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Jmmary-February, 1967
<br /> gles should be worn where splashes 4. Union Carbide Corporation: Booklet
<br /> are likely. F-41083. Union Carbide Corp.,270 Park '
<br /> 4. Ingestion: Accidental ingestion is Avenue, New York, New York 10017
<br /> highly improbable. (1964).
<br /> 5. Faith, W. L., et al.: Industrial Chem.
<br /> .u. Fire and explosion: The flash point. icals. 3rd Ed.,p. 780,John Wiley&Sons,
<br /> approximately 270'F, is too high for New York.(1965).
<br /> TDI to present a serious fire or ex- 6 Zapp J A.: Hazards of Isocyanates in
<br /> plosion hazard. The polyurethanes. polyurethane Foam Plastic Production.
<br /> particularly the foams, will burn and AMA Arch.Ind.Health 15: 324 (1957).
<br /> may release dangerous amounts of 7. Manufacturing Chemists' Association:
<br /> pyrolytie products. Chemical Safety Data Sheet SD-73,
<br /> 110160eIV. Medical Information Tolylene Dii.saeyanate. Manufacturing
<br /> A. EMERGENCY TREATMENT: Inhalation-the Chemists' Assoc., Inc., Washington,
<br /> patient should be removed to an area tree D. C. (1965).
<br /> from all source a exposure and con- 8. Committee on Threshold Limit Values:*
<br /> Threshold Limit Values for 1966.
<br /> American Conference of Governmental,
<br /> r [aminated clothing removed and the skin C e .
<br /> washed thoroughly with soap and water. rnmental
<br /> The severity of respiratory symptoms will Industrial, Hygienists, 1014 'Broadwav!
<br /> determine the need for oxygen and bron- Cincinnati, Ohio 45202 (1966).
<br /> chodilators. Eyes should be irrigated 9• Dernehl, C. U.: Personal comumnica-
<br /> thoroughly with water for at least 15 tion, Union Carbide Corporation, 270,1
<br /> minutes. All emergency cases should be Park Avenue, New York 10017.
<br /> seen by a physician. 10. Duncan, B., L. D. Scheel, E. J. Fair.
<br /> B. SPECIAL MEDICAL PROCEDURES: Pte-em- child, R. Killens, and S. Graham: Toly'"y
<br /> I plovment physical examination should ex- uene Diisocyanate Inhalation Toxicity",
<br /> de Pathology and Mortality. Amer.' In
<br /> elud:
<br /> i persons with chronically recurring Hyg. Assoc. J. 23: 447 (1962). L
<br /> pulmonary disease and/or an allergic
<br /> history. Initial evaluation should include 11. Walworth, H. T., and W. E. Virchow:
<br /> Al chest x-rav and pulmonary , function Industrial Hygiene Experiences with
<br /> studies (vital capacity and timed one- Toluene Dnisocyanate. Amer. Ind. Hyg.
<br /> second vital capacity). Employees who Assoc.J. 20: 205 (1959).
<br /> have experienced acute or chronic low 12. Elkins, H. B., G. W. McCarl, H. G.
<br /> grade respiratory symptoms from TDI Brugsch, and J. P. Fahy: Massachusetts
<br /> should be removed from further expos- Experience with Toluene Diisocyanate.
<br /> ures. Amer. Ind. Hyg. Assoc. J. 23: 265
<br /> (1962).
<br /> V. References 13. Maxon, F. C.: Respiratory Irritation
<br /> 1. Synthetic Organic Chemical Manu- from Toluene Diisocyanate. AMA Arch.
<br /> facturer's Association.: SOCMA Hand- Environ. Health 8: 755 (1964).
<br /> book, Commercial Organic Chemical 14. Williamson, K. S.: Studies of Diiso-
<br /> Names. American Chemical Society, cyanate Workers. Trans. Assoc. Ind. {
<br /> 1155 Sixteenth Street, N.W., Washing- Med. Officers 15: 29 (1965),
<br /> ton, D. C. (1966). 15. Dernehl, C. U.: Health Hazards As
<br /> 2. National Safety Council: Data Sheet sociated with Polyurethane Foams.`
<br /> 489, Isocyanates. National Safety Coun- Occup. Med. 8: 59 (1966).
<br /> cil, Chicago, Illinois1960
<br /> ( ) I6. Munn,A.: Hazards of Isocyanates. Ann. i
<br /> 3. Allied Chemical Corp.: National Or- Occup.XYg•8:59 (1965).
<br /> ganic Chemicals. Allied Chemical Corp., 17. Pa. Dept. of Health: Occup. Health
<br /> 40 Rector Street, New York (1964). News & Views. Vol. 4, No. 2, p. 3
<br /> j'.
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