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Mr. Marcus Pierce, Engineering Geologist g February 2012 <br />Central Valley Regional Water Quality Control Board <br />Subject: Copper Sulfate Impacted Soil Removal <br />A groundwater sample will also be collected from beneath the excavation to determine if <br />groundwater has been impacted by the copper sulfate in soil. Using direct -push technology, a <br />boring will be advanced to first occurrence of groundwater for collection of a grab groundwater <br />sample using a HydropunchTM tool, or similar technology. Soils will be cored continuously to <br />provide a detailed analysis of lithology for logging purposes and to visually observe and <br />document occurrences of copper sulfate in soil at deeper intervals, if any. A photoionization <br />detector (PID) will be used to screen the cored soils for VOCs approximately every five feet. <br />Boreholes will be abandoned according to SJCEHD's regulations with neat cement and the top <br />3 feet backfilled with clean native materials (SJCEHD, 2005). <br />The grab groundwater sample will be collected in sterile, laboratory -supplied containers, <br />submitted to a California -certified laboratory under appropriate COC documentation, and <br />analyzed for California Title 22 Metals using USEPA Method 601013/7000. <br />Additionally, representative samples of the excavated soil (a 4 -point composite sample) will be <br />collected by OTIE and also submitted to the California -certified analytical laboratory under <br />proper chain -of -custody documentation. Based upon waste impoundment requirements, the <br />sample may be analyzed for one or more of the following: <br />• Total petroleum hydrocarbons (TPH) by USEPA Method 8015 -modified; <br />• Volatile organic carbons (VOCs) by USEPA Method 8260B; <br />• California Title 22 metals by EPA Method 60106/7000; and <br />• Polychlorinated biphenyls (PCBs) by EPA Method 8082. <br />After confirmation sample collection, the excavation will be backfilled with clean borrow material <br />and compacted using the backhoe bucket or a sheepsfoot roller backhoe attachment. <br />Compaction testing will not be conducted for the site, as we anticipate that the proposed <br />compaction method will render the location usable for its previous use (i.e., vehicle <br />parking/storage). The excavation area will then be graded flush with the adjacent contours of <br />the site and the paved with asphalt to match the surrounding ground surface. Equipment will be <br />demobilized from the site following completion of these activities. <br />This approach to excavation, confirmation sampling, and backfilling during a single mobilization <br />is preferred for the following reasons: <br />• The impacts to soil are presumed to be limited in extent and, in general, will be visually <br />definable; <br />• CSMS personnel will have full use of their vehicle parking and storage facilities more <br />expediently; and <br />• Expensive excavation equipment will not be tied up at the site pending confirmation <br />sample analytical results, and can be re -mobilized readily if necessary to do so. <br />OTIE will notify the CVRWQCB of planned excavation activities at least one week prior to <br />implementation. <br />If confirmation sample results indicate that it is necessary to remobilize for additional <br />excavation, the clean backfill material will be removed and stockpiled adjacent to the <br />excavation, and additional soil will be excavated in the affected area. Confirmation samples will <br />then be recollected to ensure all impacted soil has been removed. <br />Oneida Total Integrated Enterprises, LLC Page 3 of 4 <br />