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detected in KF-2 was MTBE, at a concentration of 0.97 ppb. Lead was not detected in any of the <br /> wells. <br /> After rising during the fourth quarter of 2001, TPH-g and BTEX concentrations in KF-3 resumed <br /> their decline, and concentrations of all analytes were at least 50% lower than in the fourth quarter. <br /> The TPH-g concentration of 280 ppb and the benzene concentration of 39 ppb represent 99% <br /> declines from their peak concentrations in August of 1997. The MTBE concentration of 66 ppb <br /> suggests that the previously reported concentration of 140 ppb in November was excessive, due to <br /> the inaccuracy of EPA method 8020. Examination of Table 2 illustrates that two out of three times, <br /> analysis by method 8020 has yielded a result that is 2-4 times greater than that detected using the <br /> more accurate method 8260. <br /> Tertiary-amyl-methyl ether (TAME) and tertiary-butanol (TBA) were also detected in KF-3, at <br /> concentrations of 0.51 and 28 ppb. This is the first time that the laboratory has achieved reporting <br /> limits of 2 ppb and 100 ppb, respectively, and consequently this is the first time these hydrocarbons <br /> have been detected. <br /> After falling below the reporting limits in the fourth quarter of 2001, concentrations of some <br /> analytes increased in KF-5 during the first quarter of 2002. Gasoline was detected at 190 ppb, <br /> benzene was detected at 41 ppb, and xylene was detected at 0.65 ppb. In addition, MTBE, TBA, <br /> and 1,2-DCA were also detected at relatively low concentrations in this well. <br /> Benzene concentrations are plotted against time in Figure 5 for those wells in which it has been <br /> detected. The maximum concentration limit (MCL) for benzene (1 ppb) is also shown for reference. <br /> Concentrations in the three original. wells (KF-1, 2, and 3) were greater than 1,000 ppb when <br /> monitoring began in late 1994 and remained'high through 1997, but began falling in early 1998. <br /> This fall was coincident•with a rise in the water table (Table 1). Concentrations rose again in early <br /> 1999, but have since fallen in two of the three wells to below the reporting limit. During that time, <br /> the depth to groundwater oscillated between 6 and I1 feet below grade, and the decline in <br /> hydrocarbon concentrations did not correlate with the changes in water depth. <br /> 4.4 Hydrocarbon Plume Maps <br /> As requested by PHS/EHD, the February 2002 laboratory data from the Chevron site were obtained <br /> from Gettler-Ryan, and contour maps of TPH-g, total BTEX, and MTBE were constructed (Figures <br /> 6-8). The TPH-g and Total BTEX snaps depict two partially separated plumes, centered in the <br /> vicinity of Chevrons MW-1 and MW-4, with a less-contaminated area in the center of that site <br /> between these "hot spots". The plume around MW-1 is larger than that around MW-4, and extends <br /> east of the site under Franklin Street and encroaches on the southwestern corner of the Kwikee site. <br /> There is a strong eastward concentration gradient, and concentrations decrease rapidly east of MW_ <br /> 1, as illustrated in Figure 9. <br /> The map of MTBE is somewhat different. MTBE was not detected in MW-4 at the Chevron site, <br /> because interference from other hydrocarbons masked its presence and the detection limit was <br /> 5 <br />