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0 • <br />facilitate removal by "stripping" of the volatile contaminants out of the groundwater. In <br />addition, in biosparging, pure oxygen may be used instead of air. <br />To apply biosparging at this site, air or pure oxygen would be injected under pressure into the <br />groundwater in typically one -inch diameter wells or sparge points. As in air sparging, an air <br />compressor would be required to provide the pressurized air but at a lower injection rate. <br />Injection might also be implemented on a timer; the timed cycle would be determined based on <br />results of respiration tests. Such tests would be conducted onsite as part of a field pilot test for <br />the design of the full-scale treatment system. <br />One advantage of biosparging over air sparging/SVE is that neither vapor emission control nor <br />separated liquid handling would be needed. In addition to the sparge depth (anticipated to be <br />more than 30 feet), the generally low air or oxygen injection rate would typically not result in <br />driving the volatile contaminants from the groundwater into the vadose zone, as would be the <br />case in air sparging; therefore, no soil vapor capture would be necessary. As such, no treatment <br />or control of vapor emission and separated liquid would be required. <br />Addition of nutrient, such as nitrate and phosphate, may be needed if oxygen alone would not be <br />sufficient to sustain microbial biodegradation of the hydrocarbons. The requirement for nutrient <br />supplement would be determined based on groundwater quality data from baseline and during <br />treatment. <br />4.3.1 Technical Effectiveness <br />As the organic contaminants are amenable to aerobic biodegradation, biosparging has the <br />capability of reducing the bulk mass of TPH-g and BTEX in the groundwater. The current onsite <br />groundwater conditions indicate low oxygen content (less than 1 milligram per liter [mg/L]) <br />within the contaminant plume; introducing oxygen via biosparging should stimulate microbial <br />biodegradation of the organics. <br />As in the previous two alternatives, the presence of silty and clayey soils would limit the <br />effectiveness of biosparging to achieve a complete removal of the hydrocarbons from the <br />subsurface. It is expected that this process would take as much time as in the other two <br />alternatives. The overall effectiveness of this alternative is therefore considered moderate. <br />4.3.2 Implementability <br />Biosparging is easy to implement. Biosparge equipment is commercially available and simple to <br />install. Because a biosparge system does not produce contaminated soil vapor or liquid, no <br />additional aboveground treatment will be required. As such, permitting for air emissions or <br />liquid discharge to POTW will not be necessary. If oxygen were to be used, a building permit <br />for housing an oxygen generator as hazardous material might be required. Such a requirement <br />FS -Onsite Petroleum Hydrocarbon Remediation.doc 4-6 Shaw Environmental, Inc. <br />