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Cleanup in Vulnerable Communities'Initiative Final Project Reference:Bobson Cleaners <br /> Discovery and Enforcement Discovery Project Number:60688620-5.1 <br /> Investigation Work Plan <br /> Water samples that require acidification will be checked to confirm that sufficient acid has been added to attain a pH <br /> of less than 2. In the case of samples collected for VOCs analysis, the check vial will be discarded.The results of the <br /> pH check will be recorded in the field logbook. <br /> 3.2.8 Sample Packaging and Shipment <br /> A sample label will be affixed to each sample container with clear tape for proper identification in the field and for <br /> tracking in the laboratory. The sample labels will include the following information: <br /> • Job no., <br /> • Sample ID no., <br /> • Sampler's initials, <br /> • Date and time of collection, and <br /> • Preservative, if any. <br /> Following collection and labeling, samples will be immediately placed in a sample cooler for temporary storage. The <br /> following protocol will be followed for sample packaging: <br /> • Sample containers will be placed in clear, plastic, leak-resistant bags prior to placement in the ice chest. Sample <br /> sleeve liner caps or container screw caps will be checked for tightness and sealed prior to placing the sample in <br /> the bag.A self-adhesive custody seal will be placed about the end of each plastic bag.All custody seals will be <br /> signed and dated. <br /> • Samples to be shipped will be placed in a study cooler lined with a large plastic trash bag prior to placing <br /> samples therein.The bottom of the cooler will be lined with bubble wrap. Glass sample containers will be <br /> wrapped in bubble wrap. Empty space in the cooler will be filled with bubble wrap or Styrofoam peanuts to <br /> prevent movement and breakage of samples during shipment. <br /> • Ice or"Blue Ice" packs will be placed in double leak-resistant plastic bags and included in the coolers to keep <br /> samples at a chilled temperature of 4 degrees Celsius(°C)plus or minus 20C during transport to the analytical <br /> laboratory.When ice is used,the drain plug of the cooler will be secured with glass fiber tape to prevent melting <br /> ice from leaking out of the cooler. <br /> • The chain-of-custody form will be placed in a water-resistant plastic bag and taped on the inside of the lid of the <br /> cooler. <br /> • Strapping and/or DTSC evidence tape(or equivalent)will be placed around each cooler to secure the lid prior to <br /> transport to the laboratory. <br /> • A self-adhesive custody seal will be placed across the front closure of the cooler any time it is not in someone's <br /> possession or view before shipping. Just prior to shipping, custody seals will be affixed to the front, right, and <br /> back of the cooler.All custody seals will be signed and dated. <br /> To check the potential effects of sample transportation and handling on data quality, a temperature blank will be <br /> enclosed in each sample-shipping container when samples requiring preservation by chilling are transported. The <br /> temperature blank will be comprised of a 40-mL vial filled with distilled or potable tap water and clearly marked to <br /> indicate its purpose to the laboratory. The temperature blank will be placed next to the investigation samples during <br /> packaging.The temperature of the water in the temperature blanks will be recorded upon arrival at the laboratory. <br /> The target sample temperature is 40C plus or minus 2°C. <br /> Every effort will be made to transport the samples to the analytical laboratory at the end of each sampling day. <br /> However,for sampling days that continue after operating hours of the laboratory,the samples will be stored overnight <br /> in a secured location (e.g., in a locked office)under appropriate chain-of-custody procedures, and the samples will be <br /> shipped to the laboratory the next day. Prior to overnight storage, the cooler(s)will be restocked with new ice or blue <br /> ice to maintain the groundwater samples in a chilled state of 40C plus or minus 2°C. The sample collector will check <br /> the temperature blank inside each cooler at the beginning of the evening and in the morning and the temperature <br /> readings will be recorded in the field logbook.Alternately, samples may be shipped to the laboratory by overnight <br /> courier under chain-of-custody requirements specified herein. <br /> Prepared for: Department of Toxic Substances Control AECOM <br /> 19 <br />