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No 385 ETHYL BENZENE 11188 <br /> SECTION 6. HEALTH HAZARD INFORMATION cont. <br /> SECTION <br /> eyes,including under the eyelids,gently but thoroughly with flooding amounts of running water for at least 15 minutes Skin.Rinse <br /> e affected area with plenty of water,then wash it with soap and water Inhalation Remove the exposed person to fresh air,restore an <br /> support his or her breathing as needed Have qualified medical personnel administer oxygen as required Ingestion Unlikely Should <br /> this type of exposure occur,the aspiration hazard must be considered Do not induce vomiting unless directed to do so by a physician To <br /> prevent aspiration by spontaneous vomiting,keep the v,ctim's head low(between his or her knees) Get medical help(In plant,para- <br /> medic,community)for all exposures.Seek prompt medical assistance for further treatment,observation,and support after first aid Note <br /> to Physician Professional judgment is required as to whether or not to induce vomiting because of the possibility of aspiration A gastric <br /> lavage may be administered,followed by saline catharsis,if this procedure is appropriate to the specific incident.Moartor cardiac and <br /> pulmonary functions <br /> SECTION 7. SPILL, LEAK, AND DISPOSAL PROCEDURES <br /> SpiIVUak: Notify safety personnel,evacuate unnecessary personnel,eliminate all sources of ignition immediately,and provide adequate <br /> explosion-proof ventilation Cleanup personnel nerd protection against skin or eye contact with this liquid as well as inhalation of its vapor <br /> (see sect.8) Contain large spills and collect waste or absorb it with an mert material such as sand,earth,or vermiculite Use flonsparkmg <br /> tools to place waste liquid or absorbent into closable containers for disposal Keep waste out of sewers,watersheds,and waterways Waste <br /> Disposal Contact your supplier or a licensed contractor for detailed recommendations Follow Federal,state,and local regulations <br /> OSHA Designations <br /> Listed as an Air Contanunant(29 CFR 1910 1000 Subpart 2) <br /> EPA Designations(40 CFR 302A) <br /> CERCLA Hazardous Substance,Reportable Quantity l ODD lbs(454 kg),per the Clean Water Act(CWA),H 311 (b)(4)and 307(a) <br /> SECTION 8. SPECIAL PROTECTION INFORMATION <br /> Goggles Always wear protective eyeglasses or chemical safety goggles Where splashing is possible,wear it full face shield Follow <br /> OSHA eye-and face-protection regulations(29 CFR 1910 133) Respirator. Wear a NIOSH-approved respirator per Genlum reference 88 <br /> for the maximum-use concentrations and/or the exposure limits cited in section 2 Follow OSHA respirator regulations(29 CFA 1910 134) <br /> For emergency or nonroutint operations(spills or cleaning reactor vessels and storage tanks),wear an SCBA Warning Air-purifying <br /> respirators will not protect workers in oxygen-deficient atmospheres Other: Wear impervious gloves,boots,aprons,and gauntlets,etc,to <br /> prevent prolonged or repeated skin contact with this material Ventilation Install and operate general and local maximum,explosion-proof <br /> ventilation systems powerful enough to malntaln airborne levels of this material below the OSHA PEL standard cited m section 2 Local <br /> exhaust ventilation is preferred because it prevents dispersion of the contaminant into the general work area by eliminating it at its source <br /> Consult the latest edition of Gemum reference 103 for detailed recommendations Safety Stations Make emergency eyewash stations, <br /> safety/quick-drench showers,and washing facilities available in work areas Contaminated Equipment Contact lenses pose a special <br /> hazard,soft lenses may absorb irritants,and all lenses concentrate them Do nor wear contact lenses in any work area Remove contami- <br /> nated clothing and launder it before wearing it again,clean this material from shoes and equipment.Comments Practice good personal <br /> hygiene,always wash thoroughly after using this material and before eating,drinking,smoking,using the toilet,or applying cosmetics <br /> Keep it off your clothing and equipment-Avoid transferring it from your hands to your mouth while eating,drmkmg,or smoking Do not <br /> eat,drnal,,or smoke in any work area.Do not inhale ethyl benzene vapor <br /> SECTION 9. SPECIAL PRECAUTIONS AND COMMENTS <br /> Storage/Segregation Ston--ethyl benzene in closed containers in a cool,dry,well-ventilated area away from sources of ignition and <br /> strong oxidizers Protect containers from physical damage Special Handling/Storage Outside,isolated,detached,or remote storage is <br /> recommended for large quantities of ethyl benzene isolate bulk storage areas from acute fire hazards Engineenng Controls Make surf <br /> all engineering systems(production,transportation)are of maximum explosion-proof design To prevent static sparks,electrically ground <br /> and bond all containers,pipelmes,etc,used in shipping,transferring,reacting,production,and sampling operations Other Use safety <br /> cans for transferring small amounts of ethyl benzene <br /> Transportation Data(49 CFR 172.101-2) <br /> DOT Shipping Dame. Ethyl Benzene <br /> DOT Hazard Class Flammable Liquid <br /> ID No UN1175 <br /> DOT Label- Flammable Liquid <br /> DOT Packaging Exceptions 49 CFR 173 118 <br /> DOT Paciaging Requirements 49 CFR 173 119 <br /> J'NJO Shipping Name Ethylbenzene <br /> IMO Hazard Class 3 2 <br /> IN10 Label Flammable Liquid <br /> D14DG Packaging Group I1 <br /> References 1,26,38,94-94, 100, 116, 117, 120, 122 <br /> Judgments as to the suitability of mforinauon hemin for purchasers purposes ars prepared by PJ Igoe,BS <br /> nec4ssanly purchaser's responsibility '!herefore although reasonable cars has <br /> been taken in the preparation of such inforniaban Cesium Publtslung Corp Industrial Hygiene Review DJ Wilson,CIH <br /> uteods nowusaabes rnakes no mpresenutions+nd as==no responsibility <br /> as to the accuracy or nuumity of such infomminn for application to <br /> purchasers intended purpms or for consequences of its use , Medical Review W Silverman,MD <br /> Cep"bi O 1985 by Gearum Publubmg Carporstian <br /> AnY C4)=ercte use or reproductieaWithaut the publxsW s pernussinn is ploWbited <br />