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No.385 ETHYL BENZENE Aso$ `oe
<br /> SECTION 6. HEALTH HAZARD INFORMATION cont. >
<br /> flush eyes,including erode the eyelids,gently but thoroughly with flooding amounts of runaing water for at but 15 minutes.Skin.Rinse
<br /> the affected area with plenty of water,thea wash it with heap and warn.Inbaiation.Remove the exposed pawn to bub air restart and/or
<br /> support his or he breathing as needed.Have qualified medical personnel admiaister oxygen as required.Ingestion.Unlikely.Should
<br /> this type of exposure occur.the aspiration hazard must be considered.Do not induce vomiting unless directed to do so by a physician.To
<br /> prevent aspiration by spontaneous vomiting,beep the victim's bead low(between his at her)caws).Get medial help(in plant,para-
<br /> medic,a:atamtmtty)for W acpoenres.Seek prompt medical assistance for further treatment,observasioa,and support after first aid.Note
<br /> to Phydeian: Professional judgment is required as to whether or net to induce vomiting because of the possibility of expiration.A gastric
<br /> lavage may be administered,followed by saline catharsis,if this procedure is appropriate to the specific ioeidenL Mo&wr cardiac and
<br /> pulmaoary functions.
<br /> SECTION I.:..;.SPILL, LEAK, AND DISPOSAL- PROCEDURES
<br /> Splll/LAW" Notify safety personmel,evacuate unnecessary personnel.e ' i*at.all sources of ignition immediately,and provide adequate
<br /> explosioaproof vmt0stioa Cleanup personnel need protection against skin or eye contact with this liquid as well as inhalation of its vapor
<br /> (sex sect 11).Contain large spills and collect waste or absorb it with an inert material such as sand,earth.or vermiculite.Use nonspaking
<br /> I
<br /> to place waste liquid or absorbent into closable containers for disposal.Keep waste out of sewer,watersheds,and waterways.Waste
<br /> Disposal: Contact your supplier or a licensed connector for detailed recommendations.Follow Federal,state,and local regulations.
<br /> 061iA Daafgaatloas
<br /> LisW as ser Aa Coammiaaw(29 CFR 1910.1000 Subpart Z7.
<br /> EPA Dedgnadow(40 CFR MA)
<br /> CFRMA Hasardoua Subnaace,Repormble Qto=ty:IWO in(454 kg).per The C kaa Water Aa(CWA).it 311(b)(4)aad 307(a).
<br /> SECTION S. SPECIAL PROTECTION INFORMATION
<br /> Goggles: Always wear protective eyeglasses or chemical safety goggles. Where splashing is possible,wear a full face shield.Follow
<br /> OSHA eye-and face-protection regulations(29 CFR 1910.133).Respirator. Wear a NIOSH-approved respirator per Genium referemce 99
<br /> for the maximum-use concentrations and/or the exposure limits cited in section 2 Follow OSHA respirator regulations(29 CFR 1910.134).
<br /> For emergency or nonroutine operations(spills or cleaning reactor vessels and storage tanks),wear an SCBA.Warning: Air-Purifying
<br /> respirators will mor protect workers in oxygen-deficient atmospheres.Other: Wear impervious gloves,boots,aprons,and gauntlets,etc,to
<br /> prevent prolonged or repeated skin contact with this material.Ventilation: Install and operate general and local maximum.explosion-proof
<br /> ventilation systems powerful enough to maintain airborne levels of this material below the OSHA PEI,standard cited in section 2.Local
<br /> exhaust ventilation is preferred because it prevents dispersion of the cootaminant into the general work area by eliminating it at its source.
<br /> Consult the latest edition of Gemium reference 103 for detailed recommendations.Safety Stations~ Make emergency eyewash stations,
<br /> ufety/quick-dmmch showers,mad washing facilities available in work areas.Contaminated Equipment: Contact lenses pose a special
<br /> hazard;soft lenses may absorb irritants.and all lenses concentrate them.Do mor wear contact km=in any work area.Remove contami-
<br /> nated clothing and launder it before wearing it again;clean this material from shoes and equipment.Comments: Practice good personal '
<br /> hygiene;always wash thoroughly afar using this material and before eating,drinking,smoking,using the toilet,or applying cosmetics.
<br /> Keep it off your clothing and equipment.Avoid u=ferriag it from your hands to your mouth while eating,drinking,or smoking•Do era
<br /> M drink.or smoke in any work ane.Do not inhale ethyl benzene vapor.
<br /> SECTION 9. SPECIAL PRECAUTIONS AND COMMENTS
<br /> Storage/Segregation: Ston.ethyl benzene is a 10M4 Containers in a cool,dry,well-ventastcd area away from sources of ignition sad
<br /> strong oxidizers.Protect containers from physical damage.Special Handling/Storage: O uuide,isoWed,detached.or remote storage is
<br /> recommended for large quantities of ethyl benzene.Isolate bulk storage areas from scute fire hazards-Engineering Controlx Make sure
<br /> all engineering tystems(production,t ansporudon)are of maximum explosion-proof design.To prevent static sparks,ekctrically ground
<br /> and bond all containers,pipelines,etc,used in shiPpm&transferring,fig'production,and sampling operations.Other. Use safety
<br /> cans for transferring small amounts of ethyl benzene.
<br /> Transportation Data(49 CFR 172.101.2)
<br /> DOT Shipping Tame: Ethyl Bt:trzene
<br /> DOT Hazard Class: Flammable liquid
<br /> ID No.UN 1175
<br /> DOT Label: Flammable liquid
<br /> DOT Packaging Exceptions: 49 CFR 173.119
<br /> DOT Packaging Requirements: 49 CFR 173.119
<br /> LMO Shipping Name: Ethylbeazene
<br /> IMO Hazard Class: 32
<br /> DIO Label• Flammable liquid
<br /> D11DG Packaging Group: II
<br /> References: 1.26,38,94-94. 100. 116. 117, 120, 122.
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