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Treadwell&Rollo <br /> A LANSAN COMPANY <br /> Request for Low-Threat Case Closure 6 June 2013 <br /> RWQCB case#391149 and#391162 Page 9 <br /> 420 and 423 N Madison Street <br /> Stockton,California <br /> Project:731589001 <br /> 420 N Madison Street <br /> The BioScreen model results(discussed above) provided estimates of the plume mass in groundwater <br /> (page 3 of Attachment 6). The estimated benzene mass with first-order degredation is 0.0103 kg. A <br /> conversion factor of 1.8% (typical fraction of benzene in TPHg) benzene in TPHg was used to extrapolate <br /> the mass of TPH in the plume based on the estimated mass of benzene (Heath et al., 1993). Estimating <br /> TPH mass based on a typical fraction of benzene results in a conservative value of TPH mass because the <br /> modeled benzene would extend farther than TPH in groundwater. The total TPH mass remaining in <br /> groundwater was estimated to be 1.3 lbs. This estimate is based on the benzene concentration in the <br /> excavation in June 2004,which is nine years ago and prior to the addition of ORCO to the groundwater at <br /> the site in April 2005; therefore,the TPH remaining in the groundwater is very likely less than this <br /> estimate. <br /> 423 N Madison Street <br /> The extent of TPH in groundwater at the 423 N Madison site was estimated based on groundwater <br /> monitoring and sampling results from 1999 through 2003 (Figure 9). The plume area was calculated to <br /> be approximately 2,670 ft2, the saturated thickness was assumed to be 20 feet, and effective porosity <br /> 0.25. The average total TPH concentration was taken as the sum of the detected TPHd and TPHmo <br /> concentrations at boring 15-B-8 in May 2000, 670 pg/L. <br /> The resulting total TPH mass was estimated to be 0.45 lbs. Because it has been 13 years since the <br /> sample that contained TPH was collected,the amount currently in groundwater at the Site is likely less <br /> than this estimation due to biodegradaton. <br /> CLOSURE REQUIREMENTS UNDER LOW-THREAT UST CASE CLOSURE POLICY <br /> On 6 November 2012 the California State Water Resources Control Board implemented the Low-Threat <br /> Underground Storage Tank Case Closure Policy(LTCP). The LTCP guidelines indicate that closure is <br /> appropriate for a site if the following can be demonstrated: <br /> • The unauthorized release is within the service area of a public water system (i.e.; <br /> untreated groundwater is not a municipal resource or the community relies on surface <br /> water imports); <br /> • The unauthorized release consists only of petroleum chemicals(including oxygenates); <br /> • The unauthorized release has been stopped; <br /> • Free product has been removed to the maximum extent practicable; <br /> • A conceptual site model has been developed; <br /> • Secondary source has been removed to the extent practicable; <br /> • Soil and groundwater have been tested for Methyl tert-butyl ether(MTBE), and results <br /> have been reported in accordance with Health and Safety Code Section 25296.15 <br />