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SUPER UNLEADED GASOLINE <br /> MATERIAL .SAFETY DATA SHEET (RFG WITH MTBE) <br /> DENNIS K. BURKE. INC- t aASOS NO. SNL-1. PAGE 2 <br /> Y SECTION 5 INGESTION-Do nor indvca.omaing beceusa of danger of aspirating liquid into k pa.Gat <br /> imenecWw medical atterdion.If sponcanoorn vomiting occurs,hold the viciirri a head lo.,.,sun <br /> - - - - hips to pmvenl aspimlipn, <br /> REACTIVITY DATA NOTES TO PHYSICIAN-In case of ingestion.fie moss impoream flak to asaau it the sealant <br /> of aspiration of This product into the lungs.Since In IMA6 chemist pnIUMOnitp Can rapl6y <br /> STABILITY .,.,....................:. .........viii.. -,viii. STABLE progress to respiratory failure.Gasping,coughing and Choking are Praaumpii,it eyidance of <br /> CONDITIONS TO AVOTO FOR STAR([ITY-Avoid heat.aperks and open flames-Prevent vapor aspiration.It is suggested Na at all patiar suspected d hiedcOcerbon aspinttion hairs bete line <br /> is chwtt x4sye.Immediate hospitalization shovid be coeu;eWod lar asymptomatic cdl6ren with <br /> aCCurhulatim. an ahnotmal Chest e+a.OolundOd Or h Cx C.intenl'Onal Or massive In Ons, <br /> INCOMPArrBILiry Mafedefa lo Arold -May react with strong oxidizing a nm. Y YP Pea4 and patients <br /> ( 1 Y� n4 r'9 got with iDnormal csett z+ayc with cllrhkagy tlgnlflcara pulmonary diseaaa. <br /> 'HAZARDOUS DECOMPOSITION OR BYPRODUCTS-Carbon Ntono.de and other unidantiGed Gasanartastinaf symptoms ane uaSuStly minor and pathological changes Of she firer and kidneys <br /> organic compounds can be lc,med upon cornbmtioni are ieponed m be uncommon in azure itakaooru.0econrAmlrletlon pnduced emesis or tava0e1 <br /> r HAZARDOUS POLYN£RIZATION..............................,........,...... ................,.:k,.... NONE should be considered on the media of each individual usa.The usual pnscAulion of an endo <br /> ' CONOMONS TO AVOID HAZARDOUS POLYMERIZATION•...........:_. ............ NA tracheal tuba should be considered prior b lavage. a " <br /> Hydrocarbons.may increase the sansllivity d the myocerdiun 16 calecWtimitles.Electro. <br /> SECTl�l Y.6 cardiographic monitoring may be indicated ud ca-10 cons;deralion ahoufd be given h the <br /> ! • selection of bronchodilators. <br /> HEALTH HAZARD QATA hypo cute central <br /> a5 system signs and symptoms n+eys r l from In"Ingestions or aspiretior* <br /> In case of skin Injection,prompt dabridemerti oil the'waund is necessary to minlmlte neuosis <br /> ROUT£(S)OF.ENTRY-Inhalation,aoeorphon,and ingestion 7 hygienic practices am not and lissae loss. - v <br /> observed. - <br /> `S ( e r a SECTION 7 <br /> HULIH HAZARDS (Acute And Chronic) <br /> EYE.CONTACT-Skghtly.iriitating.Exposure 16 vapors.fumes or mists may Cause Rmanon, - - - -- <br /> f radn*m,pain,blveed virion.lacrimeuon and coniunctvita PRECAUTIONS FOR';GAFE HANDLING AND USE <br /> SKIN CONTACT-Slightly irritating.Repealed or prolonged comad with the skin souk]cause -- <br /> dela!Grg.redness,itching.Cracking,and possible secondary inrecr,on of dermatitis to eflecled <br /> I arae,Symptoma,rtiay indvde pain or a looling of howl,discoloration,swaging and blistering. STEPS TO 8E TAKEN IN GI C A(ATERIAL h RELEASED OR SPR1£D-Shut o!!igrdtion sevums; <br /> no Maras,smoking or JX"'"arf'hLz rd-Area.Slop 1•ak a ytW can wkhoud nsk Kmp unnecessary <br /> INJECTION-High pressure skin iniectidrks may nor appear Serious at hr51;within a few hours,. psopis away.isolate Mford`pa"d deny entry-Stay upwind and kaep out or lo+areas,ley fit. <br /> [issue will become swollen,discolored and extremely painful. lot hail mile in all d1iiclons'if3ans;or tank truck is involved in Ere.Wale,soray may reduce <br /> • SPECIAL TOXIC EFFECTS-May cause adverse liver and Whey affects based on tests with vapor but may ri�.pis':iein ignibon in cioud spates _ <br /> laboratory animate.A product of similar rompoaition has been found to be ce,cinogenlc to 6on9deredAf tr8 itantler pollutani.releases or this product should be Pr"Moo from Iron. <br /> taho alory an,ri,its-hen given by inhalation. - <br /> famnntirti�atsQ xMei-and from entering drainage and seer"ms.Certain Fquid to p ritr.ent <br /> IARC has deiennimed[hero is limited evidence foe the ci rcinogonricy,of gasoline in erperimental Ivithar to�,"natfon of soil,surface-alar or groundwater.Clean up small apillt using send <br /> animals and Inadequate evidence to the rarcinogenicdy in humans.