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No. 317 4186 TOLUENE SECTION 6. HEALTH HAZARD IIVFORMATION TLV o acne u not ,: . . ,: .. ,.:;.. .. gen USFR- SUMMZXTTMK%; Vapors of ieftatioo of the eye;none arpm respiratory t�and Skin. Exposure b 200 ppm for S hours names mild fin uc may cause has no 040c:dvc 00 �a'mon(�+�P is(a SeaSat m of FrAlw& tangling.a creeping on�al m that •P and,b severe b ��O0wmvzWw may cause headache,rause;dirermess.dilated pupils.Sod soh eats.may sass sow carocal and death. The liquid JS mi"b The ryes Sod Skin. Cbmact MdV"prolonged 000�use with etranstre akin dam,m°j�vsl irritation Sod burns V not promptly removed. Repeated �'cause drying and cracking. h may be absorbed IMough ag"in bxic legation causes initatioc of the gast:oiotestinal tract and may caws effetza resembling those glom inhalation of _Spas APw Chronic overexposure b rolueoe may cause reversible kid $'flush rya.includingunder a �'Sod liver injury. $$gyp }saute' SKIN CbtJ[AfT• Yelids.with running water far st lean 15 minutes. Get medical atlmtion!t imitation Immediately flush Skin(for at least 15 minutes)while removatg onotamoioared shoo .s ea Wash exposed arwith soap and water. Get medical advolion V irritation and persists a if a e area has �• : Remove victim b fresh air. Restore and/or support bread WS d required�Keep victim warm Sod quiet Get medical help' INStF.mQN: Give victim 1 b 2 glasses of water or milk.Contact a poison control center. Do sot Induce vomit= ambsS directed to do so.Transport victim On a medical facility.Never give Soythin by mouth On a who is 011oo00friatmeal observation and ag►pous or convulsing. •GET MEDICAL ASSISTANCE.In plant.paramedic,commanity, Gu m�lashP or:afher fast all,if indicated SECTION 7. SPILL LEAK AND DISPOSAL PROCEDURES SPILn PAX: Notify yfuy persona of large Spills or oaks. Remove all scums of bat and eupkxion-proof ventilation. limit access b Spam area b el y necessary personnonlRemove Kms provide ma�timum place if feasible. Cleanup pers000el need ing° b tate wAc['t: DICPO.cAt, pro�a0°��contact withf y9'rid sad inhalation of vapor(ser sect. hi). Absorb small Spills with paper bwei or vermiculite.COMM lege Spills Sod 0011WA if feasible,or absorb with vermiculite or tend. Place waste solvent or absorbent into closed containers for disposal using nompatiting bols. Liquid can be flushed with water On So open holding arta for handling. DO sot flush On Sewerwatershed,or waterway. MMMENTS: Place in suitable container for disposal by a licensed contractor or bora in ao approved inebwator.Consider uclaiming by distillation.Contaminated absorbent can be buried b a Sanitary landfill Follow all Federal,state, and local regulations TLm 96: 100-10 ppm. Toluene is designated as a bwardous waste by We EPA. The EPA(RCRA)HW No.is U220(40 CFR 261). The reportable quality(RQ)is 1000 Iles/454 kg(40 CFR 117). SECTION & SPECIAL PROTECTION INFORMATION vide general sad local exhaust ventilation to mat TLV requirements. Ventilation fans and other electrical service must be noaspsrking and have ao explosion-proof design. Exhaust hoods should have a face velocity of at bast loo Ifm(linear feet per minute)and be designed to capatre heavy vapor. For emergency or nonroutine exposures wtm the TLV may be exceeded, swim organic chemical cartridge respirator if ooncemv2doo is less than 200 ppm and an approved canister gas mask or aelf- eoctamed breathing apparatus with full faccPmc if eoaceatratioo is grtwer than 200 ppm. Safety glasses or splash goggles Should be worn in W work seas. Neoprene gloves,aeon,face shield,boot:,and other appropriate protective clothing and equipment Should be available and worn as necessary to prevent Skin Sod eye 000tacL Remove contaminated cbthmg immediately and do not wear it aaW it bac boa properly laundered. Eyewash tuitions Sad safety shower:should be readily available In on and handling etas. Contact leases pose a special hazard;soft leases may absorb iaitaats and all Im n ooaoeatrsSe them. SECTION 9. SPECIAL PRECAUTIONS AND COMMENTS SIO A . c E ,ATLON: Store in a cool,dry,well-ventilated eta away from oxidizing agents.heak sparits,or open flame. Storage areas must meet OSHA requirements for class 1B flammable liquids.Use metal safety cans for handling small amounts. Protect containers from physical damage. Use only with adequate ventilation.Avoid contact with eyes,Stas,or clothing.Do sot inhale or ingest Use caution when handling this compound because it can be absorbed through intact Skin in brie amounts. SPECIAL HANDLiNG=RAGI Ground and bond Metal containers and equipment b prevent Static sparks when mating transfers. Do not smoke in use or Storage seas.Use noosparking bolt. ENGINEERING CONTROLS: preplacement Sod periodic medical exams emphasising the liver.kidneys.nervous Systema burgs.bears,and blood should be provided. Workers exposed b oonceanations greater than the action level(50 ppm)should be examined at least once a year.Use of doom an aggravate the On=effects of Masse. Lam: Emptied containers contain product residues. Handle accordingly! Toluene is designated as a humdous substance by We EPA(40 CFR 116). DOT Cl usifscadoo flammable b'q dd. UN1294. Data s Code: 1-9 12 16 20 21 24 26 34 E1 82. CR r�eSe,tsa.d nrc.rfaettfry arfntaema�oo e.o for Pvrhatilr Pspar Approvals Qe.�p.esa. M/tits. R ue�arily pu>st�f��sperobilYy 7ardea,attr+ou�lf�oo.eie ra:e 1 �o-wmwiw�no reerach pnocauu m��so I=uhiaja�raarypi bdusL Hylpene/Safety b a>e amury araytalibty drums mfamsem fa"p u=M to Pu�rrdr fraraa.d Popo..a res em.qu.e.d flea yr . Medical Review p-..b.oe r p*A-a CoPyti&O April 1. 1986 l•��R