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U <br /> REGULAR UNLEADED GASOLINE <br /> MATERIAL -SAFETY-DATA SHEET (RFG WITH MTBE) <br /> OENNIS K. BURKE, WC. MSOS N0, NL-1 PAGE 2 <br /> r <br /> SECTION 5 INGESTION-Oo not anduce wn+iling because of danger of aspirating squid into lungs.Get <br /> Imritediafe r,.etlical.atleNidn,if spontaneous vorirmnq occurs.nob the vaim's feria lower man <br /> hies to prevent aspiration. <br /> REACTIVITY DATA NOTES TO PHYSICIAN-In case of ngeuan,me rnosl mportant risk le ASSass if the enery <br /> of aspiration of the produsl into the kings.since an acute chemical pneumoftilis can rapidly <br /> STARRf TY ................... ........... ..,..,...,....-..I:.................,... viii.. STABLE pmgfcss 10 respiratory lailure.Gasping.cdughing and Choking are presumptive evidence of - <br /> COHDITIONS TO AVOID FOR STABILITY-Aviva heal.sparks incl Open flames Prevent vapor aspiration.II is suggested IK31 All patienls suspected N hydracarbon Widlan here base line <br /> accumvlalion,f q, - chest mays.Immediate hospitalization should be Considered for asymptdmalie children with <br /> ? - -in abnormal Chest s{ay obtunded or nypox C-mlenhanat of massive irgesllons and patients <br /> fNCOMPATIabTY.(Afaferfafs To Avoid)-May react xith strong c,,dizoig agents with abnormal Chest x-rays with clinically significant pulmonary disease. <br /> HAZARDOUS DECOMPOSf►lON OR BYPRODUCTS-Carbon Monoxide and olhe•uniderc,hea Gislroniestinal symptoms are usually minor and pathological changes of the aver and kidneys <br /> organic compounds can be formed upon c9mbus+irin. �„ are reported to be uncommon in acute lox cations,Deconlammm <br /> alton jinClueed emesis or tavagel <br /> HAZARDOUS POLYAtER1ZARON. -- ..................._.. .. .. ..,viii NONE should be considered on the merits of each indvdual case-The usual precrvtan of an endoNA Iracheaf tube showld be considered prior!o lavage ' <br /> r CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION..,,., .,viii., �. , ... <br /> a Hydrocarbons may increase the sensilivrty of the myocardium+to eettchotamoes.Electro. <br /> ! cardiographic monitoring may be indicated and careful consideration eha,ld be given to the <br /> SECTION fi <br /> - selechDrt of bronchodilalors. ., <br /> HEALTH HAZARD DATA_ ACulo central nervous system signs and symptoms may fesafl from urge iryestioru o-asprahor+. <br /> �. .induced hypdvia, <br /> In case of skin injection,prompt deonaemeni of Tka wound Is necessary to m,mmfze nec+o$i5 <br /> ROUTE(SI OF ENTRY-Inhafalgn, absorption. and rngeshon if hygienic olacnces are not ,and tissue loss. <br /> observed, <br /> HEALTH HAZARDS (Acute And Chemic) SEC.VON 7 <br /> EYE CONTACT a-Slightly irritating.Exposure to vapors.furan or musts may cause frenal,,, - - <br /> SKINie0nei.pain blurred vision.Lacrima=ion and contunctwars PRECAUTIONS F�Fl-::SAFE HANDLING AND USE <br /> SKIN CONTACT-:Slightly irritating.Repeated or Prolonged contact with the skin could cause - <br /> deWung,redness,itching,decking,and Possible secondary inlecYon or dermabfis to amctled STEPS TO BE TAKEN IN 6?EAIATEJTIAL IS RELEASED OR SPILLED-Shut off mitran sources <br /> area SymPloms'may tmdudC pain or a legkng or heal-discoloration,Swelling and blistering r9 <br /> INJECTION-High assure skin infections ma n01 nD flares.Smoking or aft?4eEth halaft3ian a.Slop laai.d you can wdhoul risk.Keep unnecessary <br /> q py appear serious at hrsl,w to a few tours. people away+soIalfNjk f6Arinil deny entry-Stay upwrind and keep"of lou,areas.Isdale <br /> ,Is Sue wA Decome"often.