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I <br /> or fall over with the slightest wind. Also, crop maturity is delayed and the <br /> plants are more susceptible to diseases and insect pests. An oversupply of <br /> nitrogen may adversely affect grain and fruit quality, as in barley, apples, <br /> and peaches. It also adversely affects sugar levels in sugar cane or sugar beets. <br /> ejected to It must not be inferred, however, that all plants are detrimentally affected <br /> ery good by large amounts of nitrogen. Many crops, such as the grasses and vegetables, <br /> is small, ; should have plenty of this element for their best and most normal development. <br /> large. At Detrimental effects are not to be expected with such crops unless exceedingly <br /> is lost in large quantities of nitrogen are applied. Nitrogenous fertilizers may be used <br /> it is lost freely in such cases, the cost of the materials in respect to the value of the <br /> unavail crop increases being the major consideration. <br /> y marked <br />!s occurs. , <br /> roots soil 9.2 Forms of Soil Nitrogen <br /> e. Others, <br />>r through. There are three major forms of nitrogen in mineral soils: (a) organic nitrogen <br />-ombined associated with the soil humus, (b) ammonium nitrogen fixed by certain clay <br /> at should minerals, and (c) soluble inorganic ammonium and nitrate compounds. I <br /> Most of the nitrogen in surface soils is associated with the organic matter. <br /> In this form it is protected from rapid microbial release, only 2-3% a year <br /> being mineralized under normal conditions. About half the organic nitrogen <br /> is in the form of amino compounds. The form of the remainder is uncertain. <br /> Some of the clay minerals (e.g., vermiculites and some smectites) have <br />'mpoun the ability to fix ammonium nitrogen between their crystal units. The amount I <br /> enzyme fixed varies depending on the nature and amount of clay present. Up to 8% <br /> I w' of the total nitrogen in surface soils and 40% of that in subsoils may be in ( I' <br /> ell nuc <br /> e ' <br /> the "clay-fixed" form. In most cases, however, both these figures would be <br /> ntial f considerably lower. Even so, the nitrogen so fixed is only slowly available <br /> develo to plants and microorganisms. I <br /> s usu <br /> kThe amount of nitrogen in the form of soluble ammonium and nitrate com- I I <br /> est an pounds is seldom more than 1-2% of the total present, except where large <br /> i and ' i, applications of inorganic nitrogen fertilizers have been made. This is fortunate f <br /> fumpn I�II <br /> since inorganic nitrogen is subject to loss from soils by leaching and volatiliza- <br /> pho tion. Only enough is needed to supply the daily requirements of the growing I� <br />�spho � <br /> ccul <br /> crops. <br /> •I <br /> po, 8.3 The Nitrogen Cycle' <br /> and' <br /> ch In all soils the considerable intake and loss of nitrogen in the course of a <br /> year are accompanied by many complex transformations. Some of these <br /> changes may be controlled more or less by man, whereas others are beyond <br /> re <br /> ho <br /> tey) <br /> For this and subsequent sections on nitrogen, the reader is referred to the monograph edited <br /> by Stevenson (1982). <br /> 9.3 The Nitrogen Cycle 2$5 <br /> a <br />