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r „ <br /> G <br /> t <br /> 04 March 1996 <br /> I AGE-NC Project No 95-0144 <br /> Page 8 of 18 <br /> In thermal oxidation systems, hydrocarbons are destroyed by open-flame combustion Natural gas is <br /> commonly used as supplemental fuel, heating the extracted vapors to a combustion temperature of <br /> approximately 1400°F Relative to internal combustion systems, these systems may be slightly more <br /> expensive to purchase and install However, they can operate at higher air flow rates, and therefore <br /> remediate sites at a faster rate For this system to be effective, hydrocarbon concentrations should <br /> range from 5,000 ppmv to 30,000 ppmv They also operate at much lower noise levels than internal <br /> ' combustion systems <br /> Catalytic oxidation units provide another option for treating vadose-zone contamination, particularly <br /> after other extraction systems have reached their effective limits due to lowered hydrocarbon <br /> concentrations These systems operate at temperatures of apprommately 700°F, requiring less <br /> supplemental fuel than ether thermal oxidizers or internal combustion engines Other requirements <br /> and limitations are similar to those for internal-combustion and thermal oxidizer systems <br /> 1 <br /> 6 1 2 EFFECTIVE SOIL CONDITIONS <br /> Operation of the blower in a vapor extraction system creates a vacuum in the subsurface, inducing <br /> res aces Vapors move by convection toward the area of lowered air <br /> air flow through the soil pore p p , <br /> pressure (the extraction point) The efficiency of this pzocess is proportional to soil porosity and <br /> permeability Soil in the upper 18 feet at this site has a high clay content, making vapor extraction a <br /> more difficult However, soil below 18 feet and in the saturated zone consists of sands, where vapor <br /> extraction would have a greater effect Figures 4 and 5 are cross sections showing soil types at the <br /> site <br /> 1 6 1 3 MONITORING ACTIVITIES <br /> Monitoring ofvapor extraction systems involves weekly measurement of hydrocarbon concentrations <br /> In the vapor stream entering the destruction utiit (influent stream) and ex�t�ng the system (effluent <br /> stream) and periodic service and repair Systems can be equipped with automatic telecommunication <br /> system to ales t the opei ator of system malfunction,or failure Vapor samples should be collected <br /> monthly to-monitor the efficiency of the remediation program When the concentration of extracted <br /> vapors decreases and stabilizes after several months of operation, confirmatory borings are drilled to <br /> collect soil samples for quantitative analysis in the laboratory to document the status of the <br /> remediation effort <br /> 4 FEASIBILITY <br /> 61 w <br /> Generally, a vacuum of 0 10 inches of water is requij ed to successfully volatilize subsurface <br /> I <br />