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Ms. Linda Turkatte <br /> December 14, 1995 <br /> Page 4 <br /> kt = In 0.0056, <br /> t = On 0.0056)/k. <br /> Substituting decay constant of -0.04 and -0.0035 produces t values of 130 days and 1,481 days (4.1 <br /> years). This suggests that benzene concentrations should have been reduced to below the laboratory <br /> detection limit of 0.005 since 1986 (more than 9.5 years, or 3,500 days). <br /> Similarly, groundwater contamination originally detected would be expected to fall below laboratory <br /> detection limits in 166 to 1,899 days (5.2 years). A review of historical groundwater analytical results <br /> indicate that dissolved concentrations of benzene decreased from 382 ppb on April 24, 1986 to <0.50 <br /> ppb on May 25, 1995, a period of 3,316 days. No benzene or other gasoline constituents were detected <br /> in downgradient wells MW2 or MW4 in two sampling rounds (May 1993 and May 1995). <br /> Conclusions <br /> Hendrix and Son Trucking, Inc. immediately discontinued operation and removed the underground tank <br /> and leaking line upon discovering a leak in 1986. A soil boring/monitoring well was installed directly <br /> over the location of the line leak. Analytical results of soil samples collected beneath the line leak <br /> indicated that gasoline constituents, including benzene, had impacted soil beneath the site to a limited <br /> extent, although no TPHG was detected in any soil samples. Benzene impaction was apparently limited <br /> to clay soils between approximately 18 and 50 feet below grade. Based on this observation it was <br /> estimated that approximately 115 cubic yards of soil had been impacted by an estimated 0.18 pounds <br /> of benzene. <br /> Since the source of the leak was immediately removed and well MWI. was placed directly over the <br /> location of the leak, we can assume that the documented concentration of benzene at 30 feet (0.89 ppm) <br /> was the maximum concentration in the soil. Based upon this maximum documented concentration of <br /> benzene in soil, the fact that the source of the leak had been removed, and estimated benzene <br /> degradation rates from numerous independent studies in the literature, it was calculated that the benzene <br /> in the soil would degrade to a level below standard laboratory detection limits in approximately 4.1 <br /> years. <br /> Making similar assumptions pertaining to groundwater, it was calculated that the benzene in the <br /> groundwater would degrade to a level below standard laboratory detection limits in approximately 5.2 <br /> years. Analytical results of groundwater samples collected from well MWI. over time and the absence <br /> of contaminants in downgradient wells tend to support the calculated degradation rates. <br /> groundze\hendriz\phs1295.jpl <br />