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�y <br /> N0, <br /> 316 <br /> SECTION VI . HEALTH HAZARD INFORMATION TLV 10 ppm or 30 mg/r3 (skin) <br /> Excessive Inhalation or prolonged skin exposure maycauseheadache, weariness loss of <br /> appetite and lassitude with incipient blood effects including Ancreased cell counts, <br /> mild lymphotosis and eosinopenia, The mrst sign{ficant toxic effect of benzene is in- <br /> sidious and otter. irreversible injury to the blood forming tissue from chronic low <br /> i. level exposures. Development of leukemia may occur from chronic excessive exposure! <br /> i Eye contact yields irritation from- liquid or high vapor concentrations. Skin contact <br /> will also yield a defatting effect. Inhalation may result in collapse, bronchitis and <br /> pneumonia. <br /> FIRST AID: <br /> -`fie c�nta�ct: dash eyes well with water for 15 minutes. Contact physician. <br /> Skin contact: Wash skin well with water. Contaminated clothing should be ramoaed at <br /> once. <br /> E Inhalation: Remove victim to fresh air. Renore breathing if required and administer <br /> viryg¢n r labored breathing. Contact physician. <br /> E ; IR esrion. Give edible fats or oils to svaL.ow. Do not induce vomiting (aspiration <br /> hazard). Contact a physician immediately. _ <br /> SECTION VII. SPILL, LEAK, AND DISPOSAL PROCEDURES <br /> t <br /> if a significant spill occurs, notify safety personnel and evacuate the area. Remo-,e all <br /> ignition dcurces. Provide maximum, explosion-proof ventilation. Clean-up personnel <br /> } mint use approved self-contained breathing apparatus and other protective equipment to <br /> avoid contact wieh benzene. <br /> 1 ? Remove free liquid. Pick up residue with an inert absorbant, such as vermiculite, and <br /> placed in a closed metal container for disposal, using non-sparking tools. When neces- <br /> sary, benzene may be flushed away from a critical area with water, but flush to open <br /> I. are., only, not to sever or to strsace waters. <br /> DISPOSAL: Incinerate waste benzene or dispose of vis a licenaci, colvnnt disposal company <br /> Do not send (or allow run off) to the sewer! <br /> SECTION VIII . SPECIAL PROTEC'T'ION INFORMATION <br /> Provide general ventilation and local exhaust ventilation where benzene is used, handled, <br /> c.r stored to meet TLV requirements. Self-contained breathing apparatus should be avail <br /> �f able for ererb?ncies and non-rr;utine situations. Approved cartridge or canister type <br /> E.� respirators can be used far benzene, concentration: up to 50 ppm for short periods. A <br /> full facapiece is required abcve 10 ppm <br /> To prevent skin contact, gloves, aprons, boots, etc of neoprene or ocher benzene-•resiscan <br /> { materials sh.3uld be used. Chemical goggles or face shields should be used if splashing <br /> �.� is possible. Eyewash station shou:.d-be available wi.,tre splashing is probable. <br /> Y?'y <br /> I : SECTION IX, SPECIAL PRECAUTIONS AND COMMENTS <br /> Whenever possible, less toxic solvents should be substituted for benzene. Consult health <br /> and saf9ty services before b�mzene is .sed in plant operations. Do not breathe vapor_. <br /> Prevent contact with liquid. it is a_ suspected cancer cau4in_g agent: ' <br /> Keep away from heat, sources of IgnitiDn, and oxidizing dents. No smoking-'in areas or- <br /> use. <br /> fuse. Store and handle as OS`.i' Class IB liquid. <br /> Pre-placement detailed medical examination is needed. Workers +oho show heart, 1ting, <br /> kidney, liver. nervous disease, or any blood abnormality s'-.auld not be assigned. Peri- <br /> odic physical examinations and Brea monitoring is required. <br /> APPROVAI.S: MIS, ` ` <br /> DATA SOURCE(S) CODE: 2-4, 12, 21 Industrial Sygie <br /> purv.r r•.+ .b+. r .r..o �. •r'e.e.w.wm...w ...ur.. nd Safety <br /> P„e,�,....p..a.,••...a.,M..,pr....,,rw.rr.rs.ew.�......nw+.a,o <br /> Corporate !Seth 1 . <br /> .. tia..w..vv+Crt+.i+o�aw'P Gavruw.Wrc.rr.Y•r..,-rrzr.a.rr..or.ro - - <br /> �+s b rrm rcr.r v nr.a.r,n.r.w•o.c v-.cn k .00�.a+a w• <br /> Staff <br /> - <br /> "'@ GEIVIUM PUBLISHING <br /> i <br /> r <br />