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<br />5,605,634
<br />TREATMENT OF CONTAMINATED
<br />GROUNDWATER
<br />This invention relates to the treatment of contaminated
<br />groundwater.
<br />BACKGROUND TO THE INVENTION
<br />The invention is aimed at simplifying the task of placing
<br />treatment chemicals and other substances into the ground,
<br />for the purpose of treating contaminants in groundwater,
<br />in-situ. Taking the water out of the ground for treatment is
<br />not particularly difficult technically, and if the water is taken
<br />out of the ground, the treatment chemicals can be applied to
<br />the water, above ground, in a reasonably well controlled
<br />manner, in whatever quantities and concentrations are
<br />required: but taking large quantities of water out of the
<br />ground, treating the water, and putting the treated water
<br />back, is very expensive, especially when the contaminant is
<br />Of the kind that is hazardous in small traces.
<br />THE INVENTION IN RELATION TO THE
<br />PRIOR ART
<br />2
<br />borehole may or may not be provided with a well -casing, but
<br />in any event the borehole is open to the throughflow of
<br />groundwater passing in through from side to side of the
<br />borehole, i.e, flowing laterally across and through the bore-
<br />s hole.
<br />A length of tubing is placed in the borehole, and arrange-
<br />ments are made for circulating the substance through the
<br />tubing. Some kinds of plastic and other non -rigid materials
<br />have the property that the plastic material is not entirely
<br />10 proof against the passage of liquids and gases. That is to say,
<br />some fluids can leak through the walls of tubes made from
<br />some kinds of plastic.
<br />The crystalline structure of the plastic is such that only a
<br />portion of the material is crystalline, and the rest is amor-
<br />15 phous. It is the amorphous areas which can allow the
<br />diffusion of fluids, especially those having the smaller
<br />molecules.
<br />20
<br />It has been proposed to inject, or otherwise place, chemi-
<br />cals, nutrients, and various substances directly into the u
<br />ground, in the path of an on -coming plume of contaminated
<br />groundwater, in order that the contaminants in the water may
<br />pass through the substances. Thereby, the contaminated
<br />groundwater may be treated without taking the water out of
<br />the ground. 30
<br />When dealing especially with treatment substances that,
<br />to be effcctive, and safe, can only be present in small traces,
<br />one of the difficulties is to inject the treatment substance
<br />evenly and smoothly, and to ensure an even dispersion of the
<br />treatment substance. In many cases, it is important that the 35
<br />treatment substance be evenly dispersed over the whole
<br />cross-sectional area of the oncoming plume, and to avoid
<br />pockets or streaks of concentration.
<br />Some treatment substances are only effective if present in
<br />the right concentration. Too much can be toxic in itself, 40
<br />besides being wasteful of expensive materials. Too little, and
<br />the treatment substance may be too dilute to have an effect.
<br />Of course, there aro streaks and pockets of varying
<br />concentration of the contaminants in the plume, and the ideal
<br />would be to tailor the concentration of the treatment sub- 45
<br />stance to exactly correspond to the concentration of the
<br />contaminant; however, it has been found to be a worthwhile
<br />contribution to the efficiency of the treatment system if the
<br />treatment substance at least is dispersed over the cross-
<br />section of the plume at an even, or pre -determined, concen- 50
<br />tration.
<br />An aim of the invention is to provide a means for injecting
<br />small traces of treatment substances into moving ground-
<br />water, in-situ, in such a manner that the concentration of the
<br />injected substances in the groundwater is smoothly and s5
<br />evenly dispersed through the water.
<br />Another aim of the invention is to provide a system for
<br />- injecting small traces of treatment substances into moving
<br />groundwater, in-situ, in such a manner that the concentration ba
<br />of the injected substances in the groundwater can be con-
<br />trolled to tighter limits than has been possible hitherto.
<br />THE GENERAL FEATURES OF THE
<br />INVENTION
<br />65
<br />The invention involves the use of a borehole or well,
<br />which is formed down into the ground from the surface. The
<br />Low density polyethylene (LDPE) is a plastic which has
<br />this property of allowing many substances to diffuse
<br />through, at significantly quantifiable flow rates, LDPE hav-
<br />ing a fairly high proportion of amorphous structure. Besides,
<br />LDPE is inexpensive and readily available, and its use is
<br />preferred in the invention. Dialysis tubing may be used when
<br />large diffusion flux rates are called for.
<br />In the invention, the substance diffuses out through the
<br />walls of the diffusion tube, and enters the ground water in the
<br />borehole. The substance is then picked up by the moving
<br />groundwater, and is home downstream along with the
<br />groundwater.
<br />DETAILED DESCRIPTION OF PREFERRED
<br />EMBODIMENTS
<br />By way of further explanation of the invention, exemplary
<br />embodiments of the invention will now be described with
<br />reference to the accompanying drawings, in which:
<br />FIG. 1 is an elevational cross-section of a polluted aquifer,
<br />containing a borehole, in which the system of the invention
<br />is being used to supply treatment material;
<br />FIG. 2 is a plan view of the aquifer of FIG. 1;
<br />FIG. 3 is a diagram showing the details of the construction
<br />of a type of diffusion tube.
<br />The apparatuses shown in the accompanying drawings
<br />and described below are examples which embody the inven-
<br />tion. It should be noted that the scope of the invention is
<br />defined by the accompanying claims, and not necessarily by
<br />specific features of exemplary embodiments.
<br />FIG. I shows a borehole 20 extending vertically down
<br />into the ground from the surface 23. The .borehole is
<br />provided with a lining or casing 25. The casing 25 is
<br />provided with openings 27, through which water can pass
<br />laterally into and out of the borehole, while screens 29 keep
<br />the borehole clear of gravel and other debris.
<br />Into the borehole is inserted a length 30 of diffusion tube,
<br />comprising a length of plastic tubing. The diffusion tube 30
<br />is placed down the borehole 20. An entry pipe 32 conveys
<br />fluid into the top or entry end 34 of the diffusion tube 30, and
<br />an exit pipe 36 takes fluid emanating from the bottom or exit
<br />end 38 of the diffusion tube 30 back out of the borehole 20.
<br />The diffusion tube lies beneath the surface 40 of ground-
<br />water present in the borehole 20.
<br />The entry and exit pipes 32,36 are brought out of the
<br />borehole, and are coupled to a circulation control unit 43,
<br />which resides outside the borehole, above ground.
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