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was injected into the groundwater beneath the former evaporation pond at the northern corner of <br /> the Site. Concentrations of nitrate and 1,2,3-TCP declined following the injections. <br /> In 2007, HRC-Xe, a longer lasting form HRC®,was injected into the groundwater at the former <br /> evaporation pond and upgradient of offsite well MW-5. After the injections, concentrations of <br /> 1,2,3-TCP declined in offsite well MW-5 and in MW-6 downgradient of the former pond. The <br /> injections didn't appear to have an effect on the nitrate concentrations either well. <br /> Since 2013, COC concentrations in the on and offsite monitoring wells have fluctuated but <br /> generally declined. Nitrate concentrations exceed the MCL in onsite well MW-3 have been below <br /> the MCL in offsite well MW-5 for three consecutive sampling events. Concentrations of 1,2,3-TCP <br /> exceed the MCL in well MW-6RR. Concentrations of 1,2,3-TCP in offsite, downgradient well <br /> MW-5R since March 2022. Concentrations in well MW-6RR have also declined since 2005, but <br /> still exceed the MCL by an order or magnitude. <br /> The August 2023 groundwater sampling analytical results are shown on Figure 5. Graphs <br /> showing the COC concentrations over time are included as Appendix A. Historical COC <br /> concentrations in groundwater are summarized on Table 3. <br /> 5.0 PILOT TEST <br /> A carbon source will be injected upgradient of well MW-3R and possibly near the northern corner <br /> of the site to determine if nitrate concentrations in the groundwater can be reduced through EISB. <br /> The injection locations are shown on Figure 4. <br /> Offsite monitoring wells MW-5R and MW-8R will be used as the compliance wells and well MW- <br /> 4R will be used as the background well to fulfill the requirements of RWQCB General Waste <br /> Discharge Requirements (WDR) Order No. R5-2015-0012. <br /> 5.1 Remediation Technology <br /> EISB consists of creating conditions in the groundwater that are favorable for the COCs to be <br /> consumed during cellular respiration. Cellular respiration, or biodegradation, is a process where <br /> carbon and an electron acceptor(the COCs) are utilized by microbes to generate cellular energy, <br /> thereby stimulating microbial growth and reproduction. <br /> Increased microbial respiration following the addition of carbon results in depletion of dissolved <br /> oxygen (DO) and lowering of the oxidation reduction potential (ORP) due to the release of <br /> hydrogen. As conditions become anaerobic, nitrate, manganese, iron, then sulfate sequentially <br /> replace oxygen as the most energetically favorable electron acceptors. Once conditions are <br /> sufficiently anaerobic and the other electron acceptors have been depleted, 1,2,3-TCP can be <br /> degraded through biodegradation, abiotic reduction, and/or reductive dechlorination. <br /> A solution consisting of water and RNAS Remediation Product's (RNAS) Newman Zone will be <br /> injected into the groundwater at the locations on Figure 4. Newman Zone is comprised of <br /> fermentable carbon sources (lactic acid and fatty acids) that stimulate microbial growth in an <br /> anaerobic environment.A product information sheet for Newman Zone is included in Appendix B. <br /> Nutrien Vernalis, California 2 p <br /> Pilot Test Work Plan <br />