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1000-07 Unleaded Gasoline MDS No.467 <br /> Eye Contact:Immediately hold the eyes open and wash continuously for at least 15 minutes with fresh running water. <br /> Ensure irrigation under eyelids by occasionally lifting the upper and lower lids.Transport to hospital or doctor without <br /> delay.Removal of contact lenses after an eye injury should only bd undertaken by skilled personnel. <br /> Skin Contact:Immediately remove all contaminated clothing,including footwear(after rinsing with water).Wash <br /> affected areas thoroughly with water(and.soap if available).Seek medical attention in event of irritation. <br /> Ingestion:Contact a Poison Control Center.If swallowed,do NOT induce vomiting.Give a glass of water. <br /> After,fust ag got appropriate to-plan4 parvmedic,or community medical support <br /> Note to Physicians:FoWcute or short term repeated exposures to petroleum distillates or related hydrocarbons: <br /> 1.Primary threat to life from pure petroleum distillate ingestion and/or inhalation is respiratory failure. <br /> 2.Patients should be quickly evaluated for signs of respiratory distress(e.g.cyanosis,tachypnea,intercostal retraction, <br /> obtundation)and given oxygen.Patients with inadequate tidal volumes or poor arterial blood gases(pO,<50 mm Hg <br /> or pCO,>50 mm Hg)should be intubated. <br /> 3.Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and electrocardiographic evidence of <br /> myocardial injury has been reported;intravenous lines and cardiac monitors should be established in obviously <br /> symptomatic patients.The lungs excrete inhaled solvents,so that hyperventilation improves clearance. <br /> 4.A chest x-ray should be taken immediately after stabilization of breathing and circulation to document aspiration <br /> and detect the presence of pneumothorax. <br /> 5.Epinephrine(adrenalin)is not recommended for treatment of bronchospasm because of potential myocardial <br /> sensitization to catecholamines. <br /> Inhaled cardioselective bronchodilators(e.g.Alupent,Salbutamol)are the preferred agents,with aminophylline a <br /> second choice. <br /> 6.Lavage is indicated in patients who require decontamination;ensure use of cuffed endotracheal tube in adult <br /> patients. <br /> Flash Point:-43°C <br /> Autoignition Temperature:280°C <br /> LEL: 1.4%v/v <br /> UEL:7.6%v/v <br /> Extinguishing Media:Foam.Dry chemical powder.Bromochlorodifluoromethane(BCF)(where <br /> regulations permit).Carbon dioxide. <br /> General Fire Hazards/Hazardous Combustion Products:Liquid and vapor are highly <br /> flammable.Severe fire hazard when exposed to beat,flatcar and/or oxidizers.Vapor forms an <br /> explosive mixture with air.Severe explosion hazard,in the form of vapor,when exposed to flame Fire Diamond <br /> or spark.Vapor may travel a considerable distance to source of ignition.Heating may cause expansion/decomposition <br /> with violent rupture of containers.On combustion,may emit toxic fumes of carbon monoxide(CO). <br /> Fire Incompatibility:Avoid contamination with oxidizing agents,i.e.nitrates,oxidizing acids,chlorine bleaches,pool <br /> chlorine etc.,as ignition may result. <br /> Fire-Fighting Instructions:Alert fire department and tell them location and nature of hazard.May be violently or <br /> explosively reactive.Wear breathing apparatus plus protective gloves.Prevent,by any means available,spillage from <br /> entering drains or water ways.If safe,switch off electrical equipment until vapour fire hazard removed. <br /> Use water delivered as a fine spray to control fire and cool adjacent area.Avoid spraying water onto liquid pools.Do <br /> not approach containers suspected to be hot.Cool fire exposed containers with water spray from a protected location. <br /> If safe to do so,remove containers from path of fire. <br /> r <br /> SmallSpills:Remove all ignition sources. Cleanup all spills immediately. Avoid breathing vapors and contact with <br /> skin and eyes.Control personal contact by using protective equipment.Contain and absorb small quantities with <br /> vermiculite or other absorbent material. Wipe up.Collect residues in a flammable waste container. <br /> Large Spills:Clear area of personnel and move upwind.Alert fire department and tell them location and nature of <br /> hazard.May be violently or explosively reactive.Wear breathing apparatus plus protective gloves.Prevent,by any <br /> means available,spillage from entering drains or water ways.No smoking,naked lights or ignition sources.Increase <br /> ventilation.Stop leak if safe to do so. <br /> Water spray or fog may be used to disperselabsorb vapor.Contain spill with sand,earth or vermiculite.Use only <br /> spark-free shovels and explosion proof equipment.Collect recoverable product into labeled containers for recycling. <br /> Absorb remaining product with sand,earth or vermiculite.Collect solid residues and seal in labelled drums for <br /> disposal.Wash area and prevent runoff into drains. <br /> If contamination of drains or waterways occurs,advise emergency services. <br /> Regulatory Requirements:Follow applicable OSHA regulations(29 CFR 1910.120). <br /> cam&0=0 Gankmwsu.eb*Carpondm Any ccumvwdd=a or .bn me wbBaWs pami..mm a pKabbbe& Page 3 of 5 <br />