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or basement floors when possible. This can be accomplished by drilling through the floor and <br /> sampling through the drilled hole. Alternatively, an angle-boring rig can be used to sample beneath <br /> the floor from outside the footprint of the building. When sampling directly beneath the floor is not <br /> possible, enough samples adjacent to the structure should be taken to adequately estimate an average <br /> concentration based on reasonable spatial and temporal scales. <br /> Soil gas measurements can be made using several techniques; however, active whole-air <br /> sampling methods and active or passive sorbent sampling methods are usually employed. Typically, <br /> a whole-air sampling method is used whereby a non-reactive sampling probe is inserted into the soil <br /> to a prescribed depth. This can be accomplished manually using a "slam bar," or a percussion power <br /> drill, or the probe can be inserted into the ground using a device such as a Geoprobe.° The <br /> Geoprobe® device is attached to the rear of a specially customized vehicle. In the field, the rear of <br /> the vehicle is placed over the sample location and hydraulically raised on its base. The weight of the <br /> vehicle is then used to push the sampling probe into the soil. A built-in hammer mechanism allows <br /> the probe to be driven to predetermined depths up to 50 feet depending on the type of soil <br /> encountered Soil gas samples can be withdrawn directly from the probe rods, or flexible tubing can <br /> be connected to the probe tips at depth for sample withdrawal. <br /> Whole-air sampling is typically accomplished using an evacuated Summa or equivalent <br /> canister, or by evacuation to a Tedlar bag. Normal operation includes the use of an in-line flow <br /> controller and a sintered stainless steel filter to minimize particles becoming entrained in the sample <br /> atmosphere. For a 6-liter Summa canister,a normal sampling flow rate for a 24-hr integrated sample <br /> might be on the order of 1.5 ml/min; however, higher sampling rates can be used for grab samples. <br /> The sampling rate chosen, however, must not be so high as to allow for ambient air inleakage <br /> between the annulus of the probe and the surrounding soils. Depending on the target compounds, <br /> excessive air inleakage can dilute the sample (in some cases below the analytical detection limits). <br /> One way to check for inleakage is to test an aliquot of the sample gas for either nitrogen or <br /> oxygen content'before the sample is routed to the canister or Tedlar bag. To test for nitrogen in real- <br /> or near real-time requires a portable gas chromatograph/mass spectrometer(GC/MS). A portable <br /> oxygen meter, however, can be used to test for sample oxygen content in real-time with a typical <br /> accuracy of one-half of one percent. If air inleakage is detected by the presence of excessive nitrogen <br /> or oxygen, the seal around the sample probe at the soil surface as well as all sampling equipment <br /> connections and fittings should be checked. Finally, the flow rate may need to be reduced to <br /> decrease or eliminate the air inleakage. <br /> The collection and concentration of soil gas contaminants can be greatly affected by the <br /> components of the sampling system. It is imperative to use materials that are inert to the <br /> contaminants of concern. Areas of sample collection that need particular attention are: <br /> • The seal at the soil surface around the sample probe <br /> • Use of a probe constructed of stainless steel or other inert material <br /> • Minimization of the use of porous or synthetic materials (i.e.,PTFE, rubber, or most <br /> plastics)that may adsorb soil gas and cause cross-contamination <br /> 63 <br />