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SITE LOCATION <br /> Former Regal Station #603, is an operating EXXON service station located at 6425 Pacific Avenue <br /> at the northwest corner of Pacific Avenue and Douglas Road, Stockton, in San Joaquin County, <br /> California. The site lies in section 21; T2N; R6E; MDB&M at approximately 12 feet above mean <br /> sea level (MSL), see Figures 1, 2 and 3. The parcel is #31 and is recorded in Assessor's Book 97. <br /> GROUNDWATER MONITORING WITH OXYGENANTS ANALYSIS <br /> Depths to groundwater measurements were obtained from all monitor wells associated with this site <br /> (MW1, MW2, MW3, MW4, MW5, MW6, MW7, MW8, MW9, MW10, MW11, MW12 and MW13) <br /> on December 16, 1997. No vacuum influence was measured, the vapor extraction/sparging system <br /> had been non-operative for eight days, see Appendix A — Field Notes and Methods and Procedures. <br /> Figure 4 represents the groundwater gradient obtained from measurements obtained on December <br /> 16, 1997 and shows a mound of higher groundwater at MW-2 flowing outwardly in all directions. <br /> Measurements obtained at MW-12 suggest high groundwater flowing towards the site or from the <br /> east to the west, with a low water trough between MW-3 and MW-10. <br /> The most recent groundwater quarterly sampled all of the wells for analysis of Total Petroleum <br /> Hydrocarbons as gasoline (TPHg), Benzene, Toluene, Ethylbenzene, Xylenes and Methyl tertiary <br /> Butyl Ether (MBTEX) using EPA method 8020, see Table 1 and Figure 5. In addition all samples <br /> were also analyzed for the Oxygenants as directed by the December 9, 1997 Memo from San <br /> Joaquin County Environmental Health, see Appendix B and F. With the exception of MW11 which <br /> contained 30 ug/L of MTBE all remaining samples were below lower laboratory detection limits for <br /> the Oxygenants; Tertiary Butyl Alcohol (TBA), MTBE, Di-isopropyl ether (DIPE), Ethyl tertiary <br /> Butyl Ether (ETBE) and Tertiary Amyl Methyl Ether(TAME). <br /> During this sampling, field measurements were obtained from all of the wells for Dissolved Oxygen <br /> (DO), Nitrate (NOA Sulfate (SO4) and Ferrous Iron (Fez). Dissolved Oxygen measurements were <br /> also obtained from select wells (MW2, MW8, MW9, MW12 and MW13) prior to turning the vapor <br /> extraction sparging system off on December 8, 1997. <br /> Figure 6 represents DO measurements obtained while the vapor extraction — sparging system is <br /> operating and shows oxygenation of the entire plume area (compare figures 5 and 6). <br /> Figure 7 represents DO measurements approximately two weeks after the vapor extraction — <br /> sparging system was turned off. This figure shows a rapid depletion of DO to below field <br /> measurement levels except near sparging and vapor recovery wells MW and MW13, down gradient <br /> well MWI 1 and upgradient wells MW4 and MW7. <br /> Figures 8, 9 and 10 represent the other three field measurements for the electron receptors Nitrate, <br /> Sulfate and Ferrous Iron respectively. These three figures demonstrate that active bio-degradation <br /> is occurring at this site with reductions of NO3 and SO4 near MW2 and MW12 and elevated levels of <br /> Fee occurring in the same areas. The Fee plume shown in Figure 10 is currently this site's best <br /> indicator of the bio-degradation process. The Fez plume shows the area that is actively consuming <br /> 2 R603 Update##50 12/97 <br />