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To apply ISCO, ozone would be injected in permanent wells or temporary injection points that <br />are strategically placed across the treatment area. The injection points would be at the depth <br />where the bulk hydrocarbon mass is present. A skid -mounted process equipment would be used <br />to inject the oxidant. Water quality data would be collected during injection from nearby <br />monitoring wells or temporary monitoring points if no monitoring wells are available. TPH-g <br />and BTEX concentrations would be monitored periodically from the monitoring wells after the <br />injection to assess treatment progress. Typical monitoring frequencies would be from weekly to <br />monthly after each injection event. <br />A field pilot test would be required to determine the oxidant injection requirements, the number <br />of injection points and injection events, and the time required between injection events. This <br />information would also assist in developing a treatment performance monitoring plan. <br />4.4.1 Technical Effectiveness <br />' ISCO is capable of reducing the bulk mass of TPH-g and BTEX in groundwater at the site. <br />Chemical oxidation is generally instantaneous and requires less time to achieve mass reduction <br />and meet the target treatment goals than those involving primarily physical or biological removal <br />' processes. Its effectiveness will still be somewhat limited, however, when applied to silty and <br />clayey soils due to the relatively low permeability of the soils that will limit the amount of <br />contact the oxidant makes with the hydrocarbons. Usually, a greater number of injection points <br />will be required in the silty/clayey soil stratum than in sandy soil to achieve the equivalent level <br />of mass removal by chemical oxidation. Overall, the technical effectiveness of ISCO is <br />' considered moderate to high in meeting the treatment objective for the site. <br />t 4.4.2 Implementability <br />ISCO is expected to be easily implementable at the site. Ozone generators can be purchased <br />from commercial suppliers to produce ozone onsite for injection via installed process piping. <br />' Because neither offgas emissions nor waste liquid will be generated, no aboveground handling <br />and treatment of the offgas and waste liquid streams will be required, thus facilitating the ease of <br />' implementation. <br />However, a permit might still be required from SJUAPCD for potential fugitive ozone emissions. <br />Additional monitoring for ozone release in and around the treatment area might also be needed. <br />A field pilot test will still be required as previously stated for full-scale treatment design, <br />extending the timetable for the implementation. Overall, the implementability of this alternative <br />is considered moderate. <br />4.4.3 Cost <br />Major cost elements include those associated with conducting a field pilot test, procuring the <br />' oxidant generation equipment, installing injection piping and wells/points, and monitoring <br />I <br />FS Onsite Petroleum Hydrocarbon Remediation.doc 4-8 Shaw Environmental, Inc. <br />