(IARC Class 2% or olh&LtQnobrnbuslibfe sorban[maleruls and place into containers lex tetar Gsposel, <br /> WARNING:The use of any hydrocarbon Neel in an area without adequate vanci[stion(nay result TKp;C1eaniiVater ACI requires The reporting of any ciechuge of crude on and petroleum Piro- <br /> in hazardous levels of combustion products and inadequate oxygan tevd[ IARC has determined 'joi i (Aeriq kind or brrnj mio surtace waters lmmod,awycaa the Natsona)Emergency Response <br /> that gasoline engine exhaysi is possibly carcinogenic to humans.(SARC Class 201 1400-424-8802._ x _ <br /> This prodoo co mama benrena.Acura benzene poisoning Causes comraf nanous System fires- .:,WACTF DISPOSAL METHODS-Place mrmmnafed ma:ar;ak in disposal cottainert and dispwa <br /> j Sion.Chemic exposure affects the h.matoParetic System causing blood disorders.Including `of in a manner consistent vilh applicable regulations Time liquid ignitable wassus are banned <br /> anemia and pancytopenia.Mutagenic and clastogenic in mammalian and noon Ammaran lest. Arom disposal by lantlfilling or in Containers.Pro-dud mcp•ery and recycling are recommended <br /> t systems Reproductive toxicant only at doses that are matefnaly toxic,based on tans-ah wtiere possible. <br /> an rhi&K May be absorbed through the skin.Benzene is earc'esoganc to labo,atoymati:vitpu, <br /> given by Intubation or by inhalation.Thera is an association bewccu <br /> ten opelbnal e,tposufe Mi-AUTIONS TO BE TAKEN IN HANDLING AND STORAGE-NFPA Clara 1A storage:Store <br /> to benzene and human leukemia. in lightly Gored container!in cad,dry,isolated."ll-"milated aria away from heat,sources <br /> This product alw contains MTBE.INS.product was tossed in i variety d'i:ps"4001city assays of igndion end incompatibles.Use non-sport loots.GMAd lines oral equipment used during <br /> and the results ware generally negative-However Its product was poe.4a ii131souje Lymphoma Ilanslef 10 reduce the possibility at static sparkinllla[ad fins or explosion.Malarial may be at <br /> I Assay.Exposure to very high concentrations of MTBE has producedmaxersr'a dror fele)tensity elevated temperatures AnNor prasaues.Exorcise Clue care then opening bleoders vol sampfing <br /> and maflorma fans in laboratory ananals.Chronic arposure to high iecie(s ofifTBE has pioducad porta. Store gasoline only In approved,cSoary labeled containers-Never store In glass of <br /> urinary System ishecre in laboralory animals.Trice expq$a AC SM.ppm d MTBE vapor; unapproved plaitie cmrai m.Precautionary bbaling lex pumps.portable eUrdainonk and drums <br /> daveiegad a slightly h'9hat irxidencce of ben' n g liter tuiimrsloped an increased is required.A-Hazardous When Empty"pictogram and OCIT"Flammable Liqud"label are <br /> .�"Rats days <br /> incidence of chronic progressive kidney damage,an 01CI_t�Ca fynoted in aging rail.These also required for drums- T ' <br /> attests n the 3006 and 8000 ppm gnxghs wore etccasnpahiddb'/Eti:IhcreaSad inciderra Of kidney EMPTY CONTAINERS-Empty eomainen contain taxiy flemmaDlekornbuetible or axplduve <br /> lunhors in the males.Benign teiaCtAar fumes weTArtKIt!IeriCAly increased in the high doss g+do. .residue or vapors-Do not cut,grind,drill,weld,reuse of dispose at containers unit its adequate <br /> °The significance of these rindings for humanj[ ARM:k unclear. precautions are taken against these hazards. <br /> INHALATION-May cause rot spinatay luso¢rgatiurs;Plaitonged•bread,ing d vapors can Cause <br /> viii. <br /> central nervous system rdlacot.Sympuarti-e map:lnclude:headeche,dilmnot,,loss of appetite, .