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Material Safety Data Sheets Collection: <br /> Genlum Publishing Corporation <br /> Gm) 1145 NY 123 Street Sheet No.713 <br /> rga <br /> -, Schcneetady,NY 12303-1836 USA Lead (Inorganic) <br /> (518)377-8854 <br /> Issued: 8/90 <br /> Lead anorganlc)(Pb)Deamtpilon:Exists widely throughout the world in a number of oras Its main commercial source R 0 Genlatr <br /> is alerts ocad sulphide)•Lc+d mineral u separated from rude ones by blast-furnace atneidagt drossing,or electrsly' I 4 <br /> re .Led is used mostly in mmufarnrmi;storage batteries.Other uses are in manufacnrutg tetracthyllead and both S - I <br /> organiC and imrgzruc led comprnuds m eccnirs,plastica,rad electronic device•is producing ammutmuon,solder, K 0 3 0 <br /> cable covering,sheet ked and other metal Produce(brass,pipes,easshatg}in metall rgy;m weights and as ballast;u a - <br /> chemica)intermediate for lead alkyls and ptgn=is;as a consttuCon material for the tank linings.]aping, and equipment Miss <br /> used to handle the corrosive guts and liquids used in sulfiric acid manufacturing.petroleum refining.halogenation.cul- H 3 <br /> fonation,exruxio4 and condensation:and for x-ray and atomic radiation psotccxioa F 1 <br /> Other Designatbus CAS No.7439-92-1.lead oxide;lead salts,inorganic:mcWlic kad;plumbum. R 0 <br /> Manufacturer:Contac your supplier or distributor.Consult the latest CMnieahveat Buyer!Guiden"for a suppliers list. ppG. <br /> Caudoas fro gan k finds a potent r70ernk poiso&Organic led(for example,uxmedryl lead)has severe,but different,health a$ear. •Sec I <br /> Occupational lead poisorting is due to inhalation of dust and fumes.Major affected organ systems are the nervous,blood,and reproductive <br /> systems,a.•d kidneys.Health iarparmcm or disease may result from a severe acute short-or long-term exposure- <br /> IOtl2.�,.,.. <br /> Lead(inorganic)f=cs and dusts,as Pb,ca 100% <br /> 1989 OSHA PELs(IA&d,Ivor- 1989.90 ACGIH TLV(Lead, 1985-86 Toxicity Datat <br /> lamic compounds) Inorganic,fumes and dusts) Human,inhalation,TCL: 10µ /inn& affects gasroinicstunal ria <br /> -hr TWA.-50µghns TLV-TWA:150µghns and liver <br /> Action Level TWA*-30µg/ms Hu mm oral TD.:450 mg/kg ingested over 6 yr affects <br /> peripheral and aural nervous systerns <br /> 29 CFR 1910.1025 Lead Standard 1988 NIOSH REL Rat.oral.TD.:790 mg/kg affects multigenerstion reproductior <br /> Brood Lead Level:40µg/100 g <br /> 10-hr TWA:<100µg/ms <br /> •Amin level applies to employee cxponue wnhou msard to respirator sue <br /> i See MOSH,RTECS(OF75250X) for-Admorul mutative,reproductive,and toxicity el _ . <br /> 6Y <br /> Section 3 ;�hyslcaL Data`�� <br /> WE <br /> IG ng Point 3164'F(1740'C) Molecular Weight-2072D <br /> Melting Point:6213 T(327.4'C) - Specific Gmvlty(20'G4'C): 1134 <br /> Vapor-Pressum: 1.77 mm Hg at 1832'F(1000'C) Water Solubility:Relatively insoluble in het or cold water' <br /> Viscosity:32 cp at 6213'F(327.4'C) <br /> Appearance and Odor.Bluish-white,silvery,gray,very soft meal. <br /> •Lead dusdva more early at a low pH. <br /> Sgiaond ,�ireandExpioslonData•. :> <br /> "', <br /> Flash Point None reported Autolgnition Temperature.None reported I LEL:None reported UEL:None nepor <br /> ExdtLgulshlag Media:Use sty ehemieaL carbon dioxide,water spray,or foam to extinguish fine. <br /> Unusual Fire or Explosion Hazards: Flammable and moderately explosive in the form of drat when exposed to beat or flame. <br /> Special Flre-rlghdng Procedures:Isolate hazard arts rad deny entry.Since rue may produce toxic fumes,wear a self•contained breathing <br /> apparatus(SCBA)with a full faccpiae operated in the pressurc-demand or positive-pressure mode and full protective equipment Be aware of <br /> runoff from rue mmol methods.Do not release to sewers or waterways. <br /> Section 8 Reactivity Data _ n r <br /> Stablllty/Polymeriratbn:Lead is stable groom mmpaanre in da closed containers under normal storage and handling conditions.It tannis}us <br /> exposure to air.Hazardous polymerization Cannot Occur, <br /> Chemical Iocompatlbllitks Mixtures of hydrogen peroxide+rioxane explode on contact with lead.Lead is incomparable with sodnmt azide. <br /> zirconiwn.disodiurn acetylide-and oxidants.A violas reaction on igution may occur with concentrated hydrogen peroxide,chlorine rifluvric <br /> sodhmn acetylide(with powdered)cad),ammonium nitrate(below,200'C with powdered Iead).Lead is anackod by pure water and weak orgy <br /> acids in the presence of oxygen.Lead is resistant to tap water,hydrofluoric acid brine,and solvents. <br /> Coodltloos to Avoid: Rubber glove containing lead may ignite in nitric acid. <br /> Hazardous Products of Iecomposltlon:Thermal oxidative decomposition of lead can produce highly toxic fumes of lead <br /> Section&:Health aiazard 'Data <br /> Careloogeddty:Although the NTP and OSHA do not list lead as a carcinogen,the IARC lists it as probably carcinogenic to humans,but hr <br /> (usually)no human evidence However,the literature reports instances of led-induced neoplasms,both benign and malignant,of the kidney a <br /> other organs in laboratory rodents.Excessive exposure to led has resubted in neurologic disorders in infants.Experimentab studies show lead I <br /> reproductive and teratagetic effects in laboratory animals.Human male and female reproductive effects are also documented. <br /> Summary of Risks:Led is a potent,systemic poison that effect a variety of organ systems.including the nervous systart kidneys,reprodxt <br /> system blood formations•and gastrointestinal(Gra system.The most imprmant way lead enters the body is through inhalation,but it can also t <br /> ingested when led dust or unwashed hands contaminate food,drink,or cigarettes.Much of ingested led passe though feecs without abso:yr <br /> into the body.Adults may absorb only 5 b 15%of ingested led;children may absorb a much larger fraction.Once in the body,lead enters th <br /> -" bloodstream and circulates to various organs.Led concentrates and remains in bone for many yean; o amount of ked the body scores <br /> b <br /> increases u exposure continues,with possibly cumulative effects.Depending on the dose entering the body.lead can be deadly within.sever <br /> days or affect health after many yeas.Very high doses can cause brain damage(encephalopathy). <br /> Medical Conditions Aggravated by Exposure: Lead may aggravate nervous system disorders(e.g..epilepsy,neuropathies),kidney disczscs <br /> high blood pressure(hypertension).infertility,and anemia.Lead-induced anemia and its effect on blood pressure can aggravate cardiovascul <br /> disease e' ^- <br />