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• <br />• <br />5,605,634 <br />TREATMENT OF CONTAMINATED <br />GROUNDWATER <br />This invention relates to the treatment of contaminated <br />groundwater. <br />BACKGROUND TO THE INVENTION <br />The invention is aimed at simplifying the task of placing <br />treatment chemicals and other substances into the ground, <br />for the purpose of treating contaminants in groundwater, <br />in-situ. Taking the water out of the ground for treatment is <br />not particularly difficult technically, and if the water is taken <br />out of the ground, the treatment chemicals can be applied to <br />the water, above ground, in a reasonably well controlled <br />manner, in whatever quantities and concentrations are <br />required: but taking large quantities of water out of the <br />ground, treating the water, and putting the treated water <br />back, is very expensive, especially when the contaminant is <br />Of the kind that is hazardous in small traces. <br />THE INVENTION IN RELATION TO THE <br />PRIOR ART <br />2 <br />borehole may or may not be provided with a well -casing, but <br />in any event the borehole is open to the throughflow of <br />groundwater passing in through from side to side of the <br />borehole, i.e, flowing laterally across and through the bore- <br />s hole. <br />A length of tubing is placed in the borehole, and arrange- <br />ments are made for circulating the substance through the <br />tubing. Some kinds of plastic and other non -rigid materials <br />have the property that the plastic material is not entirely <br />10 proof against the passage of liquids and gases. That is to say, <br />some fluids can leak through the walls of tubes made from <br />some kinds of plastic. <br />The crystalline structure of the plastic is such that only a <br />portion of the material is crystalline, and the rest is amor- <br />15 phous. It is the amorphous areas which can allow the <br />diffusion of fluids, especially those having the smaller <br />molecules. <br />20 <br />It has been proposed to inject, or otherwise place, chemi- <br />cals, nutrients, and various substances directly into the u <br />ground, in the path of an on -coming plume of contaminated <br />groundwater, in order that the contaminants in the water may <br />pass through the substances. Thereby, the contaminated <br />groundwater may be treated without taking the water out of <br />the ground. 30 <br />When dealing especially with treatment substances that, <br />to be effcctive, and safe, can only be present in small traces, <br />one of the difficulties is to inject the treatment substance <br />evenly and smoothly, and to ensure an even dispersion of the <br />treatment substance. In many cases, it is important that the 35 <br />treatment substance be evenly dispersed over the whole <br />cross-sectional area of the oncoming plume, and to avoid <br />pockets or streaks of concentration. <br />Some treatment substances are only effective if present in <br />the right concentration. Too much can be toxic in itself, 40 <br />besides being wasteful of expensive materials. Too little, and <br />the treatment substance may be too dilute to have an effect. <br />Of course, there aro streaks and pockets of varying <br />concentration of the contaminants in the plume, and the ideal <br />would be to tailor the concentration of the treatment sub- 45 <br />stance to exactly correspond to the concentration of the <br />contaminant; however, it has been found to be a worthwhile <br />contribution to the efficiency of the treatment system if the <br />treatment substance at least is dispersed over the cross- <br />section of the plume at an even, or pre -determined, concen- 50 <br />tration. <br />An aim of the invention is to provide a means for injecting <br />small traces of treatment substances into moving ground- <br />water, in-situ, in such a manner that the concentration of the <br />injected substances in the groundwater is smoothly and s5 <br />evenly dispersed through the water. <br />Another aim of the invention is to provide a system for <br />- injecting small traces of treatment substances into moving <br />groundwater, in-situ, in such a manner that the concentration ba <br />of the injected substances in the groundwater can be con- <br />trolled to tighter limits than has been possible hitherto. <br />THE GENERAL FEATURES OF THE <br />INVENTION <br />65 <br />The invention involves the use of a borehole or well, <br />which is formed down into the ground from the surface. The <br />Low density polyethylene (LDPE) is a plastic which has <br />this property of allowing many substances to diffuse <br />through, at significantly quantifiable flow rates, LDPE hav- <br />ing a fairly high proportion of amorphous structure. Besides, <br />LDPE is inexpensive and readily available, and its use is <br />preferred in the invention. Dialysis tubing may be used when <br />large diffusion flux rates are called for. <br />In the invention, the substance diffuses out through the <br />walls of the diffusion tube, and enters the ground water in the <br />borehole. The substance is then picked up by the moving <br />groundwater, and is home downstream along with the <br />groundwater. <br />DETAILED DESCRIPTION OF PREFERRED <br />EMBODIMENTS <br />By way of further explanation of the invention, exemplary <br />embodiments of the invention will now be described with <br />reference to the accompanying drawings, in which: <br />FIG. 1 is an elevational cross-section of a polluted aquifer, <br />containing a borehole, in which the system of the invention <br />is being used to supply treatment material; <br />FIG. 2 is a plan view of the aquifer of FIG. 1; <br />FIG. 3 is a diagram showing the details of the construction <br />of a type of diffusion tube. <br />The apparatuses shown in the accompanying drawings <br />and described below are examples which embody the inven- <br />tion. It should be noted that the scope of the invention is <br />defined by the accompanying claims, and not necessarily by <br />specific features of exemplary embodiments. <br />FIG. I shows a borehole 20 extending vertically down <br />into the ground from the surface 23. The .borehole is <br />provided with a lining or casing 25. The casing 25 is <br />provided with openings 27, through which water can pass <br />laterally into and out of the borehole, while screens 29 keep <br />the borehole clear of gravel and other debris. <br />Into the borehole is inserted a length 30 of diffusion tube, <br />comprising a length of plastic tubing. The diffusion tube 30 <br />is placed down the borehole 20. An entry pipe 32 conveys <br />fluid into the top or entry end 34 of the diffusion tube 30, and <br />an exit pipe 36 takes fluid emanating from the bottom or exit <br />end 38 of the diffusion tube 30 back out of the borehole 20. <br />The diffusion tube lies beneath the surface 40 of ground- <br />water present in the borehole 20. <br />The entry and exit pipes 32,36 are brought out of the <br />borehole, and are coupled to a circulation control unit 43, <br />which resides outside the borehole, above ground. <br />