��CTf�N 8 <br /> v,aaknaw and loss d caordoaton,Doge Ykalivkhanges in the Fie{kidneys and Done marrow <br /> may occur with'prolonged.high concentriitione May Adso cause anemia and irregular heart <br /> Zrhythm.RepeAted or prolonged uposures may cause behavioral changes- - - "CONTROL MEASURES - <br /> $liveN"snitf,rsg"(abuse)or intensional prolonged overexposure M high levoke of vepon can <br /> prvducil sbhorrmal behavior,convulsions,delirium,nervous system damage and sudden death, A£SPIRATORV PROTECTION-NIOSWMSHA appiovod salt-contained breathing apparatus o, <br /> JHC£SWON- 4bdemlely suit,Aspiration:to lungs may cause pnetemonilis. May Cause r supplod-eir mask must be available for nonaoutins and emergency uv.Mirk must be used <br /> ga.stroird"inat disturbances.Symptoms may include irritation,nausea.vomiting and diarrhea, for entry Into large tanks,vessets or other confinad spaces.Vom!larion may be used to cordrot <br /> May cause harm+ul centraN nervous system ersech.Etlects may include eycitatdn,euphoia. or reduce airborne concentrations ' - <br /> .headache.dizziness,drowsiness,blurred vision,latigva.Immors,convulsions.loss of con yENT1fJSTlOH - - <br /> sdousness,come•respiralory crest and death.Aspiration hazard it vomiting occurs."nay` LOCAL EXHAUST_- _-.. viii-NA SPECIAL -. <br /> - darn may'be evidenced b than es in u6no o _. ......................... ---. .-.... NA - <br /> ago y y V u1puL urine appearance o edema. <br /> .v. ... . <br /> MEOlf:al COHDI7lONS OFNEAAl LY AGGRAVATF�T BY fIPOSURf-Pre resting eye.skin MECHANfCAL (General) EXPLOSION PROOF OTHER .._ NA <br /> and respitatary disorders may be aggravated by exposure to this product.Impaired liver and SKIN PROTEC110H-Wear Imparyious gloms and protective cbNirp to prevart skin Contact. <br /> kidney functions from prebxisting disorders they be aggravated by exposure to this product..: .jyE PAOTECTION-Me,safety glasses or chemical goggles lo prevent eye contad.Co rat <br /> IARC has determined that gasoline engine exhaust is'posaofy car[inpgdni[. woof ami=lenses when work,ng with i"substance.Have eye washing tacsity readily xvaearile <br /> EMERGENCY AND FtRSr Arg PRoC£oURES � ... where eye contact can occur <br /> EYE CONTACT-Flush immediately with large arftounLs of bash avatar for ori least s5 minu[as. OTHER PACTECTIVE CLOTHING OR EOUIPAIEHT-Use a Chemical-esi rianl won.' <br /> Rennvecm[aaiensesniori Eyslids ahovldbehold away from the e"Miltoensure rnrhron,gn <br /> rinsing,Gel medcaf Clenion A imtalion persists. - WORK PRACTICES-Oo not use or[fors no a fumo-;pais or hot turtac.e.Usii only in volt <br /> renliiated area.Koop container closed.Never siphon by mouth-Do not weld,heal or drift cons <br /> SKIN CONTACT-Remove contaminated[Lomas ImmddiaiHy Wash skin Inoougnty wqn soap Miner.Replace cap or bung.Do not use pressure to empty drvm Or explosion may razun.Use <br /> and water.Get medicaF attention d irritation persists.Wash contaminated Cbthas, onl as-a motor[vel.Do not usa for daanin <br /> y g,pressure appliance lust,or nny Otl+er use.Keep <br /> INJECTION-High pressure'rhjeclions are serious mad icil emerge nc,es.Gel-odicM ane ntien heed away from container when opening or d"riling.. , <br /> immediately. <br /> HYGIENIC PRACTICES - Remov. conuminatoa cloning and dean before rause. wash <br /> INHALATION-Remove andLtEd person from source or e.possure'n nor braatning,ensure open thoroughly with soap and water after handing, <br /> airway and institute candiepulrnonary resuscitation{CPR[.11 breathing is difficult:eamin_isten <br /> OrY9en if availdbte.Get rthedCet aluinlipn, NA - MOT APPLICAELE• NDA - No ()ATA AVAILABLE <br /> This,nAwmarion rs based an'he cava evs,'sblt 10 us and considered 10 be con ru Ho,.- Dennis K. Burke,Inca makes no werrenry.dxpMlSed P'implied,mganinp the eocvracy d oris da'e, <br /> o,the rtsufrs to be obtained hom the use meteor.Omnis K.Burne.Inc .slu-es no rasnonsibRrs+for injury or lass Imm rhe use d me product 0ascnhel he,a,n <br />