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Oxygenate compounds methyl tert butyl ether(MTBE), ethyl tert butyl ether <br /> (ETBE), tert butyl alcohol (TBA), and tert amyl methyl ether (TAME) have <br /> never been detected in site groundwater samples The oxygenate compound <br /> dl-isopropyl ether (DIPE) has been measured at concentrations less than <br /> 16 µg/L in samples collected from wells near the source of the release <br /> Monitoring data indicates that the lateral extent of DIPE Impact is limited to <br /> Earthgrain's property boundaries <br /> Current depth to groundwater averages about 40 feet below ground surface <br /> (bgs) The lowest depth to groundwater, observed during our historic site <br /> monitoring, was about 60 feet bgs in December 1992 The PHS/EHD suggests <br /> that groundwater was at a depth of about 80 feet in 1978 Groundwater has <br /> consistently been evaluated to flow in an east-northeast direction across the <br /> site (see Figure 3) Groundwater flow has ranged from a direction of 53 <br /> degrees east of north(N53E) to N83E The historical mean direction of <br /> groundwater across the site is approximately N70E <br /> Current groundwater elevation data and historical elevation data are presented <br /> in Table 1 and Table 2, respectively Groundwater analytical data for this <br /> quarter is in Table 3 A summary of historic BTEX and TPH-G concentrations <br /> in groundwater is contained in Table 4 A summary of historic oxygenate <br /> concentrations in groundwater is contained in Table 5 <br /> 1.4 Natural Biodegradation of Petroleum in Groundwater <br /> Groundwater samples were collected in December 1996 and analyzed for <br /> various parameters to indicate the occurrence of natural intrinsic <br /> biodegradation of the petroleum hydrocarbon impact Groundwater sampling <br /> and analytical procedures followed those described in Protocol for Monitoring <br /> Intrinsic Bioremediation in Groundwater (Chevron Research and Technology, <br /> March 1995) A copy of the Chevron document and results of our assessment <br /> are contained in Philip's February 21, 1997 Quarterly Groundwater <br /> Monitoring And Natural Biodegradation Assessment Report <br /> The tested parameters included alkalinity, dissolved oxygen, oxidation- <br /> reduction (redox) potential, pH, specific conductivity, temperature, nitrate, <br /> sulfate, and ferrous iron Philip observed definite correlations between <br /> petroleum hydrocarbon concentrations and the location of samples within the <br /> plume, to dissolved oxygen, nitrate, sulfate, and redox potential values These <br /> results, and the observed decreases in petroleum concentrations over time, <br /> 1 strongly indicate that naturally occurring biodegradation is occurring in <br /> groundwater at this site <br /> May 1999 Subsurface Investigation and Groundwater Monitoring Report <br /> The Earthgrams Company Facility <br /> 2651 South Airport Way <br /> Stockton,CaliforniaPrepared for THE EARTHGRAINS COMPANY Prepared by Philip Services Corp <br /> C V21382\121382CGI1259971o599REP DOC June 22,1999 <br /> 3 <br />