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I"001 <br /> PRIMA Environmental, Inc. channs/2 of <br /> Confidential December 9,2007 <br /> Secor—Circle K rfp <br /> 1503+C5H120 5CO2+ 1502+6H2O Eqn. 4 <br /> MTBE <br /> 1203+C4Ht00 4CO2+ 1202+5H2O Eqn. 5 <br /> TB. <br /> Table 1. Ozone Stoichiometry <br /> Compound e Ozone!e contaminant <br /> Benzene 9.2 <br /> Toluene 9.5 <br /> Eth Ibenzene 9.5 <br /> Xylenes 9.5 <br /> MTBE 8.2 <br /> TBA 8.5 <br /> Because ozone is a gas,sparging with ozone could result in removal of contaminants by <br /> stripping rather than oxidation, especially under laboratory conditions. Lab testing will, <br /> therefore, address contaminant destruction versus volatilization. <br /> As with all strong oxidants, ozone is a non-selective oxidizing agent and may react with <br /> soil and water constituents other than the target compounds. The most likely potential <br /> effects of ozone treatment include oxidation and precipitation of dissolved iron, oxidation <br /> and dissolution of manganese oxides, oxidation of naturally-occurring bromide to <br /> bromate, and oxidation of soil chromium to hexavalent chromium, Cr(VI). The <br /> magnitude and duration of these changes is site specific and may or may not be of <br /> significance at this site. <br /> APPROACH <br /> Batch tests will be conducted to evaluate ozone. Specific goals are: <br /> • measure the ozone demand of soil and groundwater <br /> • evaluate COC removal and assess destruction versus volatilization <br /> • evaluate the effect of ozone treatment on secondary water quality parameters <br /> • if necessary, assess the potential for natural attenuation of Cr(VI) <br /> Specific tests to achieve these goals are presented in the Scope of Work. PRIMA <br /> Environmental will evaluate the effectiveness of each oxidant based on the results of the <br /> bench tests and will present findings in a report to SECOR. The report will include <br /> results as well as observations and discussion. However, it is the responsibility of <br /> SECOR to review the report and use its knowledge and expertise to determine whether <br /> ozone should be applied at the site. <br />