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F <br /> omplex and variable. Environmental models that attempt to predict pesticided transport in the environment are beyond the scope of this investigation. <br /> ubject property is proposed to be developed into a three-parcel subdivision,pesticides <br /> alf-lives that may have been applied decades ago,primarily DDT, may be of a very <br /> ern. It is a possibility that DDT was applied to the subject property in the 1940s, 50s <br /> y 1960s before it was banned in 1972. DDT was used extensively throughout the <br /> agricultural fields of the San Joaquin Valley and degradates of DDT are found in virtually all of <br /> these soils. Previous Exposure Assessments made on typical San Joaquin Valley soils suggest an <br /> extremely low probability of adverse health effects from soil DDT/DDD and DDE <br /> concentrations (if the concentrations even exist). <br /> It is important to note that the surface soils currently in-place will undergo considerable physical <br /> and chemical changes during project development. These alterations include increases in <br /> ultraviolet light exposure, moisture content and aeration. Final concentrations of DDT or its <br /> degradates in the play areas or garden areas of each new single family residence cannot be <br /> predicted, and it is likely that no pesticide residues even exist. It can be reasonably concluded <br /> that the DDT, DDE and DDD concentrations will continue to degrade as reported in the <br /> published environmental fate data. The environmental fate data for DDT and its degradates <br /> DDD and DDE are illustrated below: <br /> DDT. Common name: Agritan, Anofex, Azotox, et al. <br /> Half-lives in the environment: <br /> Air: 17.7 -177 h. <br /> Surface water: 73.9 h for a pond 1 in deep. Degradation half-life of about 10 yr- <br /> average from loss rates determined in Lake Michigan. <br /> Groundwater: 16 d to 31.3 yr. <br /> Sediment: 3 to 5 yr <br /> Soil: 2-15.6 yrs based on observed rates of biodegradation in aerobic soils under <br /> field conditions. Avg. half life of-12 yrs in 3 different soils for -50 ppm in soil. <br /> (conversion of p,p'-DDT to p,p'-DDE). <br /> Environmental Fate Rate Constants or Half-Lives: <br /> Volatilization: Half-life of 3.7 d for water depth of 1 in, from soil w/h-1 of 578 h <br /> Oxidation: Photooxidation half-life of 168-8400 h in water, 17.7-177 h in air <br /> Hydrolysis: Estimated first-order half life of 22 yr <br /> Biodegradation: Aqueous aerobic half-life of 2-15.6 yrs <br /> DDE. Common name: DDE (p,p'-DDE; o,p'-DDE), product of DDT degradation. <br /> Half-lives in the environment: <br /> Air: Atmos. transformation lifetime est. to he< 1 d. <br /> Surface water: Hydrolytic half-life of >120 yr, est. half-life>300 d in lakes. <br /> Groundwater:N/A <br /> Sediment: N/A <br /> Soil: Field half life of 1000 d <br /> Biota: Elimination half-life of 340 d(rainbow trout), 300 d for birds. <br /> Page -4- <br /> Chesney Consulting <br />