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PR0544801
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Last modified
11/19/2024 10:20:02 AM
Creation date
9/4/2019 10:49:39 AM
Metadata
Fields
Template:
EHD - Public
ProgramCode
3500 - Local Oversight Program
File Section
WORK PLANS
RECORD_ID
PR0544801
PE
3528
FACILITY_ID
FA0003210
FACILITY_NAME
TEXACO TRUCK STOP
STREET_NUMBER
7500
Direction
W
STREET_NAME
ELEVENTH
STREET_TYPE
ST
City
TRACY
Zip
95378
APN
25015018
CURRENT_STATUS
02
SITE_LOCATION
7500 W ELEVENTH ST
P_LOCATION
03
P_DISTRICT
005
QC Status
Approved
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CAP Addendum:Former FueM g Station, 7500 West Eleventh Street, Tracy, G l� Page 15 <br /> which prevailed in February 2007 when the concentration of dissolved fuel hydrocarbons <br /> in the groundwater was considerably greater than was the case in July 2007. <br /> Unfortunately, that is not the case. <br /> A sufficiently large reduction in the concentration of components of fuel hydrocarbons <br /> dissolved in groundwater can permit Redox Potential and the percentage of dissolved <br /> oxygen to rise and induce aerobic processes of natural attenuation to be initiated. <br /> However, although either anaerobic or aerobic processes can readily produce such a <br /> reduction in the absence of a continuing source of petroleum hydrocarbon solutes, <br /> aerobic conditions will not be initiated unless the source of the dissolved contaminants is <br /> removed. <br /> 2.3.4.1 Continuing Sources of Contaminants in Groundwater: LNAPL and Soil . <br /> When all leaking storage tanks or other causes of releases of petroleum hydrocarbons into <br /> the subsurface have been removed, there are two continuing sources that contribute <br /> dissolved contaminants to groundwater. These are: 1) adsorbed contaminants on soil that <br /> slowly desorb and dissolve in the water column; and 2) any fuel components in the form <br /> of floating LNAPL which, due to its contact with the groundwater, will contribute <br /> dissolved contaminants that, where present, will maintain the concentration of those <br /> dissolved contaminants close to their solubility limits. Given those conditions, it is clear <br /> that what must be achieved by a groundwater remediation technology designed to <br /> increase the rate at which groundwater contaminant concentrations are reduced by natural <br /> attenuation applied at sites where soil is affected by hydrocarbons and LNAPL is to <br /> sufficiently suppress the continuing sources that contribute dissolved contaminants to the <br /> groundwater. <br /> We should now consider each of the two sources of dissolved contaminants to the <br /> groundwater — adsorbed fuel components on soil and fuel components in the form of <br /> LNAPL. As was noted in Section 2.3.4, petroleum hydrocarbons in soil amount to an <br /> estimated 45.52 % of the total mass of contaminants in the subsurface beneath the area of <br /> the Navarra Site that is affected by LNAPL. That is an overwhelmingly large fraction <br /> compared to the 0.0012% of the total contaminant mass that is estimated to be dissolved <br /> in the groundwater in the same area. However, it is important to consider the mechanism <br /> by which adsorbed contaminants contribute to the quantity of dissolved contaminants in <br /> groundwater. Contaminants adsorbed to soil desorb and are leached into groundwater at a <br /> very slow rate,particularly from clastic soils that contain a high fraction of clays having a <br /> high cation exchange capacity, as is the case at the depth of the water table at the Navarra <br /> Site. As is evidenced by the aerobic conditions that prevail in groundwater in all areas of <br /> the site where LNAPL is absent but soil is affected by components of hydrocarbon fuels, <br /> the rate at which desorbtion from soil is occurring is significantly less than the rate at <br /> which aerobic processes of natural attenuation are remediating the dissolved <br /> contaminants in the groundwater. This is the typical condition at all sites except those <br /> where soils contain unusually high concentrations of petroleum hydrocarbons and <br /> contains no clay, or where the clay fraction of clastic deposits is composed entirely of <br /> minerals, such as kaolin, that have low cation exchange capacities. <br />
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