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g. <br /> r <br /> No. 317 4l86 TOLUE <br /> SECI'IOti 6. HEALTH HALARD I.NFORti1ATI(_)_N 'fLV <br /> io[uC=_.is co 0 <br /> t G $1C:Cr=a carCL^.oS,ea a;L ,x I r,"AL,of tLUrW. � .apors of toiucae may cause <br /> irritzioa of the e}es,nose,upper respiratory tract,and skin. Ex,-,.)sree to 200 ppm for 8 hours causes wild fatigue. <br /> we.�eu,coafusioa,lamimatitm(Leafing)tai pars:thesia(a sensation of prickling,tinE'Lig,tr. aaping w the skin dust <br /> W rn objcrtivc sue). Exposure to high,-,coocc =i:as may rause hrxlache,nausm dizziw&l,dilated pupils,and <br /> euphoria,rad,in severe ries,cuy cause use m;�rioesnas and doth. 7YK liquid is irritating to ft cyea and skim. Contact <br /> with the eyes may cause U=ient cortical dam§;e,ct.aiuuctivau natation,aril burn-if not promptly removed Repeated <br /> and/or prolonged canres with the sk:m may cause drying and cracking. It tory lee etsorbed through the skin in toxic <br /> =mumts. Ingestion causes ime2tion of the gastrointestinal tract and may cxusc effects resembling those from inhalation of <br /> the vapor. Chrodic oettexposure 1.0 toluene may cause reversible kidney and livrr cajuty. 251 AIa EY E tf_ACT; <br /> Mediately flush eyes,including uadrs c}elide with running wait for+I last 15 n'inu,rs. Cert medical atrcakao it R7itatiog <br /> persism* SKIN CONTACT: immediately flush skin(for at less:IS minutes)K file removing contamirstttd shoes and <br /> rroshiog. Wash exposed ami with soup rod water. Get medical meati-,m if irritation persists or if a large an has beeff <br /> aim•' I?NHA_i8IIQN: Remove victim to fresh air. Restore fodror ssepport Srr .iag as rerqui;d Keep victim warm and <br /> quiet Get medial help•' ILISrEST14N. give vkdm 110 2 glasses of water co milk:Contact a poiram coonnl omrcr. Do not <br /> induce vomiting unless ditscted to do so.Taunsport victim to a mtdical faciEty.!'Weser give mything by mootdh to a person <br /> I who is unconscious or convulsing. •GET MEDICAL ASSISL%NCE.In plant,pmm odic,community. Get medical help <br /> lar feather treumcm,observation,and stun=after fust said,if imSicatel. <br /> SECTION 7. SPILL LEAK AND rISPOSAL PROCEDi1RES <br /> SPn.LJ F AICr AK: Notify srlcry pessomel of large spills or leaks. Remove all sow=of heat and igaidod, provide mAxi—of <br /> explosion-proof ventilation. Limit+ecus to spill caeca to rccusary pe soonel only. it-move 1ea16ng COWAimers to safe <br /> (r plate if feasible. Cleanup personutl need protection:gains;contact with liquid&W inhalation of vapor(sm zd-B). <br /> WASTE T YSMSal. Absorb small spills with paper towel or vermiculite.Ceotain large spills and wlleu if feasible,or <br /> absorb with vermiculite or sand. Place waste solvers or absorbent into closed coutaioers..'nr disposal using m8 nc mYirki4$ <br /> tools. Liquid can be flushed with water eco an open holding arra for handling. Do=,,lush ro sewer,watcrslsA or walcmly. <br /> i':` 5o1 $: Place is suitable container for disposal by a licensed contractor or bare in eco approved incinerator.Con.