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Sheet Steel <br /> Components CAS No. % Weight Exposure Limits <br /> ACGIH TLV m Im') OSHA PEL (mg/ml) <br /> Sodium ritd(e 763240-0 <0.01 <br /> 10 Oxide Dust <br /> Zinc (galvanized) 7440 66-6 0 A - 10 5 OxideFume 5 Oxide Fume <br /> 10 Oxide Fume STEL 10 Oxide Dust <br /> NOTE : No Permissible exposure limits ( PEL) or threshold limit values (TLV) exist for steel over all . The above listing is a <br /> summary of elements used in alloying Modesto Steel products . Various grades of steel will contain different combinations <br /> of these elements and/or trace materials . Exact specifications may be found by calling the division and asking for a <br /> specification sheet. <br /> 4 , FIRST AID MEASURES <br /> Eye Contact- In case of overexposure to dusts or fumes , immediately flush eyes with plenty of water for at <br /> least 15 minutes occasionally lifting the eye lids . Get medical attention if irritation persists . Thermal burns <br /> should be treated as medical emergencies . <br /> Skin Contact - In case of overexposure to dusts or particulates , wash with soap and plenty of water, Get <br /> medical attention if irritation develops or persists . if thermal burn occurs , flush area with cold water and get <br /> immediate medical attention . <br /> Inhalation - In case of overexposure to dusts or fumes , remove to fresh air. Get immediate medical attention <br /> if symptoms described in this SDS develop . <br /> Ingestion - Not considered an ingestion hazard . However, if excessive amounts of dust or particulates are <br /> swallowed , treat symptomatically and supportively. Get medical attention . <br /> Notes to Physician - Inhalation of metal fume or metal oxides may produce an acute febrile state , with <br /> cough , chills , weakness , and general malaise , nausea , vomiting , muscle cramps , and remarkable <br /> leukocytosis . Treatment is symptomatic, and condition is self limited in 24-48 hours . Chronic exposure to <br /> dusts may result in pneumoconiosis of mixed type . <br /> 6 . FIRE FIGHTING MEASURES <br /> Flash Point ( Method ) - Not applicable <br /> Flammable Limits ( % volume in air) - Not applicable <br /> Auto ignition Temperature - Not applicable <br /> Extinguishing Media - For molten metal, use dry powder or sand , For steel dust use or dry sand , water, <br /> foam , argon or nitrogen . <br /> Special Fire Fighting Procedures - Do not use water on molten metal . Do not use Carbon Dioxide (CO2) . <br /> Firefighters should not enter confined spaces without wearing NIOSH /MSHA approved positive pressure <br /> breathing apparatus (SCBA) with full face mask and full protective equipment. <br /> Unusual Fire or Explosion Hazards - Steel products do not present fire or explosion hazards under normal <br /> conditions . Any non -oxidized fine metal particles/ dust generated by grinding , sawing , abrasive blasting , or <br /> individual customer processes may produce materials that the customer should test for combustibility and <br /> other hazards in accordance with applicable regulations . High concentrations of combustible metallic fines <br /> in the air may present an explosion hazard . <br /> 6 . ACCIDENTAL RELEASE MEASURES <br /> Precautions if Material is Spilled or Released - Emergency response is unlikely unless in the form of <br /> combustible dust . Avoid inhalation , eye , or skin contact of dusts by using appropriate precautions outlined <br /> in this SDS (see section 8) . Fine turnings and small chips should be swept or vacuumed and placed into <br /> appropriate disposable containers . Keep fine dust or powder away from sources of ignition . Scrap should <br /> be reclaimed for recycling . Prevent materials from entering drains , sewers , or waterways . <br /> Fire and Explosion Hazards - Some customer processes may generate combustible dust that may require <br /> specific precautions when cleaning spills or releases of dust . <br /> Environmental Precautions . Some grades of steel may contain reportable quantities of alloying elements . <br /> See Section 15 for additional information . <br /> Waste Disposal Methods - Dispose used or unused product in accordance with applicable Federal , State , <br /> and Local regulations . Please recycle. <br /> Page 4 of 8 <br />