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STANDARD OPERATING PROCEDURE - <br />- GROUNDWATER SAMPLING <br />lit <br />Gettler-Ryan Inc. field personnel adhere to the following procedures for the collection and handling of <br />groundwater samples prior to analysis by the analytical laboratory. Prior to sample collection, the type of <br />analysis to be performed is determined. Loss prevention of volatile compounds is controlled and sample <br />preservation for subsequent analysis is maintained. <br />Prior to sampling, the presence or absence of free -phase hydrocarbons is determined using an interface <br />probe. Product thickness, if present, is measured to the nearest 0.01 foot and is noted in the field notes. <br />In addition, all depth to water level measurements are,collected with a static water level indicator and are <br />also recorded in the field notes, prior to purging and sampling any wells. <br />After water levels are collected and prior to sampling, each well is purged a minimum of three well <br />casing volumes of water using pre -cleaned pumps (stack, suction, Grundfos), or disposable bailers. <br />Temperature, pH and electrical conductivity are measured a minimum of three times during the purging. <br />Purging continues until these parameters stabilize. <br />Groundwater samples are collected using disposable bailers. The water samples are transferred from the <br />bailer into appropriate containers. Pre -preserved containers, supplied by analytical laboratories, are used <br />when possible. When pre -preserved containers are not available, the laboratory is instructed to preserve <br />the sample as appropriate. Duplicate samples are collected for the laboratory to use in maintaining <br />quality assurance/quality control standards. The samples are labeled to include the job number, sample <br />identification, collection date and time, analysis, preservation (if any), and the sample collector's initials. <br />The water samples are placed in a cooler, maintained at 4aC for transport to the laboratory. Once <br />collected in the field, all samples are maintained under chain of custody until delivered to the laboratory. <br />The chain of custody document includes the job number, type of preservation, if any, analysis requested, <br />sample identification, date and time collected, and the sample collector's name. The chain of custody is <br />signed and dated (including time of transfer) by each person who receives or surrenders the samples, <br />beginning with the field personnel and ending with the laboratory personnel. <br />A laboratory sl7pplierl trip binnk nor.nmnanipq <br />aarh camnlinn cat <br />samples, 5% trip blanks are included. The trip blank is analyzed for some or all of the same compounds <br />as the groundwater samples. <br />As requested by Chevron Products Company, the purge water and decontamination water generated <br />during sampling activities is transported by IWM to McKittrick Waste Management located in <br />McKittrick, California. <br />NXa1if0mi8Vam1slcheā€ž ivn-SOP. I 1-11-02 <br />