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DRAFT <br /> . IIAZARD EVALUATION <br /> TLV IDLH LEL <br /> Parameter (ppm) (ppm) (%) HEALTH <br /> gasoline 300 in air ND 14 eyes, skin,resp sys,CNS, liver,kidneys <br /> benzene 10 in air 500 12 eyes, skin,resp sys,blood, CNS,bone marrow <br /> toluene 100 in air 500 11 eyes, skin,resp sys, CNS, liver,kidneys <br /> ethylbenzene 100 in air 800 08 eyes, skin,resp sys,CNS <br /> xylenes 100 in air 900 0 9 - 1 1 eyes, skin,resp sys, CNS,GI tract, liver,kidneys <br /> MtBE/oxygenates 100 in air N/A LFL 2 5 as above <br /> SPECIAL PRECAUTIONS <br /> Remove PPE when wet or contaminated, prevent eye or skin contact, recommend access to eyewash <br /> and/or quick drench facilities Respiratory protection not normally needed, ensure good ventilation If <br /> breathing stops as result of sever inhalation, provide mouth-to-mouth cautiously using protection <br /> FIRST AID <br /> Contact(Skin and eyes) Remove contact lenses, irrigate eyes/flush skin with cold water immediately <br /> Inhalation Move to fresh air immediately, provide mouth-to-mouth resuscitation if breathing stops <br /> Ingestion Immediate medical attention required, drink several glasses water/milk, induce vomiting <br /> Other <br /> IV. PERSONAL PROTECTIVE EQUIPMENT <br /> Minimum personal protective equipment, check all Wheable items <br /> ® Hard-hat Level of personal protection <br /> ® Safety glasses/goggles/face shield <br /> ® Steel-toed/shank shoes or boots ❑ A <br /> ® Clothing protection/gloves ❑ B <br /> ® Hearing protection ❑ C <br /> ❑ Negative-pressure respirator ® D <br /> ❑ Safety vest <br /> ❑ Other(specify) <br /> SURVEILLANCE EQUIPMENT AND MATERIALS <br /> Instrument Action Level <br /> HNU PID Work in breathing zone will be suspended when <br /> hydrocarbon levels reach 25 ppm for 5 minutes <br /> SSP 911-011 lA <br />