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MSDS: Nufamt Weedar 64 Broadleaf Herbicide Page 3 of 7 Special Fire Fighting Procedures: Firefighters should wear NIOSH/MSHA approved self-contained breathing apparatus and full protective clothing. Dike area to prevent runoff and contamination of water sources. Dispose of fire control water later. Unusual Fre and Explosion hazards: Under fire conditions, toxic, corrosive fumes are emitted. Containers will burst from internal pressure under extreme fire conditions. Hazardous Decomposition Materials(Under Fire Conditions): Hydrogen chloride, oxides of nitrogen, and oxides of carbon. 6.ACCIDENTAL RELEASE MEASURES Evacuation Procedures and Safety:Wear appropriate protective gear for the situation. See Personal Protection information in Section 8. Containment of Spill: Dike spill using absorbent or impervious materials such as earth, sand or clay. Collect and contain contaminated absorbent and dike material for disposal. Cleanup and Disposal of Spill:Pump any free liquid into an appropriate closed container. Collect washings for disposal. Decontaminate tools and equipment following cleanup. (See Section 13.) Environmental and Regulatory Reporting:Prevent material from entering public sewer system or any waterways. Do not flush to drain. Large spills to soil or similar surfaces may necessitate removal of top soil.The affected area should be removed and placed in an appropriate container for disposal. Spills may be reportable to the National Response Center(800-424-8802)and to state and/or local agencies. 7.HANDLING AND STORAGE Handling: Handle containers carefully to avoid damage and spills. Storage: Store in original container in a dry secured storage area. Do not contaminate water, food or feed by storage or disposal. Avoid storage in close proximity to insecticides, fungicides, fertilizers and seeds. Keep container tightly closed when not in use. 8.EXPOSURE CONTROLS/PERSONALPROTECTION General: These recommendations provide general guidance for handling this product. Because specific work environments and material handling practices vary, safety procedures should be developed for each intended usage, including maintenance and repair of equipment. Contact personal protective equipment manufacturers for assistance with selection,use and maintenance of such equipment. Personal Protective Equipment: Respiratory Protection: When respirators are required, select NIOSH/MSHA approved equipment based on actual or potential airborne concentrations and in accordance with the appropriate regulatory standards and/or industrial recommendations. Under normal conditions, in the absence of other airborne contaminants, the following devices should provide protection from this material up to the conditions specified by the appropriate OSHA or ANSI standard(s):Air-purifying(half-mask/full-face)respirator with cartridges/canister approved for use against pesticides. Under conditions immediately dangerous to life or health, or emergency conditions with unknown concentrations, use a full-face positive pressure air-supplied respirator equipped with an emergency escape air supply unit or use a self-contained breathing apparatus unit. Eye/Face Protection: Eye and face protection requirements will vary dependent upon work environment conditions and material handling practices.Appropriate ANSI Z87 approved equipment should be selected for the particular use intended for this material. Eye contact should be prevented through use of protective eyewear such as chemical