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`"owl <br /> MATERIAL SAFETY DATA SHEET NG• 467 <br /> 13ENIUM PUBLISHING CORPORATION AUTOMOTIVE <br /> 1145 CATALYN STREET GASOLINE, LEAD-FREE <br /> SCHENECTADY. NY 12303-1036 USA <br /> (510)377.0055 emum/YaUWNgCpM, <br /> Date October 1981 <br /> SECTION 1 . MATERIAL IDENTIFICATION <br /> TERLAL NAME. AUTOMOTIVE GASOLINE, LEAD-FREE <br /> DESCRIPTION: A volatile blend of hydrocarbons for automotive fuel <br /> OTHER DESIGNATIONS: Petrol, CAS lOOS 006 619, ASTM D439 <br /> MANUFACTURER: Available from several suppliers. <br /> SECTION 11 . INGREDIENTS AND HAZARDS z I4AZARD DATA <br /> Gasoline 100 -hr TWA 330 ppm or <br /> A hydrocarbon blend that can include normal and branche 900 mg/m <br /> chain alkanes, cycloalkanes, alkenes, aromatics and <br /> other additives.** (Lead max 0.013 g/L, phosphorus Man <br /> max 0.0013 g/L, sulfur max 0.10 wt%. May contain ye: 500 ppm/1H <br /> benzene, <52; see ASTM D3606). Moderate irritation <br /> *ACGIH 1981 TLV (Intended Changes List). See also <br /> Am. Ind. Hyg. A. 39 110-117 (1978) Inhalation: <br /> **The composition of fuel is varied with altitude and TCLo 900 ppm/1H <br /> seasonal requirements for a locality. The blend must TFX:CNS <br /> meet antiknock requirements. (Antiknock Index min 85, <br /> ASTM D439.) <br /> _K SECTION II1 . PHYSICAL DATA <br /> Distillation at 1 atm, Initial, deg C >39 Specific gravity, 60/60 F - 0.72-0.76 <br /> 502 distilled - 77-121 Melting point, deg C ------ -90.5-95.4 <br /> End point ---- <240 Evaporation rate — -- N/A <br /> Vapor density (Air-1) ----------- 3.0-4.0 <br /> Solubility in water ----- --- Insoluble <br /> Appearance and Odor: A clear, mobile liquid with a characteristic odor which can be <br /> recognized at about 10 ppm in air. (Gasoline may be colored with dye.) <br /> SECTION IV. FIRE AND EXPLOSION DATA LOWER UPPER <br /> Flash Point and Method I Autoi nation Tem 'Flammability Limits In Air <br /> -45 F - by volume 1.4 7.6 <br /> Extinguishing Media: Dry chemical, carbon dioxide, alcohol foam. Use of water may be <br /> ineffective to extinguish fire, but use water spray for cooling fire-exposed drums <br /> and tanks to prevent pressure rupture. It is a dangerous fire and explosion hazard <br /> when exposed to heat and flames. Vapors can flow along surfaces, reach distant igni- <br /> tion sources and flash back. Can react violently with oxidizing agents. <br /> Firefighters should wear self-contained breathing apparatus and full protective clothin . <br /> SECTION V. REACTIVITY DATA <br /> This is a stable material in closed containers at room temperature under normal storage <br /> and handling conditions. It does not undergo hazardous polymerization. <br /> This is an OSHA Class IA flammable liquid. A mixture of gasoline vapors and air can be <br /> explosive. It is incompatible with oxidizing agents. <br /> Thermal-oxidative degradation can yield carbon monoxide and partially oxidized <br /> hydrocarbons. <br /> w�;�,.',„.r",,,� .',.,.6w. GENI UM PUBLISHING <br />