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Treatability Study Report and Feasibility Evaluation for <br />In Situ Petroleum Hydrocarbon Remediation <br />Field Maintenance Shop #24, 8020 South Airport Way <br />Stockton, California <br />1.3. TREATABILITY STUDY TECHNOLOGY DESCRIPTION <br />The following is a general description of the technology associated with the SVE, AS, and <br />HVDPE treatability study. Specific details associated with implementing these technologies for <br />the treatability study at the site are presented in Sections 2 through 5 below. The objective for <br />evaluating these technologies is to determine the degree to which they might be effective in <br />enhancing the removal of COPCs from soil and/or groundwater at the site, and in preventing <br />further migration of COPCs in groundwater. Technical information obtained during <br />implementation of these treatability studies is the basis for evaluating the technical feasibility of <br />the technologies (or a combination of them) for future remediation decisions at the site. That <br />evaluation is presented in this document. <br />The primary COPCs at the site are TPH-d, TPH-g, and VOCs (including BTEX, fuel oxygenates, <br />and naphthalene) related to suspected releases from former diesel and gasoline USTs. The <br />proposed approach to pilot testing includes volatilization with direct injection of air to the <br />subsurface, enabling a phase transfer of petroleum hydrocarbons and related compounds <br />adsorbed to soil and dissolved in groundwater to a vapor phase. The air and vapors are then <br />vented to the surface through the unsaturated zone. AS/SVE is achieved by injecting air directly <br />into the aquifer and extracting the air and contaminant vapors under negative pressure through <br />SVE wells, mitigating the vapor plume in the unsaturated zone. HVDPE wells were installed and <br />screened through the vadose zone and the contaminant plume in groundwater. HVDPE <br />removes a combination of contaminated groundwater and soil vapors from the subsurface, to be <br />treated and collected for disposal. It creates a pressure gradient towards the DPE wells via use <br />of vacuum, thus enhancing groundwater and soil vapor recovery. <br />1.3.1. Soil Vapor Extraction <br />For SVE, a vacuum is applied to the soil matrix to create a negative pressure gradient that <br />causes movement of vapors toward extraction wells. Volatile constituents such as petroleum <br />hydrocarbons and related constituents can readily be removed from the subsurface through the <br />extraction wells, and the extracted vapors are treated at the surface. Two key parameters used <br />to determine if SVE could be a viable alternative for remediating hydrocarbon -impacted soils are <br />the permeability of the soil and the volatility of the contaminants of concern (in this case <br />petroleum constituents). When these parameters are favorable for SVE at a site, a treatability <br />study can be implemented to investigate the effective ROI beneath the site, evaluate vapor - <br />phase concentrations and hydrocarbon mass removal rates, and obtain engineering design <br />parameters for determining appropriate equipment capacities for potential site -wide remediation. <br />The SVE treatability study was intended to determine the ROI for soil vapor extraction in soils <br />impacted with petroleum hydrocarbons and related constituents above groundwater in the <br />source area (former USTs area). The number and depth of proposed SVE wells and associated <br />monitoring points were selected to maximize data acquisition from various portions of an <br />approximately 30 feet of impacted soil in the vadose zone. Each portion was tested separately. <br />1.3.2. Air Sparge Testing <br />AS technology is implemented to reduce concentrations of volatile constituents in petroleum <br />hydrocarbons that are adsorbed onto soils and/or dissolved in groundwater. The technology <br />involves injecting contaminant -free air into the saturated zone, with the objective of transferring <br />petroleum hydrocarbons and related volatile constituents from a dissolved phase to a vapor <br />phase. The air is then vented through the unsaturated zone. <br />OTI E <br />