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DEC -14 -leg 09:41 ID:L# TOLEDCi <br />TEL Fl0:419-24oR21 tt509 Pati <br />TITANIUM TETRACHLORIDE <br />breathing, supplemental oxygen may be <br />given from a demand type or <br />continuous -flow inhaler, preferably <br />with a physician's advice. Get medical <br />attention immediately. <br />The recommendations described in this <br />section are provided a general <br />guidance for minimizing exposure when <br />handling this product. Because use <br />conditions will vary depending upon <br />customer applications, specific safe <br />handling procedures should be deve.ioped <br />by 2 intended use onconknowledgeable <br />t onsedgand ` of the <br />equipment. <br />During the development of safe handling <br />procedures, Consideration should be <br />given to the need for cleaning of <br />equipment and piping systems to render <br />them nonhazardous before maintenance <br />and repair activities are performed, <br />Waste resulting from these procedures <br />should be handled in accordance with <br />SECTION XIV: DISPOSAL OF MATERIAL/ <br />CONTAINER. <br />ENGINEERING CONTROLS: <br />In those cases where <br />engineering <br />controls are indicated by <br />the use <br />conditions, the following <br />traditional <br />exposure control techniques may be used <br />to effectively minimize <br />employee <br />exposure: local exhaust <br />ventilation, <br />enclosed system design or <br />process <br />isolation and remote control in <br />combination with appropriate <br />use of <br />personal protective equipment. <br />reduce potential for exposure <br />INGESTION: <br />All food must be kept in a separate <br />area away from the storage/use <br />location. Eating, drinking, smoking <br />and carrying of tobacco products must <br />be prevented in areas where there is a <br />potential for exposure to this <br />material. Before eating, drinking or <br />smoking, hands and face must be <br />thoroughly washed. <br />SHIN CONTACT: <br />Skin contact with liquid or its aerosol <br />must be prevented through the use of <br />impervious clothing gloves and <br />footwear selected with regard for use <br />condition exposure potential. <br />Safety <br />showers, with quick <br />opening <br />valves <br />which stay open, should <br />be <br />readily <br />available in all areas <br />where <br />the material is handled or <br />Water should <br />stored. <br />insulated <br />be supplied <br />and heat -traced lines <br />through <br />Prevent freeze ups in cold weather. <br />to <br />EYE CONTACT: <br />Eye contact with liquid or aerosol must <br />be prevented through the use of <br />chemical safety glasses, goggles or a <br />face shield selected with regard for <br />use condition exposure potential. <br />Eye wash fountains, or <br />other means of <br />washing the eyes with <br />a gentle flow o <br />tap water, should be <br />readily availab <br />in all areas where <br />this material <br />handled or stored. <br />Water should t <br />supplied through <br />insulated an <br />heat -traced lines to prevent freeze-up <br />in cold weather, <br />respirators <br />INHALATION: <br />This material is normally handled under <br />closed process conditions. <br />In an <br />emergency situation where <br />adequate <br />ventilation is not available <br />and use <br />conditions could generate <br />vapor or <br />hydrogen chloride fumes, <br />inhalation <br />must be prevented through <br />the use of <br />NIOSH -approved, acid -gas <br />respirators <br />with dust, mist and fume <br />filters to <br />reduce potential for exposure <br />under the <br />use conditions_ Where <br />exposure <br />potential under the use <br />conditions <br />necessitates a higher <br />level of <br />Protection, use a positive <br />-pressure, <br />air -supplied respirator. <br />Page 4 of 6 <br />