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5.5 HAZARDOUS MATERIALS HANDLING <br /> TABLE 5.5-4 <br /> Toxic Effects and Exposure Levels of Regulated Substance <br /> Name Toxic Effects Exposure Levels-Pure NH3 <br /> Anhydrous Toxic effects for contact with pure liquid or vapor causes Occupational Exposures <br /> Ammonia eye, nose, and throat irritation, skin burns, and PEL=35 mg/m3 OSHA <br /> (99% NH3) vesiculation. Ingestion or inhalation causes burning pain TLV= 18 mg/m3 ACGIH <br /> in mouth, throat, stomach, and thorax, constriction of TWA= 18 mg/m3 NIOSH <br /> thorax, and coughing followed by vomiting blood, STEL=35 mg/m3 <br /> breathing difficulties, convulsions, and shock. Other Hazardous Concentrations <br /> symptoms include dyspnea, bronchospasms, pulmonary IDLH = 300 ppm <br /> edema, and pink frothy sputum. Contact or inhalation LD50=350 mg/kg-oral, rat <br /> overexposure can cause burns of the skin and mucous ingestion of 3 to 4 mL may be fatal <br /> membranes, and headache, salivation, nausea, and Sensitive Receptors <br /> vomiting. Other symptoms include labored breathing, ERPG-1 =25 ppm <br /> bloody mucous discharge, bronchitis, laryngitis, ERPG-2 =200 ppm <br /> hemmoptysis, and pneumonitis. Damage to eyes may be ERPG-3 = 1,000 ppm <br /> permanent, including ulceration of conjunctiva and cornea <br /> and corneal and lenticular opacities. <br /> ERPG = Emergency Response Planning Guideline <br /> ERPG-1 = Maximum airborne concentration below which nearly all individuals could be exposed for up to 1 hour <br /> without experiencing other than mild transient adverse health effects <br /> ERPG-2= Maximum airborne concentration below which nearly all individuals could be exposed for up to 1 hour <br /> without developing irreversible or serious health effects <br /> ERPG-3= Maximum airborne concentration below which nearly all individuals could be exposed for up to 1 hour <br /> without experiencing life-threatening health effects <br /> IDLH = Immediately dangerous to life and health <br /> LD50= Dose lethal to 50 percent of those tested <br /> mg/kg = milligrams per kilogram <br /> Mg/M3= milligrams per cubic meter <br /> mL= milliliters <br /> PEL=OSHA-permissible exposure limit for 8-hour workday <br /> ppm =parts per million <br /> STEL= Short-term exposure limit, 15-minute exposure <br /> TLV=ACGIH threshold limit value for 8-hour workday <br /> TWA= NIOSH time-weighted average for 8-hour workday <br /> Ammonia will only be transported along approved transportation routes. The <br /> recommended routes, subject to Caltrans approval, are as follows: <br /> • From I-5 exit at SR 12 interchange then turn south onto North Thornton Road,west on <br /> Frontage road, and south on North Cord Road; <br /> • From I-5 exit at West Eight Mile Road interchange then turn north onto North Thornton <br /> Road, west on Frontage road, and south on North Cord Road; <br /> Outbound trucks would proceed on 1-5 to access hazardous waste facilities throughout the <br /> state. Hauling would be carried out in accordance with local, state, and federal regulations <br /> that include the Resource Conservation and Recovery Act (42 U.S. Code 6901 et seq.) and <br /> the California Integrated Waste Management Act (Public Resources Code Sections <br /> 40000 et seq.). <br /> 5.5-16 SAC/371322/082330015(LEC_5.5_HAZMAT.DOC) <br />