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Mr. W. T. Nickerson - 2 - 12 December 2000 <br /> The graphs depicting four-point moving averages for various constituents clearly show that most <br /> constituents are present in greatest concentrations in MW-6 and MW-8 which are the proximate <br /> downgradient wells from the northern former evaporation pond (northern pond), and present in lesser <br /> concentrations in MW-2 which is at the northern pond. These constituents include ethylene dibromide <br /> .(EDB), chloroform, 1,2-DCP, and nitrate. This suggests that the center of mass of the plume has <br /> migrated from the northern pond to the vicinity of MW-6 and MW-8. <br /> The graphical averages also show that after the October 1998 installation of caps over the former ponds <br /> (northern and southern ponds), concentrations of 1,2-DCP, 1,2,3-trichloropropane, nitrogen, chloroform, <br /> and EDB decreased significantly in MW-2, MW-6, and MW-8. To date, there is not a corresponding <br /> reduction in constituent concentrations in MW-5, which is downgradient of the southern pond. <br /> Table 3 of the first and third QMRs list MW-12 as containing a nitrate concentration of 223.5 mg/l in <br /> March 1999. The correct value should be 23.5 mg/l, as presented in the 1999 QMRs. <br /> DRAFT REVISED MONITORING AND REPORTING PROGRAM <br /> On behalf of UNOCAL, Sierra-Pacific proposes to reduce the frequency of groundwater elevation <br /> monitoring from quarterly to semi-annually, remove MW-6 from the monitoring schedule, and reduce <br /> monitoring in the deep monitoring well MW-7 and in upgradient wells MW-1 and MW-3 from semi- <br /> .annually to annually. It also proposes that analyses for chlorinated herbicides be removed from the <br /> schedule for the furthest downgradient wells MW-9 and MW-12 until they are detected in the mid- <br /> gradient well MW-5, and that the total Kjeldahl nitrogen analyses be replaced with ammonium analyses. <br /> Table 1 summarizes UNOCAL's proposal and Board staff's concurrence or counter-proposal as <br /> discussed in more detail below. <br /> Table 1. Proposed Changes to MRP No. 96-816 , Western Farm Service, Stockton <br /> Element of Change UNOCAL's Proposal Board Staff's Proposal <br /> TKN analyses Change to ammonium Concur <br /> Remove from schedule MW-6 Exchange MW-5 for MW-6 <br /> Reduce monitoring frequency from Groundwater elevation monitoring Concur <br /> quarterly to semi-annually <br /> Reduce monitoring frequency from MW-1, MW-3, MW-7 Concur. Add MW-6 <br /> semi-annually to annually <br /> Reduce EPA 8150 (chlorinated Analyze in MW-9 and MW-12, Analyze annually in MW-9 until <br /> herbicides) analyses contingent on detection in MW-5 detected. Then analyze semi- <br /> annually in MW-9 and MW-12. <br /> As Mr. Chase stated in his 28 July letter, Board staff provided verbal approval in 1997 to UNOCAL to <br /> substitute ammonium analyses for TKN. This change is formalized in the draft revised MRP. <br /> We concur with the frequency reduction for quarterly groundwater monitoring, and reducing monitoring <br /> frequency for the deep well MW-7 and upgradient wells MW-1 and MW-3 to annually in the fall. The <br /> monitoring history for MW-1 and MW-3 shows small seasonal variations in nitrate concentrations with <br /> the maximum occurring in the fall. MW-10 is further upgradient than MW-1 and MW-3, shows greater <br /> seasonal variations than the other two wells, and will continue to be monitored semi-annually. MW-7 <br />