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SELF-MONITORING SAMPLE PROGRAM <br /> Permittee:Atlantic Richfield Company and Secore International, Inc. <br /> Location: 16 E. Harding Way,Stockton <br /> Effective Date:December I,2002 <br /> Permittee shall perform the following self-monitoring sample program: <br /> Parameter Frequency Type Location Discharge Analyticai <br /> (diagram attached) Li <br /> mlt Method <br /> Flow Continuous Metered 001-Final discharge 5 GPM N/A <br /> Lower Explosive Continuous Metered and 001-Final discharge 10% N/A <br /> Limit(gasoline) recorded <br /> PH Once prior to initial Grab,well mixed 001-Final discharge 5.0- 10.0 EPA 150.i <br /> discharge and then and representative <br /> once per month of reporting period <br /> Total Once prior to initial Grab,well axed 001-Final discharge 100 mg/1 EPA 1664 <br /> Petroleum discharge and then and representative EPA 418.1 <br /> Hydrocarbons once per month of reporting period <br /> Benzene Once prior to initial Grab,well axed 001-Final discharge Total= EPA 8021 <br /> Toluene discharge and then and representative 4.57 mg/1 EPA 8260 <br /> Ethylbenzene once per month of reporting period Benzene= <br /> Xylene <br /> 0.5 mg/I <br /> MTBE Once prior to initial Grab,well axed 001-Final discharge Below EPA 8021 <br /> discharge and then and representative detection EPA 8260 <br /> once per month of reporting period lint MDL= <br /> <0.5µg/1 0.5 pg/I <br /> Cadmium,Total Once prior to initial Grab, well mixed 001-Final discharge 2.0 mg/I EPA 200 <br /> Chromium,Total discharge and then and representative 5.0 mg/l Series <br /> Copper,Total once per year of reporting period 6.0 mg/1 <br /> Lead,Total 2.0 mg/I <br /> Nickel,Total 5.0 mg/I <br /> Zinc,Tota] <br /> 7.0 mg/1 <br /> Total Toxic Once prior to initial Grab,well mixed 001-Final discharge Total= EPA 624 <br /> Organics discharge and then and representative 4.57 rrig/1 and <br /> 40 CFR 413 once per year of reporting period Benzene= EPA 625 <br /> 0.5 mg/1 <br /> Page 1 oft <br />