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No.470 Diesel Fuel Oil No.2-D 11/90 <br /> Section 6- :Health; Hazard Data t p "" <br /> Camloogenlclty: Although the IARC has not assigned an ovCTxu evaluation to diesel fuck u a u it has evaluated occupational exposures in <br /> petroleum refining as m IARC probable human carcinogen(Group 2A).It has evaluated distill=(light)diesel oils as not classifiable as human <br /> caseinogens(Group 3). <br /> Summary of Risks: Although diesel fuel's toxicologic effects should resemble kcrosin �somewhat <br /> �h�tmi�P.ou° natise�uvo=ting,and <br /> such as sulfurized esters.Excessive inhalation of aerosol or mist can cause respiratory nause recover <br /> loss of coordination,deprndmg on cooccat anon and exposure time.When removed from exposure crest,afYxted persons Y, to twat in- <br /> completely.If vomiting occurs after ingestion and if oil is aspirated Into the lungs,hemoahagtng and pulmonarypede�ma.prvgrespstsm8 <br /> volvement and chemical pneumonitis,may result A comparative ofmr�l toaaspir>��irumffi rosy be Sin body eelk)Amfxtio4 may ahs n- <br /> result in trarsirnt CNS depression or excitement Secondary Y hypoxia - and CNS toxicity, <br /> cele formation,and chrome lung dysfunction.Inhalation may result is euphoria,cardiac das,respiratory�•s les and a ts,usually on <br /> Prolonged or repeated skin contact may irritate hair follicles and block sebaceous glands, ucmg a rash of acne pimp )" Y <br /> arms and legs. <br /> Medical Conditions Aggravated by Long-Term Exposure: None reported. <br /> Target Organs Cee nervous system,Ildrl, and mucous membranes. <br /> Primary Entry Routes:Inhalation,ingestion. and in aevere cases central nervous stem <br /> Acute Effects:Systemic effects from ingestion include gastrointestinal irritation,vomiting,dinntica, ycarda( Y rap <br /> depression,pmgrrs.Ting,to coma or death Inhalation of aerosok or mists may result in imercascd rate of respiration,tach excessive id <br /> heart beat),and cyanosis(dart purplish discoloration of the skin and raucous membranes caused by deficient blood oxygenation). <br /> Chronic Effects:Repeated contact with the skin causes dermatitis. <br /> FIRST AIDtical <br /> Eyes:Gently lift the eyelids and flush immediately and continuously with flooding amounts of water until transported to an eimergencY <br /> facility.Consult a physician imnrdiatcly <br /> Skin:Ql ickl remove contamiaeted clothing.Riose with flooding amounts of water for at least 15 min.U large areas of the body have been <br /> exposed or if irritation pasisu,gas medical help immediately.Wash affected arca with soap and water. <br /> Inhaktlon:Remove exposed person to fresh err cad support bteatthhmin�u needed. <br /> Ingestion: Never give anything by mouth to an unconscious or conwIsing person.If ingested,do not induce vomiting due to aspiration hazard. <br /> Contact a physician immediately.Position to avoid aspiration. <br /> After first aid,get apP roprlate in-plant,paramedltq or community medlcal support and milkto cases of severe <br /> to Physicians:Gamic lavage u contraindicated due to aspiration hazard.Preferred antidotes are charcoal - <br /> aspiration pneumonitis,consider monitoring arterial blood gases to ensure adequate ventilation.Observe the patient for 6 hr.If vital signs become <br /> abnormal or symptoms develop,obtain a chest X-ray. <br /> 77 777 7777. <br /> -<. <br /> Section 7, SpU4 beak,and Disposal Procedures :i <br /> Spp ak:Notify safety persconcl,evacuate area for large spills,remove all heat and ignition sources,and provide i Etre ons plosio r P dc. <br /> ventilation.Cleanuyy rsomnel should protect mast erapor inhalation and liquid contact Clear illspromptly , hazer <br /> Use a noncombustible absorbent mate to pi up atnall spills or residua.For large