&scDlored and eMremely pa.nlvl. far half mile in aft dlleclion'0 tank-or tank true%is invelvecT in Erre.Wilat spray may'educe <br /> -May cause ad-erre Luer and kidney¢llects based on tests with vapor W1 may'ijo �+rcvettt ignition in closed spau5 <br /> SPECIAL TOXIC EFFECTS <br /> laboratory animals A product of Minicar composition has been found b be carcinogenic to ConSidelBd'fa'A;:l:p walYf DWlulanl,releases of they product should or p'eve nSeO horn(on <br /> laboratory an, when given by inhalation „.. [ammatn'sod drld.w5itr.end from entering drainage and sewer systems.Gonuin Ipud to preen' <br /> IARC has determined there is Lrn,led e+ndence for the carcfnogenic.ty of gasoline to ekpehmenfat luno(.con4amvi3tlon at soil.surface watc,or groundwater.Clean up small spills using sero <br /> animals and inadoquate evidence for the carcinogenic rty in humans,(uIRC Cuss 281 " Or o17tiQ7_ADi+Combustibte sorbem mateeals and place into containers lo'Later disposal <br /> WARNING:The use Of any hydrocarbon fu¢l in in area without adequate ventifaGOn may rssufl Thp,Clein'Water Act requiros the reporting of any discharge Of crude dif and petroleum pro. <br /> +nlsazardausle"CISdcbmbusli0t%PDCunsaMin2dequaopovygen6evets IARChasdelermned.:- 3;;du[t,;jurt"kind or form)into sthlace water%.tinniedialelycall the National Emergency Pg"ponsc <br /> s that gasoline engine exhaust is possibly carcinogenic to humans.(IARC Class 281 ::Conler'al 1-606-e2e-8802- - <br /> This pfuduct contains beaten.Acute benzene Doason,ng causes central nervous system dep es WASTE DfSPOS4L METHODS-Pup;cUntamnated materials in disposal CGrtair+er3 and por <br /> d se <br /> s-on-Chronic exposure affects the hematopoialC system causing blood disorders.nclud ng 'DI n a manner consistent with applicable regulations.free EpuiQ igroGbk wastes are panned <br /> anemia and Oartcytpponia.Mutagenic and CtdSSage nl[n mammalian and non-mdm+ylpeian les[ .from diSpOS71 by landfilling or in cont2iners.Product recovery and recyclingdr!recDmmended <br /> systems.Aepfodudlve toxicant only al doses that are maternally toxic,based.ort.iests with,. where possible. <br /> an.maK.May be absorbed through ire Stir.Bentene is carcmogene-lo taborabry'tutimgiy Wteen - <br /> qwe,by intubation or-by inhalation-There is an association between occupatlona[(ixposure PRECAUTIONS TO BETAKEN INHANDLfNG AND STORAGE-NFPAGass 1Astorage.Swre <br /> to benzene Ory human leukemia. in lightly closed containers in cool,dry-isolated.welLwmlilated area away from heat,sources <br /> This product also contains MTBE.This product bras tested in a variety p'{:mtEs>: anicify assays tit f9^d'on and ncompatbfeS.Use honapark fools.GfDUnd tines and equipment used during <br /> and the fesirlls'were geneeaay negative.However.this p'odud was po5ltjve'ti'y'Mglijt Lymphorna transfer to reduce Me passibdi[y Of slaht$part-+rrtiated hie or explosion.MatoraI may be at <br /> Assay.Exposure to very high eoneomralien s of MTBE has produced-m,,�Pfia6erd6 telaI lox icity elevated temperatures and/or DreSSvfes.Exercise due cafe when Opening Weekrs and Sampfrrg <br /> Andnalbrmalans it laboratory animals.Chronic exposure to high",;VsofUTBEhas produced Ports.Store gasoline Only in approved,clearly labek6 containers.Never store in glass of <br /> urinary syslem effects in laboravy animals-Mice exposei9.p'XW..ppm of MTBE vapors unapproved plastic containers.Precautionary labdting kr pumps,portable containers.and drums <br /> developed a slightly higher incidence of benign liver IWkors'"Rals developed an increased Is sequared,A"Hazardous When Empty'piclogfarn and DOT"Flammable Lqud"label are <br /> incidence Or chronic ' essive kidney damage.en..gf 1 - also required for drums, ' <br /> P Dgr Y 9 (tC TyQcalfy�npted in aging rats.These � - <br /> effects in the]600 and 80M ppm groups were accgrnpiiited�bjr.as increased Incidence of kidney EMPTY CONTAINERS-Emply containers contain loan IlammatileitOmbustible or explosive <br /> lurrkN3 in the males.Benign festcuLat tumors wefs:nurparigaly increased in the high dose group- residue a vapors.Oo not Cul,grind,drill.wetd,frust of d4potic of Containers unit ss edecluaoe <br /> Inc sign Ncance of these findings lot humatt Agjefthis urscl¢ar. 