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i <br /> 1 3.2 In-Situ Vapor Extraction <br /> lie In-situ soil vapor extraction utilizes a series of wells to remove VOC from the soil <br /> matrix A vacuum is applied to the extraction wells, typically by means of a blower, <br /> and VOC vapors contained within soil pore spaces are extracted from the subsurface <br /> In-situ vapor extraction can be a time and cost-effective remedial technology in <br /> permeable soil, and if contaminants are volatile at ambient temperatures Vapor <br /> extraction systems have been shown to efficiently remove lighter-chain hydrocarbons <br /> (e g , gasoline) from soil Vapor extraction systems have also been shown to <br /> effectively remove floating liquid contaminants, and have a limited effect on dissolved <br /> contaminants In general, the vapors brought to the surface will require treatment, <br /> unless contaminant concentrations are low Numerous options are available for <br /> treatment of extracted vapors In order of decreasing contaminant concentration, <br /> treatment options include thermal incineration, thermal oxidation, catalytic oxidation, <br /> carbon adsorption, and direct discharge (no treatment) The type of vapor treatment <br /> is determined by local air discharge regulations, cost, contaminant types, and <br /> concentrations <br /> 1 3 3 Physical Containment <br />' The physical containment of contaminants in soil is accomplished either by the <br /> injection of stabilizing agents into the soil matrix or by excavating soil and adding a <br /> stabilizing, vitrifying, or encapsulating agent The success of physical containment <br /> methods mainly depends on soil matrix grain size Soil with a coarse-grained matrix <br /> has a relatively high permeability and low attraction between soil particles, thus <br /> enhancing the ability of stabilizing agents to completely penetrate the soil Soil with <br /> a fine-grained matrix has a relatively low permeability and higher attraction between <br /> soil particles, thus inhibiting the introduction of stabilizing agents and reducing the <br /> effectiveness of the stabilizing process The presence of groundwater in close <br /> proximity to a containment area complicates placement of stabilizing agents and the <br /> ability of the agents to set up at or below the soil/water interface. Because physical <br /> containment does not remove or degrade waste material, long-term monitoring may <br /> be required This alternative is feasible for a wide range of organic and inorganic <br /> compounds <br /> 2 0 GROUNDWATER REMEDIATION <br /> 2 1 No Acton <br />' This alternative to groundwater remediation involves a negotiated plan to monitor <br /> groundwater quality without an active remediation system Generally speaking, for <br /> this option to be considered, free-phase product must not be present on the <br />' groundwater table For example, it is a matter of policy with the California State <br /> Water Resources Control Board regarding leaking underground fuel tanks saes that <br /> free-phase petroleum product must be removed from the groundwater table in all <br /> cases In any event, contaminants in groundwater must be demonstrated not to pose <br /> an immediate and/or long-term threat to the public health <br />