spills.dike fat ahead to contain.Pickup liquid, m Qoral(� <br /> tion or disposal.Do not release to sowers or waterways due to health and fire andlor explosim hazard.Follow applicable OSHA regula <br /> CFR 1910.120).Diesel fuel oil No.2-D spills maybe catal harards.Report large spills• <br /> Disposal:Contact your supplier or a licoased contraclot for detailed tern mmendations.Follow applicable Federal,state,and local regulations. <br /> EPA Designations <br /> RCRA Hazardous Waste(40 CFR 261.21):Ignitable waste . <br /> CERCLA Hazardous Substance(40 CFR 302.4):Not loud <br /> SARA Extremely Hazardous Substance(40 CFR 355):Not listed <br /> SARA Toxic Chemical(40 CFR 372.65):Not listed <br /> OSHA Designatlons <br /> Air Contaminant(29 CFR 1910.1000,Subpart 2):Not listed ._ <br /> Section 8. Special Protection Data <br /> Goggles:Wear protective eyeglasses or chemical safety goggles,per 0.5 HA eye-and face-protection regulations(29 CFR 1910.133). <br /> Respirator:Seek fessional advice prior b respirator selection and use.Follow OSHA respirator regulations(29 CFR 1910.134)md,if neces- <br /> sary,use a NIOSH-approved to ks),respirator <br /> with a SCBmist A.Wfarruniter�Abm-g arc vapor ing r sv�d�4do notFor emergency <br /> Pr B�workers in oxygen-deficient or nomoutine operations leaning spills, <br /> os- <br /> Othereactor v car i or storage tanks), 8• P cIY t esP <br /> Other.Wcaz impervious gloves,boots, aprons,and gauntlets at prevent stria maintain <br /> ontact- <br /> Ventilation: Provide general and local czplosion-proof ventilation systems to maintain airborne concentrations that promote worker safety ands <br /> productivity.Local exhaust ventilation is preferred since it prevents contaminant dispersion into the work area by controlling it at its source. <br /> Safety Stations:Make available in the work as emergency eyewash stations,safetylquickdmo hshowerslenses coon ttst facilities. <br /> Remove this <br /> COmnminated Equipment:Never wear contact lenses in the,work ca:ork arsoft lenses may absorb, <br /> andmaterial from your shoes and equipment.Launder contaminated clothing before wearing. iall before eating,drinking. <br /> Comments:Neva ut,drink or smoke in work areas.Practice good personal hygiene after using this material,espec y <br /> smoking.using the toilet,or applying cosmetics. <br /> Section,9. Special Precautions and Comments <br /> Storage Requirements: Use and storage conditioos should be suitable for OSHA Class D combustible liquid Store in closed containers in a <br /> well-ventilated area away from hast and ignition sources and strong oxidizing agents.Protect containers from physical damage.To prevent smile <br /> sparks,electrically ound and bond all container and equipment cued lo shipping,receiving,or transferring operations.Use nonsparking tools <br /> and explosion-pproo�clectri cal equipmcnL No smoking in storage or use area. <br /> Engineering Controk:Avoid vapor or mist inhalation and prolonged skin contact Wear protective rubber gloves and chemical safety glasses <br /> what contact with liquid or high mist concentration may occur.Additional suitable protective clothing may be requited depcndimg on working <br /> conditions.Instiniu a respvatnry protection progam that includes regular training.mamieaanu,laspection,and evaluation.Praztice Good <br /> personal hygiene and housekecpmg pprated urns.DO not tvcar oil wn[aminaud clothing.At least weekly lamderiag of work clothes is recom- <br /> mended.Do not put oily rags in pockets.When working with this materia), weaz gloves or use barrio cream. <br /> Transportation Data(49 CFR 172.101) <br /> DOT Shipping Name:Fuel oil <br /> DOT Hazard Class:Combustible liquid <br /> ID No.: NA 1993 <br /> DOT Label: None <br /> DOT Packaglog Exceptions: 173.11 Ea <br /> nnT Pr ,,Irrmen Lc: None <br />