed Animal Carcinogen. <br />extractable <br />fraction) <br /> <br />Naphthalene <br />(91-20-3) <br />1ppm = 5.24 mg/m3 <br />Skin eye, ingestion, and inhalation hazard. <br />Over exposure may cause headache, nausea, <br />diaphoresis, hematuria, fever, anemia, liver <br />damage, vomiting, convulsions, and coma. <br />Flammable when exposed to heat or flame <br />reacts with oxidizing materials. Reacts <br />violently with CrO3; aluminum chloride + <br />benzoyl chloride. <br /> <br />10 ppm TWA <br />(15 ppm) <br />Skin <br /> <br />IDLH: 250 ppm <br /><0.3 ppm 0.9 8.12 <br />Metals / Inorganics <br />Arsenic, and <br />inorganic <br />compounds as As <br />(7440-38-2) <br />A human carcinogen; a powerful allergen, <br />inhalation and contact causes burning, <br />swelling and redness in the eyes, nose, <br />throat and skin; ingestion causes nausea, <br />vomiting, nervous system effects in the <br />extremities (numbness, tingling, weakness); <br />long term exposure can cause liver, kidney, <br />and blood damage. A fire hazard in the form <br />of dust or contact with oxidizers; thermal <br />decomposition produces toxic gases <br />0.01 mg/m3 <br />TWA <br />C – 0.002 <br />mg/m3 (15- <br />min) <br />IDLH/Ca: (5 <br />mg/m3 as As) <br />N/A N/A N/A <br />Cadmium, as dust <br />(7440-43-9) <br />Exposure routes via inhalation and ingestion. <br />A suspected human carcinogen; skin, eye, <br />respiratory irritation; mild flu and fever <br />symptoms (metal fume fever); pneumonitis, <br />pulmonary edema. Silver-white, blue-tinged <br />lustrous, odorless solid. Reacts violently with <br />ammonium nitrate; finely divided cadmium <br />metal can become pyrophoric; avoid heat, <br />flame, causes cadmium fume formation. <br />0.005 mg/m3 <br />TWA <br /> <br />IDLH/Ca: 9 <br />mg/m3 (as Cd) <br />N/A N/A N/A <br />Copper, dusts and <br />mists as Cu <br />(7440-50-8) <br />Exposure routes via inhalation, ingestion, <br />skin and/or eye contact. A mucous <br />membrane, respiratory tract irritant. Also <br />can produce conjunctivitis, dermatitis, <br />nausea, vomiting, abdominal pain, liver, <br />1 mg/m3 as Cu <br />dusts or mists <br /> <br />N/A N/A N/A