&cr <br /> reclati ring by distillation.Contaminated absorbent can be buried io a sanitary IWO. Follow all Federal,star;and local <br /> Mulations. TLm 96: 100.10 ppm. Tolueme is drsig zed as a hazardous waste by the EPA. 71s:EPA(ROU)IM No,is <br /> U220(40 CFR 261). The reportable quantity(RQ)is 1010 lbs14S4 kg(40 CFR 117). <br /> -�SECTION S. SPECIAL PROTEC110N INFORMATION77 <br /> 1 Provide&email and total cxlw st w nWu+�win meet TLV rcgWvew=a L Vcvalzuom fans ad o:hr.•elocasai service must be <br /> mntparkiaS and hire an explosiun-proof design. Exhaust hoods should hzve a face velocity of ss least 100 ft(lafrr feet <br /> ,act minute)aad be desidscd to capaue heati j vapor. For emergency or nooroutLic expasures where the TLV:may br excr sdcd, <br /> L. tats m o3zatic chemical cartridge respirator if conrentratian it Ices thm 200 ppm and as approved canister gas mask or$elf- <br /> ar_uined breathicx apprstus wit:fun rsccpicet if ttlnrxrtrarioa is gtuta rias 200,per. <br /> Safety glasses or splash goggIca slieuld be wort s all work aeas. Neoprene glovta,zim;.e,face shield.boot•,and other <br /> appropriate p-mective clothing ane equipment slioWd be available and wrom as oecessarj to prevent skim and eve CoctxL <br /> a Remowr.comwomated clothing immediately and do cot wear it "Wil it has boat pro sy laundered. <br /> Eye.eush stadons nd safety showet:should be readily ivai];ble in uz and b"ling areas. <br /> j Contact Ieases post.a special ha=d;soft lenses may absorb iratams and J1 leases concentrate them. <br /> SECTION w SPECIAL PRECAUTIONS �!iJi3 COMMENTS <br /> ..�... . <br /> i SifSRAGF C QRFQ TtON: Store in a coo6 dry,well-ventilated 3m&sway from n,.fdincB agtiLt,hear.sparks,orcpen flame <br /> Storage+teas must meet OS14A rcqulrt=ou for class III flammabi:Liquids.Use metal safety c=,fnr hurdling small amounts. <br /> Astec:containcts froth physical damage. Use only with tdcquate ventilation.Avoid c=nI wilt yret skim,orcloW.ing.Do <br /> t not inhale or ingest.Use cavtioo when ha dling this compound because ii cera be absorbed fhro3dti ii=skin it toxi, <br /> FS amounts. SPECIAL HAHQL14r;/S Q AGF• Ground and band metal containers and equipment ro wrveat static sparks when <br /> tusking transfers. Do mot sooke io use or storage ares,Use wcspatidap tools. EN,IWEERING 6oEza S, Preplacement <br /> sad paiOdk medical exams emphasizing the liver,kidneys,oa,rous system,iungs,harm and blood should be prow"ded. <br /> Wotkes exposed to cuncmtrationt greater thm the action lever(50 Apra)should be examioed at least once a yea.Use of <br /> alcohol tam aggravate she toxic effxts of tnlucoe. <br /> COML4L-1M: Emptied cootai[acs contain product residues, Ha dle accord nplyl <br /> Toluene is desjp=d as a J%&=dous substance by the FPA(40 CFR 116). DGT Classification:Flamm- le liquid. UN1294. <br /> Data Soumdsl Cote., 1-9. 12, I6.20,21.:4.26.34.81,82, CR <br /> 7udga>a=ainONfwabttur-mroemmoahawforpumh.di,woaa App,OsalS 4�eeiiorw, 1f/�D. <br /> Ntaee�rrtlr punlu.eft�e,pdotsb,ipy.Shneteia alnrwatt tra+onaNrw •--� - . <br /> IL"e®uraamu>aprcp= trachmromwon.�isth"IRMctcorp. Imdli ene/sare <br /> Corp.. <br /> Itst. yl; ty - <br /> E# was+caoxror suum oracnmformwootor.rpuc"era_yR�uufa <br /> rFina.apcapo+c+orrwcae.ar+mcaarQawe Medici[ Review <br /> fr PLv.m,.p� .p aftM" Copyr'tht V April 1. 1986 V — <br /> Aff wasW.re r A�saA <br /> MUM <br /> ix <br />