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• <br /> Ms. Penny Fottrell GEOMATRU< <br /> Chevron Environmental Management Company <br /> September 12, 2002 <br /> Page 2 <br /> Soil sample analytical results are summarized in Table 1 and presented on Figure 3. Total extract- <br /> able petroleum hydrocarbons quantified as crude oil (TPHc)were detected at concentrations <br /> varying from 480 to 4,500 milligrams per kilogram(mg/kg) in samples collected from borings <br /> GP 96, GP 97,GP 117, and GP 120,where affected soil was observed. Grey green staining and a <br /> slight odor was reported between 18.5 and 20 feet bgs (bottom of boring) in boring GP 173,how- <br /> ever, TPHc was not detected in the sample analyzed from this interval. TPHc was not detected in <br /> samples from the 11 remaining borings within Site 3, confirming the observations made during <br /> drilling. <br /> Samples from the four borings where TPHc had been detected(GP 96, GP 97, GP 117, and <br /> GP 120) also were analyzed for benzene,toluene, ethylbenzene, and xylenes (BTEX)and <br /> polynuclear aromatic hydrocarbons (PAHs). BTEX were not detected in any of the samples <br /> analyzed. However, several PAHs were detected in the samples at concentrations up to 0.7 <br /> mg/kg. <br /> Groundwater was encountered at depths ranging from 5.5 to 13.5 feet bgs in borings in this area. <br /> Grab groundwater samples were collected and analyzed from borings GP 96, GP 97, GP 117 <br /> (drilled within affected soil),and GP 138 (where no affected soil was observed) with a bailer from <br /> the open borehole. Grab groundwater samples were analyzed for BTEX, TPHg, TPHd, and <br /> PAHS; results are summarized in Table 2 and presented on Figure 4. No constituents were <br /> detected above laboratory reporting limits in the sample collected from GP 138. Separate phase <br /> petroleum hydrocarbons were observed in the groundwater samples collected from borings GP 96, <br /> GP 97, and GP 117. Total extractable petroleum hydrocarbons quantified as diesel(TPHd)were <br /> detected in samples from these borings at concentrations ranging from 20,000 to 310,000 micro- <br /> grams per liter(µg/1). TPHg were also detected in the samples collected from these borings at <br /> concentrations ranging from 43,000 µg/1 and 110,000µg/1. These TPH results are due to the <br /> presence of non-dissolved petroleum in the samples (either petroleum globules or petroleum <br /> adhered to soil particles) and do not represent dissolved concentrations. Benzene and toluene <br /> were detected in the sample collected from GP 117 at 2.0 and 1.2 µg/1,respectively. PAHs were <br /> detected in all three samples at concentrations up to 110 µg/l (fluorene). <br /> DATA NEEDS <br /> Existing data were reviewed and evaluated with respect to the Consistent Technical Approach <br /> (CTA)l that is typically applied at ChevronTexaco's historic pipeline sites. Based on this review, <br /> additional information is needed to better assess site conditions and evaluate potential risks to <br /> human health from petroleum.constituents present in soil and groundwater. The major compo- <br /> nents of the CTA and the data needed to address them are summarized below. <br /> • Delineation of the Vertical Extent ofAffected Soil-The vertical extent of petroleum hydro- <br /> carbons in soil was visually delineated at boring GP96 and GP 120. GP 96 was advanced to a <br /> Geomatrix Consultants,Inc.,2001,Draft Revised Technical Approach to Site Evaluation and Decision- <br /> Making,Old Valley Pipeline Sites Central Valley Region, October;and Geomatrix Consultants,Inc., 1997, <br /> Technical Approach to Site Evaluation and Decision-Making, Old Valley Pipeline Sites—Central Valley <br /> Region,March 19. <br />