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Revised Quarterly Monitoring Report – <br />Fourth Quarter/Annual 2024 <br />www.arcadis.com <br />Revised - Forward Landfill 4Q24 Quarterly Mon Report 06262025 4 <br />(RWQCB 2024a); equipment, field, and trip blanks were analyzed for VOCs by United States Environmental <br />Protection Agency (USEPA) Method 8260. <br />Toluene was measured in two of the trip blanks at quantifiable concentrations of 0.12 J and 0.56 micrograms per <br />liter (µg/L). PCE was measured in one field blank at a quantifiable concentration of 0.75 µg/L. PCE was also <br />measured in one equipment blank at a quantifiable concentration of 0.69 µg/L. No VOCs were measured in the <br />laboratory method blanks analyzed with the groundwater samples. Inorganic constituents (chloride, dissolved <br />antimony, dissolved copper, dissolved sodium, total dissolved solids (TDS), hexavalent chromium, sulfate, and <br />total iron) were measured at estimated trace concentrations in one or more of the laboratory method blanks <br />analyzed with the groundwater samples. Several samples contained similar reported concentrations of these <br />compounds, which are considered suspected laboratory contaminants. <br />Results from the duplicate groundwater samples collected from monitoring wells MW-10 and AMW-36S are <br />presented in Tables 3a through 3c along with the primary results for the wells. Comparison of the primary and <br />duplicate results for both wells and their duplicates indicate a relative percent difference of 20% or less for the <br />routine monitoring parameters (i.e., turbidity, temperature, specific conductance, and pH). All results had a <br />relative percent difference of 20% or less. Based on evaluation of the laboratory QA/QC data, the laboratory <br />results generated for fourth quarter 2024 were deemed acceptable, and the water quality samples collected are <br />representative of water quality at the Site. <br />2.2 Unsaturated Zone Monitoring <br />This section describes monitoring conducted within the vadose zone of the Site during fourth quarter 2024 and <br />the associated monitoring results. The unsaturated zone monitoring is conducted in accordance with MRP <br />Section B.2 (RWQCB 2024a). <br />2.2.1 Monitoring Program <br />The unsaturated zone monitoring network in the MRP includes 23 suction lysimeters and eight pan lysimeters <br />(MRP Table 6 [RWQCB 2024a]). The current unsaturated zone monitoring network includes 18 suction lysimeters <br />and 12 pan lysimeters, which includes four additional pan lysimeters than the MRP (TS-1 [FU-23], TS-2 [FU-23], <br />TS-3 [FU-24], and TS-4 [FU-24]). The lysimeter locations are shown on Figures 2 and 3 and listed in Table 1. <br />Five suction lysimeters (LY-E1A, LY-E1B, LY-E2A, LY-E2B, and D93B) are included in MRP Table 6 (RWQCB <br />2024a) and shown on Figure 2; however, these suction lysimeters were assumed destroyed and are proposed to <br />be removed from the MRP in the next revision. <br />The lysimeters samples were analyzed in accordance with MRP Tables 8 and 9 (RWQCB 2024a). Tables 5a and <br />5b detail results of soil pore liquids if they are present during the monitoring event. Supplemental analyses are <br />conducted every 5 years. The next 5-year analyses will be conducted in third quarter 2028 (MRP Table 10 <br />[RWQCB 2024a]). <br />The MRP also states that if a lysimeter location is dry, the location will be screened for methane and VOCs, and a <br />methane sample and USEPA Method TO-15 VOC sample may be obtained (MRP Section B.2.b and Table 7 <br />[RWQCB 2024a]). This process will begin in second quarter 2025. The prescreening of methane and total VOCs <br />will be conducted using a gas analyzing device for methane detection and a photo ionization detector for total