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Regardless of the design of the sampling equipment, there are a number of important <br /> topics to address in order to obtain reliable soil vapor concentration data. These topics <br /> are discussed below. <br /> B. Field activities prior to sampling/documentation <br /> Written documentation of field conditions during sampling is recommended. This <br /> includes weather conditions (temperature, barometric pressure, wind direction and speed, <br /> humidity, degree of cloudiness); surface soil conditions (presence of standing water, wet <br /> soil, irrigation activities, etc.) and groundwater elevations. Do not perform soil vapor <br /> sampling during or immediately after a significant rain event (e.g., >_ 0.5 inch; California <br /> EPA, 2003) due to the reduced effective diffusion coefficient and decrease in relative <br /> vapor saturation in the unsaturated zone. Maintain detailed field records of all activities, <br /> conditions, and sampling processes, including names of field personnel, dates and times, <br /> etc. It is important to maintain consistency in sampling activities between sampling <br /> events (e.g., purging volume and purge rate, sampling volume, leak testing methods, <br /> equipment used). Carefully plan all sampling activities to maintain consistency between <br /> sampling events and to avoid errors that can affect soil vapor concentrations. <br /> C. Equilibration time <br /> The installation of soil vapor sampling probes can introduce oxygen into anaerobic <br /> portions of the vadose zone. An equilibration time is required to account for the effects <br /> of soil vapor probe installation; this allows for equilibration of vapor component <br /> concentrations between the probe and subsurface. Soil vapor samples should not be <br /> obtained until after the equilibration time is reached. Probes installed using augers <br /> should be allowed at least 48 hours of equilibration time while probes installed using <br /> direct-push techniques should be allowed at least 30 minutes of equilibration time <br /> (California EPA,2003). <br /> D. Purging <br /> Prior to collecting a soil vapor sample, the stagnant air in the sampling tubes must be <br /> removed. This ensures that the soil vapor sample that is collected is representative of <br /> actual soil vapor concentrations. Field notes containing information about the above- <br /> ground sampling equipment and below-ground tubing length and inner diameter should <br /> be used to calculate the "dead volume" to be purged. The volume of the probe and <br /> borehole sand pack is not included in the calculation as it is assumed that the soil vapor <br /> concentrations in the probe and sand pack are equilibrated with the surrounding soil. The <br /> volume of a sample container, such as a Summa® canister (which is not used during <br /> purging), should not be included in this calculation. A battery powered pump can be <br /> used to purge the system. Check to make sure that all connections, fittings, etc. are <br /> tightly fit in the sampling equipment prior to purging. <br /> ETC Soil Vapor Sampling Technical Toolkit 17 <br /> Version 1.4,September 7,2005 <br />