ARCHIVED REPORTS XR0000638 - Laserfiche WebLink

Home Browse Search

4�... •ti-�. *+I.W,- ... ��- _,.., T a4 .. Jw- � ,4 �, s„!'w'�'.� -r^w�r�. r�� i�- �.-�++�+� �� 1�^+�� -�.�s__ PAGE: 1 Oft 12lA2f92 ACCT 241572 6] h OATEI 12/02/!2 ]fipift� d#9 391i4]90 CAT NAT A4524 PO NSR: N/AACCP: 241572-01 PACE: 2 / ]iSEXt Ij4923313919G, CAT MOI .11;724 PO NBR: N/A •+METHANOL•' DANGEROUS FIRE HAZARD WHEN EXPOSED OSED TO HEAT, FLA +•METHANOL+• VAPORS ARE HEAVIER THAN AIR AND MID R OXIDIZERS. MATERIAL SAFETY DATA SHEET OF IGNITION AND FLASH BACK. MAY TRAVEL A CONSIDERABLE DISTANCE _________ -" VAPOR-AIR MIXTURES ARE EXPLOSIVE.FIS70 A SOURCE EMERGENCY NUMBER: (201) 796-7100 CHEMICAL DIVISION CHEMTREC ASSISTANCE (600)424-9300 F1�45H POINT: 52 F ITT C)(CCJ UPPER EXPLOSIVE LIMIT: 36.0, (OWER EXPLOSIVE LIMIT:8.0% AUTOIGNITION TEMP.: 725 F(385 C} T REAGENT LANE , (20111-AWN NJ 796-7 100 07410 FLAMMABILITY CLAS510$MA): IB THIS INFORMATION IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST FIREFIGHTING MEDIA: INpORMATION CURRENTLY AVAILABLE TO US. HOWEVER.WE MAKE NO WARRANTY Of DRY SUCH INFORMAT OA ANY N AND WEASSUER ME LIABILITYERESULTINGLFROM IIWITH TS USE. F USERS 990 EMERGENCY RESPNONSE GUiDEB OXIDE OK DOT P OR ALCOHOL- FOAM SHOULD MAKE rH THEIR PARTICULAR STIGATIONS TO PURPOSES. THE SUITABILITY OF THE FOR LARGER FIRES, USE WATER SPRAY, FDG OR ALCOHOL-q£SIStq 11990 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.5). NT FOAM -- ---------------- FIREFIGHTING: "- SUBSTANCE IDENTIFICATION MOV$CONTAINER FROM FIRE ARE4 IF CAS-NUMBEA 67-56-1 SIDES OF CQNTAINERSPTOHAT ARE NOT SCATCTER THE 1M TIER1ALrgPpLY DIKE F CONTROL SUBSTANCE- ++METHANOL•• STAY AWAY FROM ENDS OF TAMK5.WI7NpRAW I�h4MEDlgT 3TG WATER FROM VENTING 5AFETY DEVICE OR ANY OISCOLOAATION OF 7 NK DUEF OOFIIRE ISOLATE TO IS OUT TRAO£ NAMES/SYNONYMS' FOR 1/2 MILE IN RLL DIRECTION$IF TANK RAIL CAR OA TANK TRUCK SONVpL1yFDSOUND METHYL ALCOHOL•WOOL)ALCOHOL' METHYL HYDROXIDE CARBINOL: FIRE 11990 EMERGENCY RESPONSE GUFOEE(OOK. DOT P 5800.5. GUrOE pgGE FIR MONOHYDROXYRTHANE-WOOD 50IRIT:WOOD NAPHTHA- METHYLOL: COLONIAL SPIRIT; IN COLOMBIAN SPIRIT; PYMETH IC SPIRIT C49092 RTIC IRI Ce5NCRA U15 SOLUTION; EXTINGUISH ONLY IF FLOW CAN BE STOPPED USE WATER IN PLODDING AMOUNTS A$ FpG 281. STANDARD WATER IN METHANOL STC 4909230' UN 1230: flCRA U154; SOLID STREAMS MAY NOT BE EFFECTIVE.CObI CONTAINERS W17H FIND AMO QUANTITIES A154:A451i A936: A408:A947; A935: BP1105; A4f2; A411:A433P:SVV2;: pF WATER, APPLY FROM A$ FAR A DISTANCE AS POSSIBLE.AVOID BREATHING TOXIC SC95;A452 K; A408SK;A412P: A434: A412SK: A450; A433S: CH40. ACC14280 VAPOR$, KEEP UPWIND. CHEMICAL FAMILY: ------------------ HYDROXYL,ALIPHATIC TRANSPORTATION DATA F ____ MOLECULAR FORMULA:C-H3-0-H DEPARTMENT OF TRANSPORTATION HAZARD CLASSIFICATION 49-CfA 172 301 FLAMMABLE LIQUID MOLECULAR WEIGHT:32,01 CERCLA RATINGS [SCALE 0-3): HEALTH-3 FIRE•3 REACTIVITY•0 PERSISTENCEFO DEPARTMENT OF TRANSPORTATION LABELING REQUIREMENTS 49 C(A IT1 101 AND CA SUBPART E: NFPA RATINGS_ IS LE 0-1): HEALTH.)