'DrecautiOns are taken against these hmards <br /> INHALANON-May Cause respralary IracA_((Hlatipjyt.P.Tblonged breathing of vapors can cause - - <br /> cenfrat mer vous system effects.SYmDlpijrs frl3'%_Fnl]Yi�f1 headache.60meSS.toss of appelde CIn -. .. <br /> weakness er,d foss of wadirtatian. <br /> Degeiurativf� hannd grs in the liver kidneys alaSECTION <br /> U <br /> ne marrow <br /> may occur with prolonged.high ton[eatttloas May also cause anemia and irregular hear) l; <br /> rhyrhm.Repealed of prolonged exposures rr+aycause bill changes- CONTROL MEASURES <br /> Solvent-'snit ing".(abuse)or intentional prolonged overexposure to high levels DI vapors Can <br /> produce abnoratat behavior.convulsions,delkum,nervous system damage and sudden death. RESPIRATORY PROTECTION-NIOSHTMSHA approved sell{onIamt0 Weathing apparatus or <br /> INCESTION - Modoralefy Toxic.Aspiration into lungs may cause pneumoneis.May cause supplied-sir mask must be avaifabte for non-foubre and emergency use.Mask must be used <br /> gastrointestinal disturbances.Symptoms may include nilalien,naysea.vOnuing and diarthea- 'Of entry into large links,vessels Of tither confined spaces Wniiral-On may be used to ew,ol <br /> May cause harmful central nervous system eftecls Effects may mclucse excitation,euphoria. Of ledvcd airborne concentrations_ - <br /> headache,dirtiness.drowsiness,blurred vision,fatigue.lienors.convulsions.loss OI con YENTILATION f <br /> soousness,corha,respiratory Aires[and death,A dPiraiion hazard if vomiting occurs.Kianey <br /> damage may be evidenced by charges in urine output,urine apa pfivi or edema. LOCAL EXHAUST.. __.............. NA SPECIAL NA. <br /> AfEDfCAL CONDITIONS GENERALLY ADCRAV4r£0 By EXPOSURE-Poe.ex.somg eye,skin- l MECH4NICAL (General) EXPLOSION PROOF. OTHER- T- NA <br /> and respiratory disorders may be aggravated by exposure to this oroaucl Imbaued liver and, .SKIN PROTEC71ON-Wear impervious gloves ono protective Clothing to prevent skin coNacl <br /> kidney Ivnpions Irom oretxisting disorders may be aggravated ty exposure to this pro6ucl <br /> '14RC has demrmined that gasoline engine exhaust is possibly carcnogen.c .EYE PROTECTION-Wear safety yla53e5 or Che—Cal goggles to pftvtnl eye contact.Do net <br /> wear cOntaCT tenses when working weft this substance Hare cye washing faclify readuy ariaeble <br /> EMERGENCY ANO-FIRST AID PROCEDURES - ' where eye contact Can occur, „ <br /> EYE CONTACT=1Flush immediately with large amounts of[fesh water for at teasl 15 minutes. OTHER PROTECTIVE CLOTHING DA EOUIPMENT-Use a Chemieal-remsianl aDlon <br /> ;Remove cOeta(t lenses if worn Eyelid$Should be held away from rhe eyeball to ensure Ihoraugh a <br /> rmsirg,Ge'medical attention if urination persists- svORK PRACTICES-Lyo not use or store near flame,sparks or hot surfaces.Vie only in«cin <br /> con- <br /> .SKIN COHI4CT-Remove[pn[2m+na[ad clothes immediately Wash Still Inoroughly wrin soap ventilated area.Koep container closed.Never siphon by mouth.Do not wild.heal or drill cOn- <br /> and water.Get medical a(lemion of irretailon persists.Wash contaminated[tames. tamer Replace cap or bung Do net use pressure to empty drum or explosion may resuh.Use <br /> Only 95 a motor Ivd.DD n01 use for cteanlrg-pressure acphanee fuel,of any other use.Keep <br /> INJECTION-H+gh pressure inject-ons are serous medical emergenc.its Getmeorcal atleN.on: head away froth cdnlainer when opening of dnpensino <br /> immediately. <br /> INHALATION-Remove affected Perrin'Irdm SdufCe Of exposure If mol breatnn en HYGIENIC PRACTICES - Remove contaminated ckxn•ng and cicart before reuse: Wash - <br /> g. sure Open <br /> airway and inside cardiopulmonary resuscilaDon(CPA).if bream�rq a duhcult.administer 4 y w,In soap and wafer Cher handling <br /> Oxygen+t a.a:table,+Gel med,ca+artenlion. NA = NOT APPLICABLE NDA .,HO DATA AVAILABLE <br /> Ines,nfprmaf.on is based on the darn available fo us and conS,Oered 10 be Connect Hcx e.cr Danns X 8ufke-Inc.males no warranty expressed or.n.pheLl,re9o,cknq the accwacy Or this data ' <br /> Or rhe resurt5 to be 0063006 from the use lhereol. Deems N Rake Inc assumes no respon5,0•I+Iy for"'Pry Or loss It"the use or the producl descnbed nerern <br />