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Geosptec <br /> consultants <br /> One blind field duplicate sample per media type will be collected to assess the precision and overall quality <br /> of the sampling and analytical procedures, as well as the variability (sample heterogeneity) in obtaining <br /> samples that represent one sampling point. The duplicate sub slab and soil vapor samples will be collected <br /> simultaneously with the primary sample by using a "T" connector between two SummaTM canisters. The <br /> duplicate sample will be stored in the same manner as the primary sample and submitted to the appropriate <br /> laboratory for analysis of VOCs by EPA Method TO-15. One blind duplicate groundwater and indoor air <br /> sample will also be collected simultaneously with the primary samples. As an additional quality control <br /> measure,50%of the soil vapor samples will be analyzed for helium by the analytical laboratory by modified <br /> ASTM method D-1946. <br /> 3.5.1.1 Sample Handling and Custody Requirements <br /> Chain of custody forms will be completed during sampling and will include the sample identification, <br /> location,date and time of the sampling,number and type of container,and the requested analytical method. <br /> Sample documentation will be completed in the field, and the chain(s) of custody will accompany the <br /> samples through transportation and analysis. The chain of custody procedures will be strictly adhered to <br /> during sample collection,transportation, and laboratory handling to ensure the integrity of the samples. <br /> 3.5.2 Laboratory Quality Control Samples <br /> Laboratory QC samples,or reference standards,will be introduced into the measurement process to evaluate <br /> laboratory performance and sample measurement for the EPA TO-15, TO-15 SIM, 826013, and ASTM D- <br /> 1946 analytical methods. Control samples will be prepared from environmental samples or be generated <br /> from standard materials in the laboratory. Laboratory QC samples include method blanks, laboratory <br /> control samples (LCS) and laboratory control sample duplicates (LCSD), and continuing calibration <br /> verification(CCV) standards. <br /> 3.5.3 Data Verification and Validation <br /> Data verification and validation consist of evaluating data and accepting, qualifying, or rejecting data on <br /> the basis of sound criteria using established EPA guidelines. Laboratory data will be subjected to a data <br /> evaluation that will include the following: <br /> • A review of the full data package for completeness; <br /> • Review of chain of custody forms against laboratory reported information,including review of <br /> transfer of custody signatures, sample condition upon receipt by the laboratory, and sample <br /> preservation in comparison to method requirements; <br /> • Review of holding times and assessment of any holding time exceedances; <br /> • Review of QC information provided by the laboratory which will include: <br /> o assessment of LCS, LCSD, and laboratory duplicate sample percent recoveries and <br /> relative percent differences,as appropriate; and <br /> o assessment of CCV standards and surrogate recovery results in comparison to the <br /> laboratory's quality control requirements. <br /> 10 September 2025 <br />