-FIRE_3 REACTIVITY-0 FLAMMABLE LIQUID COMPONENTS AND CONTAMINANTS DEPARTMENT OF TRANSPORTATION PACKAGING REQUIREMENTS:49-CFA 173.119 EXCEPTIONS:49-CFR 173.11& COMPONENT: METHYL ALCOHOL (METHANOL} PERCENT 100 FINAL RULE ON HAZARDOUS MATERIALS REGULATIONS SHMR, 49 CFR PARTS 171-1801. CAST 67-56-1 DOCKET NUMBERS HM-181, HM-I&IA, HM-1838, 14M-MC, HM-1610 AN OTHER CONTAMINANTS: NONE EFFECTIVE DATE OCTOBER 1 1991.HOWEVER, COMPLIANCE WITH THE R D HM-204 AUTHORIZED ON AND AFTER JANUARY 1, 1991. 155 FR 52402, 12/21/g0j EGULATIONS IS EXPOSURE LIMITQS: F EFFECTIVE DATE FOR HAfARD COMMUNICATION REQUIREMENTS IS EXTENDED TO MjpQ ppTA4262 MG/M3T OSHAHANO6A{SKIN:2S0 PAM 1326 MG/M3 OSHA STEL EXCEPT FOR EXPLOSIVES INHALATION HAZARDS. AND INFECTIOUS SUBSTANCES. THE 200 PPM 1262 MG/M3 ACGIH TWA ISKI�1: 250 PPM 328 MG/M�1 ACGIH STEL OCTOBER I, 1903. (58 FR 47158.09/TB/91) 200 PPM 262 MGlM3 NIOSH RECOMMENDED TWA SKIN): 250 PPM 328 M.,M3 NIOSH RECOMMENDED STEL U-S. DEPARTMENT OF TRANSPORTATION SHIPPING NAME-10 NUMBER. 4 200 PPM 262 MGlM3 DFG MAX TWA[SKIN); METHYL ALCOHOL-UN 1230 400 PPM 524 MGlM3 DFG MAK 30 MINUTE PEAK, AVERAGE VALUE. 4TIMES/SHIFT 9 CFR 172.101 MEASUREMENT METHOD: SILICA GEL TUBE;WATER;GAS CHROMATOGRAPHY WITH FLAME U-S.DEPARTMENT OF TRANSPORTATION HAZARD CLASS OR DIVISION, 4 3 -FLAMMABLE LIQUID g CFR 172 101: I' iDNIZATIpN DETECTION: {NIOSH VOL, lu 4t 2004. METHANOL(, ` U.S.DEPARTMENT OF TRANSPORTATION PACKING GROUP, 49 CFR 172.101 5000 POUNDS CERCLA SECTION 103 REPORTABLE QUANTITY . PG II SUBJECT TO SARA SECTION 313 ANNUAL TOXIC CHEMICAL RELEASE REPORTING U.S.DEPARTMENT OF TRANSPORTATION LABELING REQUIREMENTS. 43 CFR !72.101 'I. ! ++OSHA LIMITS ADOPTED JANUARY 19. 1989 ARE SUBJECT TO THE DECISION OF THE AND SUBPART E 11TH CIRCUIT COURT OF APPEALS{AFL-CIO V.OSHA)AS OF JULY 7. 1992•• FLAMMABLE LIQUID, POISON U S.DEPARTMENT OF TRANSPORTATION PACKAGING AUTHORIZATIONS- , _______ ----------------------------- PHYSICAL DATA EXCEPTIONS: NONE NOWBULK PACKAGING:49 CFR 173.202 OESCRIPTION:CLEAR, COLORLESS LIQUID WITH A CHARACTERISTIC ALCOHOLIC ODOR. BULK PACKAGING:40 CFR 373.243 I BOILING POINT: 149 F 165 C) MELTING POINT: -137 F(-94 C) U.S, DEPARTMENT OF TRANSPORTATION QUANTITY LIMITATIONS 49 CFR 172.101 :97.25 MMHG(P 20 C PASSENGER AIRCRAFT OR RAILCAR; 1 L SPECIFIC GRAVITY:0,7014 VAPOR PRESSURE CARGO AIRCRAFT ONLY:80 L EVAPORATION RATE: (BUTYL ACETATE=1)4.6 SOLUBILITY IN WATER: VERY SOLUBLE -----. -•----•---- I ODOR THRESHOLD: 100 PPM VAPOR DENSITY: 1.11 TOXICITY ---------'------�------ -.- METHYL ALCOHOL ++METHANOL: SOLVENT SOLUBILITY:ETHER, BENZENE,ALCOHOL. ACETONE. CHLOROFORM. ETHANOL IRRITATION DATA, 20 MG/24 HOURS MODERATE; 100 MG/24 HOURS EYSR BRITMODIT ERAT AT{ 40 MG EYE-RABBIT VISCOSITY:0 59 CPS @ 20 C TOXICITY DATA; 86.000 MG/M3 INHALATION-HUMAN TCL&300 PPM INHALATION-HUMAN TCLO;84.000 PPMl4 HOURS INHALATION-RAT LC50; 1000 PPM INHALATION-MONKEY ______________ -------- - - - - -....- LCLO: SO GM/M31Z HOURS INHALATION-MOUSE LCLO;44()DO FIRE AND EXPLOSION DATA INHALATION-CAT LCLO; 15.800 MG/KG SKIN-RABBIT LD50MG/M3/B HpIIRS ;J93 MG/KG SKIN-MONKEY LOLO;428 MG/KG pRAI•HLIMAN LDID, N2 M I FIRE AND EXPLOSION HAZARD: ORAL-MAN 1:040: 3429 Mr�KG ORAL-MAN Iota:G4/XG OMIK61 OMAN LO%4 6422 M 1 GM�K�ORAL-wOMnN T010G FAG/KG OMirb