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maximum concentration the 1,951 gallons of wastewater released from the tank may have <br /> contained 1/50'h of a gallon of gasoline or slightly less than 1/4 of a cup of gasoline. <br /> Collection and Analysis of Water Samples from the Storm Drain System <br /> On February 27, 2003, David Threlfall, a WEGE geologist, met with Mr. Shawn Hart of <br /> the San Joaquin County Public Works Department and inspected the portion of the storm <br /> drain system that was impacted by unauthorized release on February 25, 2003. Mr. j <br /> Threlfall collected water samples from the small vaults beneath the storm drain gratings <br /> on the north side of Roselawn Avenue near the origin of the spill and at the intersection <br /> of Roselawn and Buena Vista Avenues. <br /> Mr. Threlfall and Mr. Hart also inspected the large storm drain vault and pumping facility <br /> located at the southern end of Buena Vista, approximately '/4 mile south of the <br /> intersection of Buena Vista and Roselawn Avenues. This vault receives all of the storm <br /> drain water from the aforementioned entry points. The water in the vault is eventually <br /> pumped into Smith Canal, which is located immediately to the south of the vault and <br /> associated pumping station. The vault and pumping facility are operated by Reclamation <br /> District #1614. According to Mr. Clyde James, Superintendent of District 1614, the <br /> pumping station is activated during storm events, and generally requires at least I/4 of an <br /> inch of precipitation in the area to initiate pumping. The water observed in the vault on <br /> February 27, 2003 was most likely an accumulation of water from the unauthorized <br /> release on February 25, 2003 mixed with a small amount of precipitation that occurred on <br /> February 26, 2003 along with the residual accumulation of wastewater since the last I <br /> pumping cycle. <br /> Mr. Threlfall collected one water sample from the vault and one sample of the sediment <br /> that had accumulated at the base of the concrete vault. The water samples were collected <br /> in 40-m1 VOA vials that were preserved with 0.5 ml HCL. The sediment sample was <br /> collected in a 2" X 6" aluminum sleeve. The ends of the sleeve were sealed with Teflon <br /> film and further protected with plastic caps. The soil and water samples were labeled and <br /> placed in an ice chest and maintained at 4 ° C. The samples were delivered to Kiff <br /> Analytical Laboratories with accompanying chain of custody documentation on February <br /> 28, 2003. Kiff Laboratories analyzed the three water samples and one sediment sample <br /> for concentrations of Total Petroleum Hydrocarbons as Gasoline (TPH-G), Benzene, <br /> Toluene, Ethylbenzene, and Xylenes (BTEX), and Methyl-tri- butyl ether (MTBE) using <br /> 826QB. Kiff's analytical report is included as Attachment A to this report. <br /> EPA method yt p P <br /> None of the three water samples or the one sediment sample showed concentrations of <br /> TPH-G above the laboratory detection limits of 50 ug/L (water samples) or 1.0 mg/kg <br /> (sediment sample). None of the water or sediment samples showed the gasoline <br /> constituents Benzene, Ethylbenzene, or Xylenes above the laboratory detection limits of <br /> 0.5 ug/L(water samples) or 0.005 mg/kg(sediment sample). Toluene was detected in the <br /> water sample from the storm drain vault in a concentration of 0.54 ug/L,just exceeding <br /> the laboratory detection limit of 0.5 ug/L. Toluene was also detected in the sediment <br /> sample from the storm vault in a concentration of 0.1 mg/kg. The sediment sample <br /> 3 <br /> i <br />