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Ms. Lori Duncan <br /> March 31,2008 <br /> Page 5 of 7 <br /> Soil Vapor Survey,Vapor Intrusion Evaluation and Risk Evaluation <br /> In order to delineate the extent of hydrocarbon vapors in the soil and to investigate the potential for <br /> vapor migration and intrusion to indoor air, Ground Zero proposes to conduct a soil vapor survey. <br /> Five soil vapor samples will be collected at the approximate locations shown on Figure 3. The <br /> sampling locations are intended to provide data on the average concentrations of contaminant <br /> vapors beneath the building along with a biased sampling location at the former UST tank pit. <br /> Soil vapor samples will be collected in general accordance with the Department of Toxic <br /> Substances Control (DTSC) and RWQCB guidelines set forth in their report Advisory—Active Soil <br /> Gas Investigations (DTSC and RWQCB, 2003). An onsite mobile laboratory will analyze the <br /> vapor samples for constituents of concern. <br /> Drilline and Soil Vapor Sampling <br /> Drilling and soil vapor sampling will be conducted under the supervision of an experienced <br /> geologist. A C-57 licensed drilling contractor will advance five (5) soil borings to depths of <br /> approximately 5 feet bgs using push probe equipment. Soil vapor samples will be collected from <br /> each boring at approximately 5 feet bgs. Up to three (3) additional samples may be collected <br /> based upon field observations. <br /> At each sampling location, a direct push vapor sampling probe will be advanced to the desired <br /> sampling interval. The vapor collection system uses a steel vapor tip that is shielded during the <br /> driving process. Once the rod reached the desired depth of 5 feet bgs, the rod will be pulled back <br /> to expose a screen. To prevent ambient air intrusion a bentonite seal will be placed around the <br /> rod/surface interface. The seal will be hydrated and the subsurface conditions allowed to <br /> equilibrate for no less than 20 minutes after probe advancement. A leak test and a purge volume <br /> versus contaminant concentration test will be conducted per DTSC guidelines prior to the <br /> collection of the first sample. <br /> Samples will be collected from SGl at one, three and seven purge volumes and analyzed for <br /> TPHg, BTEX, gasoline oxygenates and additives and VOCs by GC/MS (EPA Method 8260). <br /> Diflouroethane (DFA) or similar leak compound will be sprayed around the rod/surface interface <br /> and tubing connections prior to collecting each vapor sample. The soil vapor samples will be <br /> collected at approximately 100 milliliters per minute (ml/min) into dedicated syringes. The <br /> samples will be uniquely identified and transferred under chain of custody protocol to the State- <br /> certified mobile laboratory on site for analysis. The purge volume containing the highest <br /> concentration of the constituent(s) of concern will be used as the purge volume for the remaining <br /> borings. If no constituents of concern are detected, a default of three purge volumes will be used. <br /> Sampling of the remaining sample point locations will continue using the same sampling protocol <br /> at the selected purge volume. A duplicate sample will be run from the sample location with the <br /> highest detected concentration of the constituent(s) of concern. <br /> G.\GROUNDZE\GABBARD\workpi ns\wp_0308.doc <br />